Skip to main content
Log in

Experimental Investigation of Phase Equilibria in the Fe-Nb-Ta System

  • Published:
Journal of Phase Equilibria and Diffusion Aims and scope Submit manuscript

Abstract

The phase equilibria in the Fe-Nb-Ta ternary system at 1200, 1100 and 1000 °C were experimentally investigated. The microstructure of each sample was observed using scanning electron microscopy, and phase compositions were measured by energy dispersive spectrometry. The constituent phases of typical samples were analyzed with x-ray diffraction. The experimental results indicated that the continuous solid solution phases, Fe2(Nb,Ta) and Fe7(Nb,Ta)6, were formed between Fe2Nb and Fe2Ta and Fe7Nb6 and Fe7Ta6, respectively, and no ternary compounds were found in this system in these isothermal sections. Based on the experimental phase equilibria data obtained in the present work, three isothermal sections at 1200, 1100 and 1000 °C were constructed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12

Similar content being viewed by others

References

  1. H. Tanigawa, H. Sakasegawa, N. Hashimoto, R.L. Klueh, M. Ando, and M.A. Sokolov, Irradiation Effects on Precipitation and Its Impact on the Mechanical Properties of Reduced-Activation Ferritic/Martensitic Steels, J. Nucl. Mater., 2007, 367, p 42-47

    Article  ADS  Google Scholar 

  2. D.H. Wen, Q. Wang, B.B. Jiang, C. Zhang, X.N. Li, G.Q. Chen, R. Tang, R.Q. Zhang, C. Dong, and P.K. Liaw, Developing Fuel Cladding Fe-25Cr-22Ni Stainless Steels with High Microstructural Stabilities Via Mo/Nb/Ti/Ta/W Alloying, Mater. Sci. Eng. A, 2018, 719, p 27-42

    Article  Google Scholar 

  3. V. Kuzucua, M. Aksoyb, and M.H. Korkutc, The Effect of Strong Carbide-Forming Elements Such as Mo, Ti, V and Nb on the Microstructure of Ferritic Stainless Steel, J. Mater. Process. Technol., 1998, 82(1), p 165-171

    Article  Google Scholar 

  4. N. Terao and B. Cauwe, Influence of Additional Elements (Mo, Nb, Ta and B) on the Mechanical Properties of High-Manganese Dual-Phase Steels, J. Mater. Sci., 1988, 23(5), p 1769-1778

    Article  ADS  Google Scholar 

  5. U.U. Gomes, J.F. Silva Jr., G.B.P. Ferreira, Effect of the Additives of Nanosized Nb and Ta Carbides on Microstructure and Properties of Sintered Stainless Steel, InTech, (2012), pp. 233–248

  6. L. Falat, A. Schneider, G. Sauthoff, and G. Frommeyer, Mechanical Properties of Fe-Al-M-C (M = Ti, V, Nb, Ta) Alloys with Strengthening Carbides and Laves Phase, Intermetallics, 2005, 13(12), p 1256-1262

    Article  Google Scholar 

  7. V. Knezevic, G. Sauthoff, J. Vilk, G. Inden, A. Schneider, R. Agamennone, W. Blum, Y. Wang, A. Scholz, C. Berger, J. Ehlers, and L. Singheiser, Martensitic/Ferritic Super Heat-Resistant 650 °C Steels-Design and Testing of Model Alloys, ISIJ Int., 2002, 42(12), p 1505-1514

    Article  Google Scholar 

  8. Y. Yamamoto, M. Takeyama, Z.P. Lu, C.T. Liu, N.D. Evans, P.J. Maziasz, and M.P. Brady, Alloying Effects on Creep and Oxidation Resistance of Austenitic Stainless Steel Alloys Employing Intermetallic Precipitates, Intermetallics, 2008, 16(3), p 453-462

    Article  Google Scholar 

  9. Y. Xu, D. Yi, H. Liu, X. Wu, B. Wang, and F. Yang, Effects of Cold Deformation on Microstructure, Texture Evolution and Mechanical Properties of Ti-Nb-Ta-Zr-Fe Alloy for Biomedical Applications, Mater. Sci. Eng. A, 2012, 547, p 64-71

    Article  Google Scholar 

  10. Y. Xu, Y. Xiao, D. Yi, H. Liu, L. Wu, and J. Wen, Corrosion Behavior of Ti-Nb-Ta-Zr-Fe Alloy for Biomedical Applications in Ringer’s Solution, Trans. Nonferr. Met. Soc. China, 2015, 25(8), p 2556-2563

    Article  Google Scholar 

  11. I. Kopova, J. Strasky, P. Harcuba, M. Landa, M. Janecek, and L. Bacakova, Newly Developed Ti-Nb-Zr-Ta-Si-Fe Biomedical Beta Titanium Alloys with Increased Strength and Enhanced Biocompatibility, Mater. Sci. Eng. C, 2016, 60, p 230-238

    Article  Google Scholar 

  12. D.E. Williams and W.H. Pechin, The Tantalum-Columbium Alloy System, Trans. Am. Soc. Met., 1958, 50, p 1081-1089

    Google Scholar 

  13. E. Rudy, Compendium of Phase Diagram Data, AFML, Wright-Patterson AFB, Ohio, Rep. No. AFML-TR-65-2, Part 5 (1969)

  14. K.C.H. Kumar, T.V. Rompaey, and P. Wollants, Thermodynamic Calculation of the Phase Diagram of the Co-Nb-Ta System, Z. Metallkd., 2002, 93(11), p 1146-1153

    Article  Google Scholar 

  15. W. Xiong, Y. Du, Y. Liu, B. Huang, H. Xu, H. Chen, and Z. Pan, Thermodynamic Assessment of the Mo-Nb-Ta System, CALPHAD, 2004, 28(2), p 133-140

    Article  Google Scholar 

  16. L.J. Swartzendruber and E. Paul, The Fe-Ta (Iron-Tantalum) System, Bull. Alloys Phase Diagr., 1986, 7(3), p 254-259

    Article  Google Scholar 

  17. T.B. Massalski, Binary Alloy Phase Diagrams, Vol 3, 2nd ed., T.B. Massalski, Ed., Materials Information Society, Materials Park, 1990

    Google Scholar 

  18. G.C. Coelho, J.G.C. Neto, S. Gama, and C.A. Ribeiro, Experimental Study of the Iron-Tantalum Equilibrium Diagram, J. Phase Equilib., 1995, 16(2), p 121-128

    Article  Google Scholar 

  19. S. Srikanth and A. Petric, Optimization and Calculation of the Fe-Ta Phase Diagram, J. Alloys Compd., 1994, 203, p 281-288

    Article  Google Scholar 

  20. A. Danon and C. Servant, Contribution to a Thermodynamic Database and Phase Equilibria Calculations for Low Activation Ta-Containing Steels, J. Nucl. Mater., 2003, 321(1), p 8-18

    Article  ADS  Google Scholar 

  21. V.T. Witusiewicz, A.A. Bondar, U. Hecht, V.M. Voblikov, O.S. Fomichov, V.M. Petyukh, and S. Rex, Experimental Study and Thermodynamic Re-assessment of the Binary Fe-Ta System, Intermetallics, 2011, 19(7), p 1059-1075

    Article  Google Scholar 

  22. V.B. Rajkumar and K.C.H. Kumar, Gibbs Energy Modeling of Fe-Ta System by Calphad Method Assisted by Experiments and Ab Initio Calculations, CALPHAD, 2015, 48, p 157-165

    Article  Google Scholar 

  23. B. Zelaya, S. Gama, C.A. Ribeiro, and G. Effenberg, The Iron–Niobium Phase Diagram, Z. Metallkd., 1993, 84(3), p 160-164

    Google Scholar 

  24. M. Takeyama, N. Gomi, S. Morita, and T. Matsuo, Phase Equilibria and Lattice Parameters of Fe2Nb Laves Phase in Fe-Ni-Nb Ternary System at Elevated Temperatures, MRS Online Proc. Libr., 2005, 842, p 461-466

    Google Scholar 

  25. S. Voß, M. Palm, F. Stein, and D. Raabe, Phase Equilibria in the Fe-Nb System, J. Phase Equilib. Diffus., 2011, 32(2), p 97-104

    Article  Google Scholar 

  26. A. Jacob, C. Schmetterer, A. Khvan, A. Kondratiev, D. Lvanov, and B. Hallstedt, Liquidus Projection and Thermodynamic Modeling of the Cr-Fe-Nb Ternary System, CALPHAD, 2016, 54, p 1-15

    Article  Google Scholar 

  27. A. Raman, Tantalum-Iron System, Trans. Indian Inst. Met., 1966, 19, p 202-205

    Google Scholar 

  28. E.F. Abrahamson and S.L. Lopata, The Lattice Parameters and Solubility Limits of Alpha Iron as Affected by Some Binary Transition Element Additions, Trans. Metall. Soc. AIME, 1966, 236, p 76-87

    Google Scholar 

  29. A. Raman, Structural Study of Niobium-Iron Alloys, Proc. Indian Acad. Sci., 1967, 65(4), p 256-264

    Google Scholar 

  30. E. Paul and L.J. Swartzendruber, The Fe-Nb (Iron-Niobium) System, Bull. Alloys Phase Diagr., 1986, 7(3), p 248-254

    Article  Google Scholar 

  31. K.C.H. Kumar and V. Raghavan, Bcc-fcc Equilibrium in Ternary Iron Alloys-II, J. Alloys Phase Diagr., 1989, 5(3), p 201-220

    Google Scholar 

Download references

Acknowledgment

The work was supported by the National Key R&D Program of China (Grant No. 2017YFB0703001) and the National Natural Science Foundation of China (NSFC) (Grant No. 51671025)

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Zhenmin Du.

Additional information

This invited article is part of a special issue of the Journal of Phase Equilibria and Diffusion in honor of Prof. Zhanpeng Jin’s 80th birthday. The special issue was organized by Prof. Ji-Cheng (JC) Zhao, The Ohio State University; Dr. Qing Chen, Thermo-Calc Software AB; and Prof. Yong Du, Central South University.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Yang, B., Du, Z., Guo, C. et al. Experimental Investigation of Phase Equilibria in the Fe-Nb-Ta System. J. Phase Equilib. Diffus. 39, 490–501 (2018). https://doi.org/10.1007/s11669-018-0658-8

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11669-018-0658-8

Keywords

Navigation