Abstract
This paper presents the failure investigation of lead-acid battery grids received from a local battery manufacturer. Distortion, cracking, and brittleness were observed in as-cast grids. These battery grids were gravity cast by re-melting of locally made Pb–Sb ingots. However, similar distortion and brittleness were not observed in grids of similar design cast by re-melting of imported Pb–Sb ingots. Spectroscopy, optical and scanning electron microscopy, SEM–EDS analysis, and microhardness measurements were carried out on both types of grids to find out the root cause of failure. It was concluded that the distortion and cracking were mainly caused because of coarse dendritic microstructure with interdendritic and intercellular segregation produced by either high pouring temperature or low cooling rates employed during casting. This conclusion suggests that the casting parameters may have differed for the two types of ingots used. However, another contributing factor was thermal stresses induced during solidification and the brittleness of the locally produced ingots which contained a high arsenic content.
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References
Hofmann, W.: Lead and Lead Alloys, 2nd edn. Springer. New York, 341p (1970)
Sklarchuk, J., Dewar, M.J., Valeriote, E.M., Vincze, A.M.: Low–antimony lead-alloy expanded grids. J. Power. Sour. 42(1–2), 38–47 (1993)
Cameron, A.: The Principles of Lubrication, 3rd edn. Longman, London, 263 p (1981)
Alarashi, R., Shaban, A.M., Kamal, M.: Evaluation of electronic transport and premature failure in the melt-spun Pb–Sn–Sb–Ag rapidly solidified alloys. Mater. Lett. 31, 61–65 (1997)
Perkins, J., Edwards, G.R.: Microstructural control in lead alloys for storage battery application. J. Mater. Sci. 10(1), 136–158 (1975)
Dawson, J.L., Gillibrand, M.I., Wilkinson, J.: The chemical role of Antimony in the lead-acid battery. J. Power Sour. 3, 1–11 (1971)
Sivaraman, G.: Engineering Properties and Applications of Lead Alloys. International Lead Zinc Research Organization, Marcel Dekker, USA (2000)
Williams, J.D.: The effect of arsenic on the age-hardening of lead–antimony alloys. Metallurgia 74(443), 105–108 (1966)
Worcester, A.W., O’Reilly, J.T.: Lead and Lead Alloys. In: ASM Handbook, vol. 2, 10th edn. ASM International, Metals Park, OH (1993)
Prengaman, R.D.: The metallurgy and performance of cast and rolled lead alloys for battery grids. J. Power. Sour. 67(1–2), 267–278 (1997)
Caldwell, T.W., Sokolov, U.S., Bocciarelli, L.M.: Casting and properties of grid alloys for maintenance-free batteries (Pb–Ca and Pb–Ca–Sn). J. Electrochem. Soc. 123(9), 972 (1976)
Osório, W.R., Claudia, S.C., Garcia, A.: Hot corrosion resistance of a Pb–Sb alloy for lead acid battery grids. J. Power. Sour. 185(2), 1471–1477 (2008)
Tsumuraya, K., Nishikawa, S.: Mechanism of enhanced precipitation phenomena in Pb(Sb) alloys with trace element As. Metall. Trans. A. 11A, 949–954 (1980)
Yu, L., Ding, G.L., Reye, J., Tewari, S.N., Ojha, S.N.: Mushy zone morphology during directional solidification of Pb-5.8 wt pct Sb alloy. Metall. Mater. Trans. A. 31A, 2275–2285 (2000)
O’Dell, S.P., Ding, G.L., Tewari, S.N.: Cell/dendrite distribution in directionally solidified hypoeutectic Pb–Sb alloys. Metall. Mater. Trans. A. 30A, 2159–2165 (1999)
Neto, J.C.M., Batista, W.W., De Castro, W.B., Luciano, B.A.: Solidification of undercooled Pb–Sb Alloys. In: 17th CBECIMat, vol. 15A, Brazil (2006)
Kallup, B.E., Bemdt, D.: Advances in lead-acid batteries. Proc. Electr. Chem. Soc. 84(14), 214 (1984)
Acknowledgments
The authors thank Prof. Dr. Ashraf Ali (Chairman of Materials Engineering Department, NED University, Karachi) for his guidance and valuable suggestions. They also thank Mr. Badar-ul-Hasan (Technical Officer, SUPARCO) for his technical assistance and discussion throughout this work and Mr. Yousuf (Centralize Science Laboratory, Karachi University) for providing SEM–EDS facility.
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Tariq, F., Umair Azher, S. & Naz, N. Failure Analysis of Cast Lead–Antimony Battery Grids. J Fail. Anal. and Preven. 10, 152–160 (2010). https://doi.org/10.1007/s11668-010-9331-1
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DOI: https://doi.org/10.1007/s11668-010-9331-1