Advertisement

Structural and Mechanical Properties of the ZrC/Ni-Nanodiamond Coating Synthesized by the PVD and Electroplating Processes for the Cutting Knifes

  • V. Chayeuski
  • V. Zhylinski
  • O. Cernashejus
  • N. Visniakov
  • G. Mikalauskas
Article
First Online:
Received:
Revised:
  • 76 Downloads

Abstract

In this work, combined gradient ZrC/Ni-nanodiamond ultradispersed diamonds (UDD) coatings were synthesized on the surface of knife blades made of hard alloy WC-2 wt.% Co by electroplating and cathode arc evaporation PVD techniques to increase the durability period of a wood-cutting milling tool. The microstructure, phase and elemental composition, microhardness, and adhesion strength of the coatings were investigated. Ni-UDD layer is not mixed with the ZrC coating and hard alloy substrate. Cobalt is present in Ni-UDD layer after deposition of ZrC. The ZrC/Ni-nanodiamond coating consists of separate phases of zirconium carbide (ZrC), α-Ni, and Ni-UDD. The maximum value of microhardness of the Ni-nanodiamond coating is 5.9 GPa. The microhardness value of the ZrC/Ni-nanodiamond coatings is 25 ± 6 GPa, which corresponds to the microhardness of the hard alloy substrate and ZrC coating. The obtained high values of the critical loads on the scratch track of the ZrC/Ni-nanodiamond coating in 24 N prove a sufficiently high value of the adhesion strength of the bottom Ni-UDD layer with WC-Co substrate. Pilot testing of ZrC/Ni-nanodiamond-coated cutting tools proved their increasing durability period to be 1.5-1.6 times higher than that of bare tools, when milling laminated chipboard.

Keywords

ceramics coatings inorganic nanomaterials structural 
This is a preview of subscription content, log in to check access.

Notes

Acknowledgments

The authors wish to acknowledge the financial support from the Ministry of Education of the Republic of Belarus through the Fund for Fundamental Research of the Republic of Belarus (project No 7.4 “Galvanotechnics,” assignment No 7.4.6).Besides that, the authors are grateful to science group of the State Center “Belmikroanaliz” (the branch Scientific and Technical Center “Belmikrosistemy” of “INTEGRAL” Holding, the Republic of Belarus) for performing part of this work and for helpful discussion.

References

  1. 1.
    F.E. Palomar, P.C. Zambrano, M.I. Gómez, R. Colás, M.P. Guerrero, and A. Castillo, Coatings Made of Tungsten Carbide and Tantalum Carbide for Machining Tools, Vacuum, 2010, 84, p 1236–1239CrossRefGoogle Scholar
  2. 2.
    K. Egashira, S. Hosono, S. Takemoto, and Y. Masao, Fabrication and Cutting Performance of Cemented Tungsten Carbide Micro-Cutting Tools, Precis Eng, 2011, 35(4), p 547–553CrossRefGoogle Scholar
  3. 3.
    LEKSIKON Leitts: catalog firmy Leitz (LEKSIKON Leitz: Leitz Co. Catalog), on CD-ROM, Moscow, Leitts Instrumenty, 2011, (in Russian)Google Scholar
  4. 4.
    V.V. Abrazumov and V.D. Kotenko, The Analysis of the Phenomena on Contact Surfaces of a Cutting at cutting Board Wood Composite Materials, Vestnik Moskovskogo gosudarstvennogo universiteta lesa, For Bul, 2006, 6, p 138–141 (in Russian)Google Scholar
  5. 5.
    V.V. Abrazumov, Wear resistance of cutting tools during machining of wooden composite materials, Doctoral (Eng.) Thesis, Moscow State Forest University, 2009 (in Russian)Google Scholar
  6. 6.
    G. Ma, L. Wang, G. Haoxiang, J. Zhang, and T. Reddyhoff, The Friction Coefficient Evolution of a TiN Coated Contact During Sliding Wear, Appl. Surf. Sci., 2015, 345, p 109–115CrossRefGoogle Scholar
  7. 7.
    A.K. Kuleshov, V.V. Uglov, D.P. Rusalsky, A.A. Grishkevich, V.V. Chaevski, and V.N. Haranin, Effect of ZrN and Mo-N Coatings and Sulfacyanization on Wear of Wood-Cutting Knives, J. Frict. Wear, 2014, 35(3), p 201–209CrossRefGoogle Scholar
  8. 8.
    A. Gilewicz, B. Warcholinski, P. Myslinski, and W. Szymanski, Anti-wear Multilayer Coatings Based on Chromium Nitride for Wood Machining Tools, Wear, 2010, 270, p 32–38CrossRefGoogle Scholar
  9. 9.
    H.K. Kim, J.H. La, K.S. Kim, and S.Y. Lee, The Effects of the H/E Ratio of Various Cr-N Interlayers on the Adhesion Strength of CrZrN Coatings on Tungsten Carbide Substrates, Surf. Coat. Technol., 2015, 284, p 230–234CrossRefGoogle Scholar
  10. 10.
    V.M. Beresnev, S.S. Grankin, S.Y. Novikov, U.S. Nyemchenko, O.V. Sobol, and P.V. Turbin, Tribotechnical Properties of the Coatings (Ti-Zr-Nb)N, J. Nano-Electron. Phys., 2014, 6(4), p 4011–4015Google Scholar
  11. 11.
    T.S. Kumar, S.B. Prabu, and G. Manivasagam, Metallurgical Characteristics of TiAlN/AlCrN Coating Synthesized by the PVD Process on a Cutting Insert, J. Mat. Eng. Perf., 2014, 23(8), p 2877–2884CrossRefGoogle Scholar
  12. 12.
    S.N. Grigoriev, A.A. Vereschaka, S.V. Fyodorov, N.N. Sitnikov, and A.D. Batako, Comparative Analysis of Cutting Properties and Nature of Wear of Carbide Cutting Tools with Multi-Layered Nano-Structured and Gradient Coatings Produced by Using of Various Deposition Methods, Int. J. Adv. Manuf. Technol., 2017, 90(9–12), p 3421–3435CrossRefGoogle Scholar
  13. 13.
    P. Philbin and S. Gordon, Characterisation of the Wear Behaviour of Polycrystalline Diamond (PCD) Tools when Machining Wood-Based Composites, J. Mater. Proces. Technol., 2005, 162–163, p 665–672CrossRefGoogle Scholar
  14. 14.
    V.Y. Dolmatov, Detonation Synthesis Ultradispersed Diamonds: Properties and Applications, Rus. Chem. Rev., 2001, 70(7), p 687–708CrossRefGoogle Scholar
  15. 15.
    S.S. Popova, G.V. Tseluikina, N.D. Solovieva, and V.N. Tseluikin, Functional Coatings Based on Iron Alloys, Electroplat. Surf. Treat., 2001, 9(1), p 34–39 (in Russian)Google Scholar
  16. 16.
    N.I. Polushin, A.V. Kudinov, V.V. Zhuravlev, N.N. Stepareva, and A.L. Maslov, Dispersed Hardening of Diamond Composite Electrochemical Coating by Nanoparticles, Rus. J. Non-Ferr. Met., 2013, 54(5), p 412–416CrossRefGoogle Scholar
  17. 17.
    V. Chayeuski, V. Zhylinskiy, A. Grishkevich, P. Rudak, and S. Barcik, Influence of High Energy Treatment on Wear of Edges Knives of Wood-Cutting Tool, MM Sci. J., 2016, 6, p 1519–1523CrossRefGoogle Scholar
  18. 18.
    A.S. Kononov, Y.S. Sachivko, A.P. Korzhenevskiy, and R.G. Shtemplyuk, Thermal Stability of Chromium Coatings Modified with Nano-Sized Oxygen-Containing Additives, Mechanics of Machines, Mechanisms and Materials, 2015, 4, p 353–357Google Scholar
  19. 19.
    G.K. Burkat and V.Y. Dolmatov, Application of Ultrafine-Dispersed Diamonds in Electroplating, Phys. Solid State, 2004, 46(4), p 703–710CrossRefGoogle Scholar
  20. 20.
    A.V. Alifanov, A.A. Grishkevich, V.V. Chayevskii, and V.N. Garanin, Influence of TiN-Coatings Hard Alloy Knives on Exploitation of Wood-Cutting Milling Tool when Processing Laminated Chipboard, Proc. BSTU, 2012, 2, p 146–149Google Scholar
  21. 21.
    A.A. Matei, I. Pencea, S.G. Stanciu, R. Hristu, I. Antoniac, E. Ciovica, C.E. Sfat, and G.A. Stanciu, Structural Characterization and Adhesion Appraisal of TiN and TiCN Coatings Deposited by CAE-PVD Technique on a New Carbide Composite Cutting Tool, J. Adhesion Sci. Tech., 2015, 29(23), p 2576–2589CrossRefGoogle Scholar
  22. 22.
    S.W. Huang, M.W. Ng, M. Samandi, and M. Brandt, Tribological Behaviour and Microstructure of TiCxN(1−x) Coatings Deposited by Filtered Arc, Wear, 2002, 252, p 566–579CrossRefGoogle Scholar
  23. 23.
    K. Chen, L. Zhao, P.C. Patnaik, and J.S. Tse, Elastic Properties of Multi-Component Nickel Solid Solutions, Superalloys, 2004, 2004, p 753–758Google Scholar
  24. 24.
    T.D. Shen and C.C. Koch, The Influence of Dislocation Structure on Formation of Nanocrystals by Mechanical Attrition, Mater. Sci. Forum, 1995, 179–181, p 17–24CrossRefGoogle Scholar
  25. 25.
    L.E. Tyryshkina, G.A. Chiganova, and A.K. Abkaryan, Influence of Nanodiamonds on Microstructure of Nickel Coatings, Univ. Proc. Powder Metal. Funct. Coat., 2014, 2, p 54–58Google Scholar
  26. 26.
    A.K. Kuleshov, V.V. Uglov, V.M. Anishchik, and D.P. Rusalsky, Synthesis High Hardness Coatings from Nano-Sized Carbides of Niobium, Copper on Hard Alloy Wood-Cutting Tools, XIIth Int. Conference Interaction of Radiation with Solid, SEPT. 19–22 (Minsk, Belarus), BSU Publishing Center, 2017, 2017, p 380–382 (in Russian)Google Scholar
  27. 27.
    W. Acchara, C. Zollfrank, and P. Greil, Microstructure and Mechanical Properties of WC-Co Reinforced with NbC, Mater. Res., 2004, 7(3), p 445–450CrossRefGoogle Scholar
  28. 28.
    W. Tillmannn and S. Momeni, Tribological Development of TiCN Coatings by Adjusting the Flowing Rate of Reactive Gases, J. Phys. Chem. Solids, 2016, 90, p 45–53CrossRefGoogle Scholar

Copyright information

© ASM International 2018

Authors and Affiliations

  • V. Chayeuski
    • 1
  • V. Zhylinski
    • 1
  • O. Cernashejus
    • 2
  • N. Visniakov
    • 2
  • G. Mikalauskas
    • 2
  1. 1.Belarusian State Technological UniversityMinskBelarus
  2. 2.Vilnius Gediminas Technical UniversityVilniusLithuania

Personalised recommendations

Cite article

Buy options