Skip to main content
Log in

A Study on the Inhibition of Copper Corrosion in Sulphuric Acid by Aqueous Extract of Leaves of Morinda tinctoria

  • Technical Article---Peer-Reviewed
  • Published:
Journal of Failure Analysis and Prevention Aims and scope Submit manuscript

Abstract

The corrosion of copper in 0.25 M sulphuric acid was studied by the addition of aqueous extract of leaves of Morinda tinctoria using weight loss and electrochemical methods. The addition of inhibitor moderately improves the inhibition efficiency. Increase in temperature and acid concentration decreases the performance of the inhibitor. The adsorption of the inhibitor on the copper surface in sulphuric acid medium obeys Freundlich isotherm. The AC impedance studies reveal that the process of inhibition is through charge transfer reaction, and polarization studies indicate the mixed nature of the inhibitor.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. R.W. Revie, H.H. Uhlig, Corrosion and Corrosion Control, An Introduction to Corrosion Science and Engineering, 4th edn. (A John Wiley & Sons, Inc., Hoboken, NJ, 2008). (in English)

    Google Scholar 

  2. D. Landolt, Corrosion and Surface Chemistry of Metals, 1st edn. (EPFL Press, A Swiss academic publisher distributed by CRC Press, Taylor and Francis Group, LLC, Boca Raton, FL, 2007). (in English)

    Book  Google Scholar 

  3. W.L. Harris, Chair, Committee on Assessing Corrosion Education, Assessment of Corrosion Education (The National Academies Press, Washington, DC, 2009). (in English)

    Google Scholar 

  4. E. McCafferty, Introduction to Corrosion Science (Springer, Alexandria, VA, 2009). (in English)

    Google Scholar 

  5. S. Li, S. Chen, S. Lei, H. Ma, R. Yu, D. Liu, Investigation on some Schiff bases as HCl corrosion inhibitors for copper. Corros. Sci. 41(7), 1273–1287 (1999). (in English)

    Article  Google Scholar 

  6. A. Igual Munoz, J. Garcia Anton, J.L. Guinon, V. Perez Herranz, Comparison of inorganic inhibitors of copper, nickel and copper–nickels in aqueous lithium bromide solution. Electrochimica Acta 50(4), 957–966 (2004). (in English)

    Article  Google Scholar 

  7. E.M. Sherif, S.-M. Park, Effects of 2-amino-5-ethylthio-1,3,4-thiadiazole on copper corrosion as a corrosion inhibitor in aerated acidic pickling solutions. Electrochim. Acta 51(28), 6556–6562 (2006). (in English)

    Article  Google Scholar 

  8. E.M. Sherif, Effects of 2-amino-5-(ethylthio)-1,3,4-thiadiazole on copper corrosion as a corrosion inhibitor in 3% NaCl solutions. Appl. Surf. Sci. 252(24), 8615–8623 (2006). (in English)

    Article  Google Scholar 

  9. L. Valek, S. Martinez, Copper corrosion inhibition by Azadirachta indica leaves extract in 0.5 M sulphuric acid. Mater. Lett. 61(1), 148–151 (2007). (in English)

    Article  Google Scholar 

  10. A.M. Shah, A.A. Rahim, S.A. Hamid, S. Yahya, Green inhibitors for copper corrosion by mangrove tannin. Int. J. Electrochem. Sci. 8, 2140–2153 (2013). (in English)

    Google Scholar 

  11. B.A. Abd-El-Nabey, A.M. Abdel-Gaber, M.E.S. Ali, Khamis E, S. El-Housseiny, Inhibitive action of cannabis plant extract on the corrosion of copper in 0.5 M H2SO4. Int. J. Electrochem. Sci. 8, 5851–5865 (2013). (in English)

    Google Scholar 

  12. R. Senthooran, N. Priyantha, Inhibition of corrosion of copper in hcl by tea leaves extracts: I. Corrosion rate measurements. Ann. Res. J. SLSAJ 12, 1–10 (2012). (in English)

    Google Scholar 

  13. E.A. Noor, Potential of aqueous extract of Hibiscus sabdariffa leaves for inhibiting the corrosion of aluminum in alkaline solutions. J. Appl. Electrochem. 39(9), 1465–1475 (2009). (in English)

    Article  Google Scholar 

  14. A. Minhaj, P.A. Saini, M.A. Quraishi, I.H. Farooqi, A study of natural compounds as corrosion inhibitors for industrial cooling systems. Corros. Preven. Control 46(2), 32–38 (1999). (in English)

    Google Scholar 

  15. M.A. Quraishi, A. Singh, V.K. Singh, D.K. Yadav, A.K. Singh, Green approach to corrosion inhibition of mild steel in hydrochloric acid and sulphuric acid solutions by the extract of Murraya koenigii leaves. Mater. Chem. Phys. 122(1), 114–122 (2010). (in English)

    Article  Google Scholar 

  16. I.E. Uwah, P.C. Okafor, V.E. Ebiekpe, Inhibitive action of ethanol extracts from Nauclea latifolia on the corrosion of mild steel in H2SO4 solutions and their adsorption characteristics. Arab. J. Chem. 6(3), 285–293 (2013). (in English)

    Article  Google Scholar 

  17. P.C. Okafor, E.E. Ebenso, U.J. Ekbe, Azadirachta indica extracts as corrosion inhibitor for mild steel in acidic medium. Int. J. Electrochem. Sci. 5(7), 978–993 (2010). (in English)

    Google Scholar 

  18. M. El-Sayed, O.Y. Mansour, I.Z. Selim, M.M. Ibrahim, Identification and utilization of banana plant juice and its liquor as anti-corrosive materials. J. Sci. Ind. Res. 60(9), 738–747 (2001). (in English)

    Google Scholar 

  19. J.C. da Rocha, J.A. da Cunha Ponciano Gomes, E. D’Elia, Corrosion inhibition of carbon steel in hydrochloric acid solution by fruit peel aqueous extracts. Corros. Sci. 52(7), 2341–2348 (2010). (in English)

    Article  Google Scholar 

  20. P.C. Okafor, M.E. Ikpi, I.E. Uwah, E.E. Ebenso, U.J. Ekpe, S.A. Umoren, Inhibitory action of Phyllanthus amarus extracts on the corrosion of mild steel in acidic media. Corros. Sci. 50(8), 2310–2317 (2008). (in English)

    Article  Google Scholar 

  21. P.C. Okafor, E.E. Ebenso, Inhibitive action of Carica papaya extracts on the corrosion of mild steel in acidic media and their adsorption characteristics. Pigm. Resin Technol. 36(3), 134–140 (2007). (in English)

    Article  Google Scholar 

  22. C.A. Loto, The effect of mango bark and leaf extract solution additives on the corrosion inhibition of mild steel in dilute sulphuric acid. Corros. Prev. Control 48(2), 59–64 (2001). (in English)

    Google Scholar 

  23. C.A. Loto, The effect of mango bark and leaf extract solution additives on the corrosion inhibition of mild steel in dilute sulphuric acid. Corros. Prev. Control 48(1), 38–41 (2001). (in English)

    Google Scholar 

  24. I.B. Obot, N.O. Obi-Egbedi, Ginseng root: a new efficient and effective eco-friendly corrosion inhibitor for aluminium alloy of type AA 1060 in hydrochloric acid solution. Int. J. Electrochem. Sci. 4(9), 1277–1288 (2009). (in English)

    Google Scholar 

  25. S.A. Umoren, I.B. Obot, E.E. Ebenso, N.O. Obi-Egbedi, The Inhibition of aluminium corrosion in hydrochloric acid solution by exudate gum from Raphia hookeri. Desalination 247(1–3), 561–572 (2009). (in English)

    Article  Google Scholar 

  26. Xianghong Li, Shuduan Deng, Inhibition effect of Dendrocalamus brandisii leaves extract on aluminum in HCl, H3PO4 solutions. Corros. Sci. 65, 299–308 (2012). (in English)

    Article  Google Scholar 

  27. E.E. Oguzie, Corrosion inhibition of aluminium in acidic and alkaline media by Sansevieria trifasciata extract. Corros. Sci. 49(3), 1527–1539 (2007). (in English)

    Article  Google Scholar 

  28. P.B. Raja, M.G. Sethuraman, Inhibitive effect of black pepper extract on the sulphuric acid corrosion of mild steel. Mater. Lett. 62(17–18), 2977–2979 (2008). (in English)

    Article  Google Scholar 

  29. K. Nisha, V. Priscillapushparani, R. Yogeshwari, P. Subashree, M. Chandran, S. Hariram, IJPI’s J. Pharmacogn. Herbal Formul. 1(6), 47–50 (2011). (in English)

    Google Scholar 

  30. G. Shanthi, D. Saridha, V. Mariappan, Pharmacognostical studies on morinda tinctoria.roxb. Int. J. Pharm. Pharm. Sci. 4(2), 636–638 (2012). (in English)

    Google Scholar 

  31. K. Krishnaveni, J. Ravichandran, A. Selvaraj, Effect of Morinda tinctoria leaves extract on the corrosion inhibition of mild steel in acid medium. Acta Metall. Sin (Engl. Lett. 26(3), 321–327 (2013). (in English)

    Article  Google Scholar 

  32. K. Krishnaveni, J. Ravichandran, A. Selvaraj, Inhibition of mild steel corrosion by Morinda tinctoria leaves extract in sulphuric acid medium. Ionics 20(1), 115–126 (2014). (in English)

    Article  Google Scholar 

  33. K. Krishnaveni, J. Ravichandran, Effect of aqueous extract of leaves of Morinda tinctoria on corrosion inhibition of aluminium surface in HCl medium. Trans. Nonferrous Met. Soc. China 24, 2704–2712 (2014). (in English)

    Article  Google Scholar 

  34. K. Krishnaveni, J. Ravichandran, Influence of aqueous extract of leaves of Morinda tinctoria on Copper corrosion in HCl medium. J. Electroanal. Chem. 735, 24–31 (2014). (in English)

    Article  Google Scholar 

  35. D.U. Omo-Dudu, N.C. Oforka, Inhibition of the corrosion of mild steel in tri oxonitrate (v) acid. Niger. J. Phys. 2, 148–153 (1999). (in English)

    Google Scholar 

  36. E.E. Oguzie, A.I. Onuchukwu, P.C. Okafor, E.E. Ebenso, Corrosion inhibition and adsorption behaviour of Ocimum basilicum extract on aluminium. Pigm. Resin Technol. 35, 63–70 (2006). (in English)

    Article  Google Scholar 

  37. E.E. Oguzie, Inhibition of acid corrosion of mild steel by Telfaria occidentalis extract. Pigment Resin Technol. 34(6), 321–326 (2005). (in English)

    Article  Google Scholar 

  38. N.O. Eddy, S.A. Odoemelam, A.O. Odiongenyi, Joint effect of halides and ethanol extract of Lasianthera africana on inhibition of corrosion of mild steel in H2SO4. J. Appl. Electrochem. 39, 849–857 (2009). (in English)

    Article  Google Scholar 

  39. S.A. Umoren, M.M. Solomon, I.I. Udosoro, A.P. Udoh, Inhibition of aluminium and mild steel corrosion in acidic medium using Gum Arabic. Cellulose 17, 635–648 (2010). (in English)

    Article  Google Scholar 

  40. D.Q. Zhang, L.X. Gao, G.-D. Zhou, Synergistic effect of 2-mercapto benzimidazole and KI on copper corrosion inhibition in aerated sulfuric acid solution. J. Appl. Electrochem. 33(5), 361–366 (2003). (in English)

    Article  Google Scholar 

  41. Y.C. Wu, P. Zhang, H.W. Pickering, D.L. Allara, Effect of KI on improving copper corrosion inhibition efficiency of benzotriazole in sulfuric acid electrolytes. J. Electrochem. Soc. 140(10), 2791–2800 (1993). (in English)

    Article  Google Scholar 

  42. S. Golfomitsou, J.F. Merkel, Synergistic effects of corrosion inhibitors for copper and copper alloy archaeological artefacts, Proceedings of Metal, National Museum of Australia Canberra ACT 4-8 (2004), ABN 70 592 297 967 (in English)

  43. H. Ashassi-Sorkhabi, B. Shaabani, D. Seifzadeh, Corrosion inhibition of mild steel by some schiff base compounds in hydrochloric acid. Appl. Surf. Sci. 239(2), 154–164 (2005). (in English)

    Article  Google Scholar 

  44. I.B. Obot, N.O. Obi-egbedi, Adsorption properties and inhibition of mild steel corrosion in sulphuric acid solution by ketoconazole: experimental and theoretical investigation. Corros. Sci. 52(1), 198–204 (2010). (in English)

    Article  Google Scholar 

  45. H. Ashassi-Sorkhabi, Z. Ghasemi, D. Seifzadeh, The inhibition effect of some amino acids towards the corrosion of aluminum in 1 M HCl + 1 M H2SO4 solution. Appl. Surf. Sci. 249(1–4), 408–418 (2005). (in English)

    Article  Google Scholar 

  46. A. Yurt, Y. Mihrican, Quantitative relationships between the structure of some thiol compounds and their inhibition efficiencies. Anti-Corr. Methods Mater. 55(4), 195–203 (2008). (in English)

    Article  Google Scholar 

  47. Jag Mohan, Organic Spectroscopy Principles and Applications, 2nd edn. (Narosa Publishing House, India, 2002), pp. 76–95

    Google Scholar 

Download references

Acknowledgment

The authors wish to acknowledge the Post Graduate and Research Department of Chemistry, Sri Ramakrishna Mission Vidyalaya College of Arts and Science, Coimbatore-20 for providing the facilities.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to J. Ravichandran.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Krishnaveni, K., Ravichandran, J. A Study on the Inhibition of Copper Corrosion in Sulphuric Acid by Aqueous Extract of Leaves of Morinda tinctoria . J Fail. Anal. and Preven. 15, 711–721 (2015). https://doi.org/10.1007/s11668-015-0002-0

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11668-015-0002-0

Keywords

Navigation