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Synthesis and characterization of 1,3,5-tris((1/2H-tetrazol-5-yl)methyl)-1,3,5-triazinane-2,4,6-trione

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Abstract

2,2′,2″-(2,4,6-Trioxo-1,3,5-triazinane-1,3,5-triyl) triacetonitrile (or tris-(cyanomethyl)-isocyanurate) and 1,3,5-tris((1/2H-tetrazol-5-yl)methyl)-1,3,5-triazinane-2,4,6-trione (or tris-(5-tetrazolylmethyl)-isocyanurate) were synthesized with new methods. High yields, simple methodology, and cheapness are advantages of the methods. Furthermore, 1,3,5-tris((1/2H-tetrazol-5-yl)methyl)-1,3,5-triazinane-2,4,6-trione was synthesized in the less hazardous condition. The compounds were characterized by elemental analysis, IR, 1HNMR, 13CNMR and mass spectroscopic analysis. In addition, DSC/TGA measurements were carried out to determine the thermal behavior of the final product.

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Acknowledgements

The authors would like to thank the team members of Central Instrumental Laboratory of Malek-Ashtar University of Technology, Tehran, Iran.

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Correspondence to Yadollah Bayat.

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Bayat, Y., Hajighasemali, F. Synthesis and characterization of 1,3,5-tris((1/2H-tetrazol-5-yl)methyl)-1,3,5-triazinane-2,4,6-trione. Chem. Pap. 71, 949–952 (2017). https://doi.org/10.1007/s11696-016-0018-2

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  • DOI: https://doi.org/10.1007/s11696-016-0018-2

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