Journal of Failure Analysis and Prevention

, Volume 9, Issue 2, pp 127–132 | Cite as

Failure Analysis: Wastewater Drum Bulging

  • P. R. Vormelker
  • J. C. Guy
Case History---Peer-Reviewed


A 55 gallon wastewater drum lid was found to bulge during storage in a remote area. This bulging was of concern because it suggested that the drum was pressurized and that the integrity of the drum could be in question. Drum samples were obtained for analysis. The interior surface of these samples revealed blistering and holes in the epoxy phenolic drum liner and corrosion of the underlying carbon steel drum. It is suspected that osmotic pressure drove permeation of water through the epoxy phenolic coating which was weakened from exposure to low pH water. The permeating water accumulated at weak spots along the coating/carbon steel interface and caused blistering and failure of the coating. The coating failed at locations throughout the drum interior. Subsequent corrosion of the carbon steel released hydrogen which pressurized the drum, thus causing deformation of the drum lid. Additional samples from other wastewater drums on the same pallet were also evaluated, and limited corrosion was visible on the interior surfaces. It is suspected that, with time, the same degradation process would have caused pressurization of the entire batch of sealed drums that contained similar wastewater solutions.


Wastewater Corrosion Hydrogen Carbon steel 



The author expresses his sincere thanks to D. Z. Nelson and C. N. Foreman for the metallographic work and also to D. J. Hathcock and D. W. Vinson for their guidance during this investigation.


  1. 1.
    Weast, R.C. (ed.): Handbook of Chemistry and Physics, p. D-149. CRC Press, Boca Raton (1974)Google Scholar
  2. 2.
    Funke, W.: Toward a unified view of the mechanism responsible for paint defects by metallic corrosion. Ind. Eng. Chem. Prod. Res. Dev. 24(3), 343–347 (1985)CrossRefGoogle Scholar
  3. 3.
    Weldon, D.W.: Failure Analysis of Paints and Coatings, pp. 29–30. Wiley, New York (2002)Google Scholar
  4. 4.
    Graystone, J.A.: Metallic substrates. In: Lambourne, R., Strivens, T.A. (eds.) Paint and Surface Coatings, Theory and Practice, 2nd edn., pp. 400-401. William Andrew, Norwich, NY (1999)Google Scholar
  5. 5.
    Fontana, M.G.: Corrosion Engineering, 3rd edn., pp. 16–17. McGraw-Hill, New York (1967)Google Scholar
  6. 6.
    Uhlig, H.H. (ed.): The Corrosion Handbook, pp. 125–129. Wiley, New York (1948)Google Scholar
  7. 7.
    Landrum, R.J.: Designing for Corrosion Control, pp. 15–20. National Association of Corrosion Engineers (1989)Google Scholar
  8. 8.
    Wiersma, B.J.: Hydrogen generation during the corrosion of carbon steel in oxalic acid (U), WSRC-TR-2004-00441, August 2004Google Scholar
  9. 9.
    Sferrazza, L., Williams, M.: Pressurized drums, what every handler should know. Department of Defense Radioactive Waste Generators Conference, May 2002Google Scholar
  10. 10.
    Larranaga, M.D., Volz, D.L., Bolton, F.N.: Pressure effects and deformation of waste containers. Fire Eng. 152(7), July 1999Google Scholar

Copyright information

© ASM International 2008

Authors and Affiliations

  1. 1.Savannah River National LaboratoryAikenUSA
  2. 2.Savannah River Nuclear Solutions, Inc.AikenUSA

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