Skip to main content
Log in

LVM Spectroscopy Investigation of Complex Defects in InAs Single Crystals Grown by the LEC Method

  • Topical Collection: 17th Conference on Defects (DRIP XVII)
  • Published:
Journal of Electronic Materials Aims and scope Submit manuscript

Abstract

N-type InAs single crystals have been studied by local vibrational mode (LVM) spectroscopy, photoluminescence spectroscopy (PL), glow discharge mass spectrometry (GDMS) and Hall effect measurement, respectively. Carbon–hydrogen complex defects CH3 and CH2 are detected in as-grown and annealed samples. After annealing, CH3 dissociates and more CH2 is formed. Results of PL and Hall measurement suggest that the complex defects of CH3 act as acceptors in n-type InAs and correlate with the change of electrical compensation after annealing. The 383 meV PL peak is attributed to CH3 defects. Based on the expected energy level of CH3 in InAs, we predicted that CH3 complex defects in InAs should introduce a resonant level 32 meV above the valence band minimum.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. L. Li, Y.C. Jiang, H. Ye, R.Q. Yang, T.D. Mishima, M.B. Santos, and M.B. Johnson, Appl. Phys. Lett. 106, 251102 (2015).

    Article  Google Scholar 

  2. H. Lotfi, L. Li, L. Lei, H. Ye, S.M. Shazzad Rassel, Y.C. Jiang, R.Q. Yang, T.D. Mishima, M.B. Santos, J.A. Gupta, and M.B. Johnson, Appl. Phys. Lett. 108, 201101 (2016).

    Article  Google Scholar 

  3. F. Wang, J. Chen, Z. Xu, Y. Zhou, and L. He, in Proceeding of SPIE (2016).

  4. R.Q. Yang, Z. Tian, Z. Cai, J.F. Klem, M.B. Johnson, and H.C. Liu, J. Appl. Phys. 107, 054514 (2010).

    Article  Google Scholar 

  5. J. Mahony and P.P. Mascher, Phys. Rev. B 55 (1996).

  6. H.A. Tahini, A. Chroneos, S.T. Murphy, U. Schwingenschlögl, and R.W. Grimes, J. Appl. Phys. 114, 063517 (2013).

    Article  Google Scholar 

  7. S. Najmi, X.K. Chen, M.L.W. Thewalt, and S.P. Watkins, J. Appl. Phys. 102, 083528 (2007).

    Article  Google Scholar 

  8. S. Najmi, X.K. Chen, A. Yang, M. Steger, M.L.W. Thewalt, and S.P. Watkins, Phys. Rev. B 74, 113202 (2006).

    Article  Google Scholar 

  9. V.J.B. Torres, J. Coutinho, and P.R. Briddon, Physica B Condens. Matter 401–402, 275 (2007).

    Article  Google Scholar 

  10. A. Mooradian and H.Y. Fan, in Proceedings of Seventh International Conference on Physics of Semiconductors (1965).

  11. H. Weijie, Z. Youwen, S. Wenrong, D. Manlong, D. Zhiyuan, and Y. Jun, J. Semicond. 31, 042001 (2010).

    Article  Google Scholar 

  12. A. Baldereschi and N.C. Lipari, Phys. Rev. B 3, 439 (1971).

    Article  Google Scholar 

  13. M. Risse and R. Vianden, J. Appl. Phys. 93, 2648 (2003).

    Article  Google Scholar 

  14. W. Ulrici, B. Clerjaud, and D. Cote, Physica B 273–274, 807 (1999).

    Article  Google Scholar 

  15. J. Edward, G. Brame, and G. Jeanette, Infrared and Raman Spectroscopy, Vol. 1 (New York, Basel: Marcel Dekker, 1977).

    Google Scholar 

  16. H.A. Szymanski, IR Theory and Practice of Infrared Spectroscopy (New York: Plenum Press, 1964).

    Book  Google Scholar 

  17. R. Bhat, P.S. Dutta, and S. Guha, J. Cryst. Growth 310, 1910 (2008).

    Article  Google Scholar 

  18. R.D. Grober, H.D. Drew, J.I. Chyi, S. Kalem, and H. Morkoç, J. Appl. Phys. 65, 4079 (1989).

    Article  Google Scholar 

  19. B. Clerjaud, D. Cote, and W. Ulrici, Physica B 273–274, 803 (1999).

    Article  Google Scholar 

  20. M.D. McCluskey, J. Appl. Phys. 87, 3593 (2000).

    Article  Google Scholar 

  21. W. Ulrici, Rep. Prog. Phys. 67, 2233 (2004).

    Article  Google Scholar 

  22. W. Ulrici, M. Czupalla, and M. Seifert, Phys. Status Solidi 210, 551 (1998).

    Article  Google Scholar 

  23. S.B. Najmi, OMVPE growth and characterization of carbon doped InAs (MM.Sc, University of Tehran, Heritage Branch, 2008).

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Guiying Shen.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Shen, G., Zhao, Y., Liu, J. et al. LVM Spectroscopy Investigation of Complex Defects in InAs Single Crystals Grown by the LEC Method. J. Electron. Mater. 47, 4998–5001 (2018). https://doi.org/10.1007/s11664-018-6228-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11664-018-6228-3

Keywords

Navigation