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Realizing 8 cd A−1 Current Efficiency for Solution-Processed Inverted Top-Emitting Polymer Light-Emitting Diodes

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Abstract

We report indium tin oxide-free top-emitting organic light-emitting diodes (OLEDs) with solution-processed organic layers. The two electrodes are made of evaporated silver, creating a Fabry-Perot resonator. The main issue of solution-processed OLEDs is the thickness reproducibility, which greatly influences the top-emitting OLED’s performance and color because of the optical resonator. In this work, we combine simulation with experimental results to show the good thickness homogeneity of the spin-coated layers, with a 7% thickness accuracy. Similar efficiencies are obtained for top- and bottom-emitting OLEDs based on the same organic materials, 8.1 ± 0.3 cd A−1 and 8.1 ± 0.2 cd A−1, respectively, with similar Commission Internationale de l’Éclairage (CIE) coordinates. This work demonstrates the feasibility to fabricate microcavity top-emitting OLEDs by solution process and the possibility to increase the performance by using a capping layer.

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References

  1. S. Taverne, B. Caron, S. Gétin, O. Lartigue, C. Lopez, S. Meunier-Della-Gatta, V. Gorge, M. Reymermier, B. Racine, T. Maindron, and E. Quesnel, J. Appl. Phys., 2018, 123, p 023108.

    Article  Google Scholar 

  2. S.M. Jo, D.G. Yoon, R. Bail, and B.D. Chin, ECS J. Solid State Sci. Technol., 2016, 5, p R3185.

    Article  CAS  Google Scholar 

  3. S. Choi, S. Kwon, H. Kim, W. Kim, J.H. Kwon, M.S. Lim, H.S. Lee, and K.C. Choi, Sci. Rep., 2017, 7, p 1.

    Article  Google Scholar 

  4. H.K. Kim, D.G. Kim, K.S. Lee, M.S. Huh, S.H. Jeong, K.I. Kim, and T.Y. Seong, Appl. Phys. Lett., 2005, 86, p 1.

    Google Scholar 

  5. G. Parthasarathy, G. Gu, and S.R. Forrest, Adv. Mater., 1999, 11, p 907.

    Article  CAS  Google Scholar 

  6. J. Lee, C. Moon, J. Kim, J. Kim, J. Lee, C. Moon, and J. Kim, Appl. Phys. Lett., 2014, 104, p 1.

    Google Scholar 

  7. H. Jin, C. Tao, M. Velusamy, M. Aljada, Y. Zhang, M. Hambsch, P.L. Burn, and P. Meredith, Adv. Mater., 2012, 24, p 2572.

    Article  CAS  Google Scholar 

  8. Y. Peng, L. Zhang, N. Cheng, and T.L. Andrew, Energies, 2017, 10, p 707.

    Article  Google Scholar 

  9. D.T. Nguyen, S. Vedraine, L. Cattin, P. Torchio, M. Morsli, F. Flory, and J.C. Bernède, J. Appl. Phys., 2012, 112, p 063505.

    Article  Google Scholar 

  10. T. Schwab, S. Schubert, S. Hofmann, M. Fröbel, C. Fuchs, M. Thomschke, L. Müller-Meskamp, K. Leo, and M.C. Gather, Adv. Opt. Mater., 2013, 1, p 707.

    Article  Google Scholar 

  11. H. Riel, S. Karg, T. Beierlein, W. Rieß, and K. Neyts, J. Appl. Phys., 2003, 94, p 5290.

    Article  CAS  Google Scholar 

  12. S. Schubert, M. Hermenau, J. Meiss, L. Müller-Meskamp, and K. Leo, Adv. Funct. Mater., 2012, 22, p 4993.

    Article  CAS  Google Scholar 

  13. W.J. Dong, J. Ham, G.H. Jung, J.H. Son, and J.L. Lee, J. Mater. Chem. A, 2016, 4, p 4755.

    Article  CAS  Google Scholar 

  14. B. Tian, G. Williams, D. Ban, and H. Aziz, J. Appl. Phys., 2011, 110, p 104507.

    Article  Google Scholar 

  15. Y.C. Han, M.S. Lim, J.H. Park, and K.C. Choi, IEEE Electron Device Lett., 2014, 35, p 238.

    Article  Google Scholar 

  16. S. Hofmann, M. Thomschke, P. Freitag, M. Furno, B. Lüssem, and K. Leo, Appl. Phys. Lett., 2010, 97, p 253308.

    Article  Google Scholar 

  17. K.A. Knauer, E. Najafabadi, W. Haske, M.P. Gaj, K.C. Davis, C. Fuentes-hernandez, U. Carrasco, and B. Kippelen, Org. Electron., 2013, 14, p 2418.

    Article  CAS  Google Scholar 

  18. S.-R. Park, and M.C. Suh, Opt. Express, 2018, 26, p 4979.

    Article  CAS  Google Scholar 

  19. C. Fuchs, P.A. Will, M. Wieczorek, M.C. Gather, S. Hofmann, S. Reineke, K. Leo, and R. Scholz, Phys. Rev. B Condens. Matter Mater. Phys., 2015, 92, p 245306.

    Article  Google Scholar 

  20. J.-J. Lee, P. Li, H.-T. Kung, and Z.-H. Lu, J. Appl. Phys., 2019, 125, p 145501.

    Article  Google Scholar 

  21. J. Meiss, M.K. Riede, and K. Leo, Appl. Phys. Lett., 2009, 94, p 1.

    Article  Google Scholar 

  22. J. Lee, T.W. Koh, H. Cho, T. Schwab, J.H. Lee, S. Hofmann, J.I. Lee, S. Yoo, K. Leo, and M.C. Gather, J. Lumin., 2015, 162, p 180.

    Article  CAS  Google Scholar 

  23. H.J. Peng, X.L. Zhu, J.X. Sun, X.M. Yu, M. Wong, and H.S. Kwok, Appl. Phys. Lett., 2006, 88, p 1.

    Google Scholar 

  24. C. Xiang, W. Koo, F. So, H. Sasabe, and J. Kido, Light Sci. Appl., 2013, 2, p 1.

    Article  Google Scholar 

  25. L. Merklein, D. Daume, F. Braig, S. Schlisske, T. Rödlmeier, M. Mink, D. Kourkoulos, B. Ulber, M. Di Biase, K. Meerholz, G. Hernandez-Sosa, U. Lemmer, H. Sauer, E. Dörsam, P. Scharfer, and W. Schabel, Colloids Interfaces, 2019, 3, p 32.

    Article  CAS  Google Scholar 

  26. A. Sandström, and L. Edman, Energy Technol., 2015, 3, p 329.

    Article  Google Scholar 

  27. Y.M. Chien, F. Lefevre, I. Shih, and R. Izquierdo, Nanotechnology, 2010, 21, p 1.

    Google Scholar 

  28. S. Olivier, E. Ishow, S.M. Della-Gatta, and T. Maindron, Org. Electron., 2017, 49, p 24.

    Article  CAS  Google Scholar 

  29. F. Ventsch, M.C. Gather, and K. Meerholz, Org. Electron., 2010, 11, p 57.

    Article  CAS  Google Scholar 

  30. S.D. Yambem, M. Ullah, K. Tandy, P.L. Burn, and E.B. Namdas, Laser Photon. Rev., 2014, 8, p 165.

    Article  CAS  Google Scholar 

  31. L. Hou, F. Huang, W. Zeng, J. Peng, and Y. Cao, Appl. Phys. Lett., 2005, 87, p 1.

    Google Scholar 

  32. S. Hofmann, M. Thomschke, B. Lüssem, and K. Leo, Opt. Express, 2011, 19, p A1250.

    Article  CAS  Google Scholar 

  33. S. Wang, Y. Zhao, H. Lian, C. Peng, X. Yang, Y. Gao, Y. Peng, W. Lan, O.I. Elmi, D. Stiévenard, B. Wei, F. Zhu, and T. Xu, Nanophotonics, 2019, 8, p 297.

    Article  CAS  Google Scholar 

  34. M. Rawat, E. Jayaraman, S. Balasubramanian, and S.S.K. Iyer, Adv. Mater. Technol., 2019, 1900184, p 1.

    Google Scholar 

  35. B.R. Patil, S. Shanmugam, J.P. Teunissen, and Y. Galagan, Org. Electron. Phys. Mater. Appl., 2015, 21, p 40.

    CAS  Google Scholar 

  36. Y. Jiang, S. Chen, and H.S. Kwok, Dig. Tech. Pap. SID Int. Symp., 2017, 48, p 161.

    Article  CAS  Google Scholar 

  37. G. Liu, X. Zhou, and S. Chen, ACS Appl. Mater. Interfaces, 2016, 8, p 16768.

    Article  CAS  Google Scholar 

  38. S. Höfle, A. Schienle, M. Bruns, U. Lemmer, and A. Colsmann, Adv. Mater., 2014, 26, p 2750.

    Article  Google Scholar 

  39. Y. Murat, E. Langer, J.-P. Barnes, J.-Y. Laurent, G. Wantz, L. Hirsch, and T. Maindron, Org. Electron., 2017, 48, p 377.

    Article  CAS  Google Scholar 

  40. Y. Murat, G. Wantz, S. Fasquel, J.-Y. Laurent, T. Maindron, and L. Hirsch, Proc. SPIE, 2016, 9941, p 994129.

    Article  Google Scholar 

  41. Y. Zhou, C. Fuentes-Hernandez, J. Shim, J. Meyer, A.J. Giordano, H. Li, P. Winget, T. Papadopoulos, H. Cheun, J. Kim, M. Fenoll, A. Dindar, W. Haske, E. Najafabadi, T.M. Khan, H. Sojoudi, S. Barlow, S. Graham, J.-L. Brédas, S.R. Marder, A. Kahn, B. Kippelen, J.-L. Bredas, S.R. Marder, A. Kahn, B. Kippelen, J.-L. Brédas, S.R. Marder, A. Kahn, and B. Kippelen, Science, 2012, 336, p 327.

    Article  CAS  Google Scholar 

  42. Y.H. Kim, T.H. Han, H. Cho, S.Y. Min, C.L. Lee, and T.W. Lee, Adv. Funct. Mater., 2014, 24, p 3808.

    Article  CAS  Google Scholar 

  43. H. Fukagawa, K. Morii, M. Hasegawa, Y. Arimoto, T. Kamada, T. Shimizu, and T. Yamamoto, Appl. Phys. Express 082104, (2014).

  44. Y. Murat, H. Lüder, and M. Gerken, Light. Energy Environ. Congr. SSL, 1 (2018).

  45. M.S. Kwon, J. Light. Technol., 2009, 27, p 4407.

    Article  Google Scholar 

  46. O.T.A. Janssen, A.J.H. Wachters, and H.P. Urbach, Opt. Express, 2010, 18, p 24522.

    Article  CAS  Google Scholar 

  47. S. Zhang, E.R. Martins, A.G. Diyaf, J.I.B. Wilson, G.A. Turnbull, and I.D.W. Samuel, Synth. Met., 2015, 205, p 127.

    Article  CAS  Google Scholar 

  48. K.M. McPeak, S.V. Jayanti, S.J.P. Kress, S. Meyer, S. Iotti, A. Rossinelli, and D.J. Norris, ACS Photon., 2015, 2, p 326.

    Article  CAS  Google Scholar 

  49. A. Ciesielski, L. Skowronski, M. Trzcinski, and T. Szoplik, Appl. Surf. Sci., 2017, 421, p 349.

    Article  CAS  Google Scholar 

  50. L. Edman, M.A. Summers, S.K. Buratto, and A.J. Heeger, Phys. Rev. B, 2004, 70, p 1.

    Article  Google Scholar 

  51. M.S. White, D.C. Olson, S.E. Shaheen, N. Kopidakis, and D.S. Ginley, Appl. Phys. Lett., 2006, 89, p 143517.

    Article  Google Scholar 

  52. H. Ma, H.L. Yip, F. Huang, and A.K.Y. Jen, Adv. Funct. Mater., 2010, 20, p 1371.

    Article  CAS  Google Scholar 

  53. X. Yang, E. Mutlugun, C. Dang, K. Dev, Y. Gao, S.T. Tan, X.W. Sun, and H.V. Demir, ACS Nano, 2014, 8, p 8224.

    Article  CAS  Google Scholar 

  54. P. Li, L. Cai, G. Wang, D.C. Zhou, J. Xiang, Y.J. Zhang, B.F. Ding, K. Alameh, and Q.L. Song, Synth. Met., 2015, 203, p 243.

    Article  CAS  Google Scholar 

  55. S. Burns, J. Macleod, T. Trang Do, P. Sonar, and S.D. Yambem, Sci. Rep., 2017, 7, p 1.

    Article  CAS  Google Scholar 

  56. S.H. Lim and H.K. Kim, Sci. Rep., 2020, 10, p 1.

    Article  Google Scholar 

  57. D. Han and S. Yoo, Sol. Energy Mater. Sol. Cells, 2014, 128, p 41.

    Article  CAS  Google Scholar 

  58. T. Maindron, B. Aventurier, A. Ghazouani, T. Jullien, N. Rochat, J.Y. Simon, and E. Viasnoff, Thin Solid Films, 2013, 548, p 517.

    Article  CAS  Google Scholar 

  59. S. Lee, J.H. Han, S.H. Lee, G.H. Baek, and J.S. Park, Jom, 2019, 71, p 197.

    Article  Google Scholar 

  60. D.J. Semin and K.L. Rowlen, Anal. Chem., 1994, 66, p 4324.

    Article  CAS  Google Scholar 

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Acknowledgments

The authors acknowledge support by Interreg (Project Rollflex, 1_11.12.2014).

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Correspondence to Yolande Murat.

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Murat, Y., Lüder, H., Köpke, M. et al. Realizing 8 cd A−1 Current Efficiency for Solution-Processed Inverted Top-Emitting Polymer Light-Emitting Diodes. J. Electron. Mater. 50, 2556–2564 (2021). https://doi.org/10.1007/s11664-021-08776-0

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