Skip to main content
Log in

Influence of Alloy Additions on the Microstructure, Texture, and Hardness of Low-Pressure Cold-Sprayed Al-Cu Alloys

  • Peer Reviewed
  • Published:
Journal of Thermal Spray Technology Aims and scope Submit manuscript

Abstract

This paper examines a series of Al-Cu binary alloy coatings, ranging from 2 to 5 weight percent copper, produced using low-pressure cold spray (CS) deposition with helium as the carrier gas. Binary Al-Cu alloy feedstock powder was produced through inert gas atomization and was sprayed over a variety of temperatures and pressures. Using helium gas, this set of Al-Cu alloys was successfully deposited as high-density coatings. Raising the carrier gas pressure increased the particle velocity and deposition efficiency (DE) in the case of spraying the Al-5 wt.% Cu powders. A clear composite deformation structure was formed in all coatings with clear prior particle centers surrounded by severely deformed regions with ultrafine grains. Microstructural deformation generated by the CS process produced a weak but clear <110> fiber texture for both Al-2 wt.% Cu and Al-5 wt.% Cu coatings. The copper content of the feedstock powder directly influenced the coating hardness and porosity, while having no systematic effect on the DE.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12

Similar content being viewed by others

References

  1. J. Villafuerte and D. Wright, Practical Cold Spray Success: Repair of Al and Mg Alloy Aircraft Components, Adv. Mater. Processes, 2010, 168(5), p 53-55

    Google Scholar 

  2. J. Villafuerte, Modern Cold Spray: Materials, Process, and Applications, Springer International Publishing, Basel, 2015

    Book  Google Scholar 

  3. V.K. Champagne, D.J. Helfritch, S.P.G. Dinavahi, and P.F. Leyman, Theoretical and Experimental Particle Velocity in Cold Spray, J. Therm. Spray Technol., 2011, 20(3), p 425-431

    Article  Google Scholar 

  4. Q. Wang, N. Birbilis, H. Huang, and M.-X. Zhang, Microstructure Characterization and Nanomechanics of Cold-Sprayed Pure Al and Al-Al2O3 Composite Coatings, Surf. Coat. Technol., 2013, 232, p 216-223

    Article  Google Scholar 

  5. X.-J. Ning, J.-H. Jang, and H.-J. Kim, The Effects of Powder Properties on In-Flight Particle Velocity and Deposition Process during Low Pressure Cold Spray Process, Appl. Surf. Sci., 2007, 253(18), p 7449-7455

    Article  Google Scholar 

  6. P.C. King, G. Bae, S.H. Zahiri, M. Jahedi, and C. Lee, An Experimental and Finite Element Study of Cold Spray Copper Impact onto Two Aluminum Substrates, J. Therm. Spray Technol., 2010, 19(3), p 620-634

    Article  Google Scholar 

  7. X.M. Meng, J.B. Zhang, W. Han, J. Zhao, and Y.L. Liang, Influence of Annealing Treatment on the Microstructure and Mechanical Performance of Cold Sprayed 304 Stainless Steel Coating, Appl. Surf. Sci., 2011, 258(2), p 700-704

    Article  Google Scholar 

  8. K. Spencer and M.-X. Zhang, Optimisation of Stainless Steel Cold Spray Coatings Using Mixed Particle Size Distributions, Surf. Coat. Technol., 2011, 205(21), p 5135-5140

    Article  Google Scholar 

  9. M. Rokni, S. Nutt, C. Widener, V. Champagne, and R. Hrabe, Review of Relationship Between Particle Deformation, Coating Microstructure, and Properties in High-Pressure Cold Spray, J. Therm. Spray Technol., 2017, 26(6), p 1308-1355

    Article  Google Scholar 

  10. N. Matthews, R. Jones, and G. Sih, Application of Supersonic Particle Deposition to Enhance the Structural Integrity of Aircraft Structures, Sci. China Phys. Mech. Astron., 2014, 57(1), p 12-18

    Article  Google Scholar 

  11. R. Jones, L. Molent, S. Barter, N. Matthews, and D. Tamboli, Supersonic Particle Deposition as a Means for Enhancing the Structural Integrity of Aircraft Structures, Int. J. Fatigue, 2014, 68, p 260-268

    Article  Google Scholar 

  12. K. Petráčková, J. Kondás, and M. Guagliano, Fixing a Hole (with Cold Spray), Int. J. Fatigue, 2018, 110, p 144-152

    Article  Google Scholar 

  13. M. Rokni, C. Widener, and G. Crawford, Microstructural Evolution of 7075 Al Gas Atomized Powder and High-Pressure Cold Sprayed Deposition, Surf. Coat. Technol., 2014, 251, p 254-263

    Article  Google Scholar 

  14. M. Rokni, C. Widener, O. Ozdemir, and G. Crawford, Microstructure and Mechanical Properties of Cold Sprayed 6061 Al in As-Sprayed and Heat Treated Condition, Surf. Coat. Technol., 2017, 309, p 641-650

    Article  Google Scholar 

  15. M.R. Rokni and C.A. Widener, Microstructural Stability of Ultrafine Grained Cold Sprayed 6061 Aluminum Alloy, Appl. Surf. Sci., 2014, 290, p 482-489

    Article  Google Scholar 

  16. L. Ajdelsztajn, A. Zuniga, B. Jodoin, and E. Lavernia, Cold Gas Dynamic Spraying of a High Temperature Al Alloy, Surf. Coat. Technol., 2006, 201(6), p 2109-2116

    Article  Google Scholar 

  17. T. Liu, J.D. Leazer, S.K. Menon, and L.N. Brewer, Microstructural Analysis of Gas Atomized Al-Cu Alloy Feedstock Powders for Cold Spray Deposition, Surf. Coat. Technol., 2018, 350, p 621-632

    Article  Google Scholar 

  18. L. Pouliot, CSM eVOLUTION Product Manual, TECNAR Automation Ltd, Saint-Bruno-de-Montarville, 2013

    Google Scholar 

  19. M. Karri, J. Singh, K. Manikrishna, B. Kumawat, N. Kumar, and D. Srivastava, On the Suitability of Peak Profile Analysis Models for Estimating Dislocation Density, Mater. Sci. Eng. A, 2017, 700, p 75-81

    Article  Google Scholar 

  20. U. Martin, U. Muhle, and H. Oettel, The Quantitative Measurement of Dislocation Density in the Transmission Electron Microscope, Prakt. Metallogr., 1995, 32(9), p 467-476

    Google Scholar 

  21. R. Huang and H. Fukanuma, Study of the Influence of Particle Velocity on Adhesive Strength of Cold Spray Deposits, J. Therm. Spray Technol., 2012, 21(3–4), p 541-549

    Article  Google Scholar 

  22. T.R. Jayasingh, T.R. Jeyaseelan, C. Kannan, and M.G. Karthikeyan, Numerical (CFD) Analysis of Thermal Spray Coating Process, Int. J. Mod. Eng. Res., 2014, 4(3), p 46-62

    Google Scholar 

  23. D. Gilmore, R. Dykhuizen, R. Neiser, M. Smith, and T. Roemer, Particle Velocity and Deposition Efficiency in the Cold Spray Process, J. Therm. Spray Technol., 1999, 8(4), p 576-582

    Article  Google Scholar 

  24. M. Rokni, C. Widener, and V. Champagne, Microstructural Evolution of 6061 Aluminum Gas-Atomized Powder and High-Pressure Cold-Sprayed Deposition, J. Therm. Spray Technol., 2014, 23(3), p 514-524

    Article  Google Scholar 

  25. L. Brewer, M. Othon, L. Young, and T. Angeliu, Misorientation Mapping for Visualization of Plastic Deformation via Electron Back-Scattered Diffraction, Microsc. Microanal., 2006, 12(1), p 85-91

    Article  Google Scholar 

  26. A.C. Hall and L.N. Brewer, Preparation of Aluminum Coatings Containing Homogenous Nanocrystalline Microstructures Using the Cold Spray Process, J. Therm. Spray Technol., 2008, 17(3), p 352-359

    Article  Google Scholar 

  27. M. Meyers, Y. Xu, Q. Xue, M. Perez-Prado, and T. McNelley, Microstructural Evolution in Adiabatic Shear Localization in Stainless Steel, Acta Mater., 2003, 51(5), p 1307-1325

    Article  Google Scholar 

  28. M. Drury and F. Humphreys, The Development of Microstructure in Al-5% Mg During High Temperature Deformation, Acta Metall., 1986, 34(11), p 2259-2271

    Article  Google Scholar 

  29. F.J. Humphreys and M. Hatherly, Chapter 13 Hot Deformation and Dynamic Restoration, Recrystallization and Related Annealing Phenomena, 2nd ed., Elsevier, Oxford, 2004, p 415-450

    Google Scholar 

  30. Y. Zou, W. Qin, E. Irissou, J.-G. Legoux, S. Yue, and J.A. Szpunar, Dynamic Recrystallization in the Particle/Particle Interfacial Region of Cold-Sprayed Nickel Coating: Electron Backscatter Diffraction Characterization, Scr. Mater., 2009, 61(9), p 899-902

    Article  Google Scholar 

  31. A. Mishra, B. Kad, F. Gregori, and M. Meyers, Microstructural Evolution in Copper Subjected to Severe Plastic Deformation: Experiments and Analysis, Acta Mater., 2007, 55(1), p 13-28

    Article  Google Scholar 

  32. J. Hines and K. Vecchio, Recrystallization Kinetics Within Adiabatic Shear Bands, Acta Mater., 1997, 45(2), p 635-649

    Article  Google Scholar 

  33. J.A. Hines, K.S. Vecchio, and S. Ahzi, A Model for Microstructure Evolution in Adiabatic Shear Bands, Metall. Mater. Trans. A, 1998, 29(1), p 191-203

    Article  Google Scholar 

  34. H. Assadi, F. Gärtner, T. Stoltenhoff, and H. Kreye, Bonding Mechanism in Cold Gas Spraying, Acta Mater., 2003, 51(15), p 4379-4394

    Article  Google Scholar 

  35. T. Schmidt, F. Gärtner, H. Assadi, and H. Kreye, Development of a Generalized Parameter Window for Cold Spray Deposition, Acta Mater., 2006, 54(3), p 729-742

    Article  Google Scholar 

  36. Y. Xiong, K. Kang, G. Bae, S. Yoon, and C. Lee, Dynamic Amorphization and Recrystallization of Metals in Kinetic Spray Process, Appl. Phys. Lett., 2008, 92(19), p 194101

    Article  Google Scholar 

  37. K. Kim, M. Watanabe, and S. Kuroda, Bonding Mechanisms of Thermally Softened Metallic Powder Particles and Substrates Impacted at High Velocity, Surf. Coat. Technol., 2010, 204(14), p 2175-2180

    Article  Google Scholar 

  38. K. Kang, J. Won, G. Bae, S. Ha, and C. Lee, Interfacial Bonding and Microstructural Evolution of Al in Kinetic Spraying, J. Mater. Sci., 2012, 47(11), p 4649-4659

    Article  Google Scholar 

  39. P.C. King, G. Bae, S.H. Zahiri, M. Jahedi, and C. Lee, An Experimental and Finite Element Study of Cold Spray Copper Impact onto Two Aluminum Substrates, J. Therm. Spray Technol., 2009, 19(3), p 620-634

    Article  Google Scholar 

  40. A. Day, P. Trimby, K. Mehnert, and B. Neumann, Channel 5 User Manual, HKL Technology A/S, Hobro, 2001

    Google Scholar 

  41. K. Kang, H. Park, G. Bae, and C. Lee, Microstructure and Texture of Al Coating During Kinetic Spraying and Heat Treatment, J. Mater. Sci., 2012, 47(9), p 4053-4061

    Article  Google Scholar 

  42. F. Humphreys and M. Hatherly, Chapter 3 Deformation Texture, Recrystallization and Related Annealing Phenomena, 2nd ed., Elsevier, Oxford, 2004, p 67-89

    Book  Google Scholar 

  43. T. Schulthess, P. Turchi, A. Gonis, and T.G. Nieh, Stacking Fault Energies in Al-Based Alloys, Properties of Complex Inorganic Solids, A. Gonis, A. Meike, and P.E.A. Turchi, Ed., Plenum Publishing Co., Boston, 1997, p 383-388

    Chapter  Google Scholar 

  44. S. Son, M. Takeda, M. Mitome, Y. Bando, and T. Endo, Precipitation Behavior of an Al-Cu Alloy During Isothermal Aging at Low Temperatures, Mater. Lett., 2005, 59(6), p 629-632

    Article  Google Scholar 

  45. K. Ichikawa, Y. Kinoshita, and S. Shimamura, Grain Refinement in Al-Cu Binary Alloys by Rheocasting, Trans. Jpn. Inst. Met., 1985, 26(7), p 513-522

    Article  Google Scholar 

  46. D. Xiao, J. Wang, D. Ding, and S. Chen, Effect of Cu Content on the Mechanical Properties of an Al-Cu-Mg-Ag Alloy, J. Alloys Compd., 2002, 343(1), p 77-81

    Article  Google Scholar 

  47. M. Murayama, Z. Horita, and K. Hono, Microstructure of Two-Phase Al-1.7 at% Cu Alloy Deformed by Equal-Channel Angular Pressing, Acta Mater., 2001, 49(1), p 21-29

    Article  Google Scholar 

  48. T. Shanmugasundaram, B. Murty, and V.S. Sarma, Development of Ultrafine Grained High Strength Al-Cu Alloy by Cryorolling, Scr. Mater., 2006, 54(12), p 2013-2017

    Article  Google Scholar 

  49. S. Ringer, K. Hono, and T. Sakurai, The Effect of Trace Additions of Sn on Precipitation in Al-Cu Alloys: An Atom Probe Field Ion Microscopy Study, Metall. Mater. Trans. A, 1995, 26(9), p 2207-2217

    Article  Google Scholar 

  50. N. Bekheet, R. Gadelrab, M. Salah, and A.A. El-Azim, The Effects of Aging on the Hardness and Fatigue Behavior of 2024 Al alloy/SiC Composites, Mater. Des., 2002, 23(2), p 153-159

    Article  Google Scholar 

  51. M. Rokni, C. Widener, A. Nardi, and V. Champagne, Nano Crystalline High Energy Milled 5083 Al Powder Deposited Using Cold Spray, Appl. Surf. Sci., 2014, 305, p 797-804

    Article  Google Scholar 

  52. M. Rokni, C. Widener, G. Crawford, and M. West, An Investigation into Microstructure and Mechanical Properties of Cold Sprayed 7075 Al Deposition, Mater. Sci. Eng. A, 2015, 625, p 19-27

    Article  Google Scholar 

Download references

Acknowledgments

We are grateful to J.A. Christophersen and J.N. Wolk for assistance with the compressed air cold spray deposition and characterization portion of this research. This research was supported by the funding from Mr. William Nickerson of the Office of Naval Research (Code 35 Sea-Based Aviation Structures and Materials, N0001414WX00148) and the funding from the college of engineering at the University of Alabama.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Luke N. Brewer.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Liu, T., Leazer, J.D., Bannister, H. et al. Influence of Alloy Additions on the Microstructure, Texture, and Hardness of Low-Pressure Cold-Sprayed Al-Cu Alloys. J Therm Spray Tech 28, 904–916 (2019). https://doi.org/10.1007/s11666-019-00860-6

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11666-019-00860-6

Keywords

Navigation