A Reaction Between High Mn–High Al Steel and CaO-SiO2-Type Molten Mold Flux: Reduction of Additive Oxide Components in Mold Flux by Al in Steel


The interfacial reaction between high-Mn–high-Al steel and CaO-SiO2-type mold flux was investigated, with particular emphasis on the reduction of additive oxide components by Al. Typical additive oxide components (B2O3, Na2O) could be reduced by Al, thereby losing their initial role in the flux. It is proposed to consider the chemical stability of the additive components in the flux in addition to the physico-chemical properties of the flux when developing the mold flux chemistry.

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  1. 1.

    J. Mahieu, B. C. De Cooman, and J. Maki: Metall. Mater. Trans. A, 2002, vol. 33A, pp. 2573–2580.

    CAS  Article  Google Scholar 

  2. 2.

    K. Sugimoto, J. Sakaguchi, T. Iida, and T. Kashima: ISIJ Int., 2000, vol. 40, pp. 920–926.

    CAS  Article  Google Scholar 

  3. 3.

    B.C. De Cooman, K.-G. Chin, and J. Kim: New Trends and Developments in Automotive System Engineering, InTech, Winchester, pp. 101–128, 2011.

    Google Scholar 

  4. 4.

    S.-H. Kim, H. Kim, and N. J. Kim: Nature, 2015, vol. 518, pp. 77–79.

    CAS  Article  Google Scholar 

  5. 5.

    K. Blazek, H. Yin, G. Skoczlas, M. McClymonds, and M. Frazee: in Proc. AISTech 2011, Association for Iron and Steel Technology, 2011, pp. 1577–86.

  6. 6.

    M.-S. Kim, S.-W. Lee, J.-W. Cho, M.-S. Park, H.-G. Lee, and Y.-B. Kang: Metall. Mater. Trans. B, 2013, vol. 44B, pp. 299–308.

    Article  Google Scholar 

  7. 7.

    M.-S. Kim, M.-S. Park, S.-E. Kang, J.-K. Park, and Y.-B. Kang: ISIJ Int., 2018, vol. 58, pp. 686–695.

    CAS  Article  Google Scholar 

  8. 8.

    J.-W. Cho, K. Blazek, M. Frazee, H. Yin, J. H. Park, and S.-W. Moon: ISIJ Int., 2013, vol. 53, pp. 62–70.

    Article  Google Scholar 

  9. 9.

    W. Wang, B. Lu, and D. Xiao: Metall. Mater. Trans. B, 2016, vol. 47B, pp. 384–389.

    Article  Google Scholar 

  10. 10.

    S. He, Z. Li, Z. Chen, T. Wu, and Q. Wang: Steel Res. Int., 2019, vol. 90, p. 1800424.

    Article  Google Scholar 

  11. 11.

    X. Fu, G. Wen, Q. Liu, P. Tang, J. Li, and W. Li: Steel Res. Int., 2015, vol. 86, pp. 110–120.

    CAS  Article  Google Scholar 

  12. 12.

    H. Shao, E.  Gao, W.  Wang, L.  Zhang: J. Am. Ceram. Soc., 2019, vol. 102, pp. 4440-4449.

    CAS  Article  Google Scholar 

  13. 13.

    E.  Gao, W.  Wang, L. Zhang: J. Non-Cryst. Solids, 2017, vol. 473, pp. 79-86.

    CAS  Article  Google Scholar 

  14. 14.

    Z. G. Yu, H. .Y. Leng, L. J. Wang, K. C. Chou: Ceram. Int., 2019, vol. 45, pp. 7180-7187.

    CAS  Article  Google Scholar 

  15. 15.

    J. Liao, Y. Zhang, S. Sridhar, X. Wang, and Z. Zhang: ISIJ Int., 2012, vol. 52, pp. 753–758.

    CAS  Article  Google Scholar 

  16. 16.

    C.-B. Shi, M.-D. Seo, J.-W. Cho, and S.-H. Kim: Metall. Mater. Trans. B, 2014, vol. 45B, pp. 1081–1097.

    Article  Google Scholar 

  17. 17.

    S. S. Jung and I. Sohn: Metall. Mater. Trans. B, 2012, vol. 43B, pp. 1530–1539.

    Article  Google Scholar 

  18. 18.

    M. Hayashi, T. Watanabe, H. Nakada, and K. Nagata: ISIJ Int., 2006, vol. 46, pp. 1805–1809.

    CAS  Article  Google Scholar 

  19. 19.

    B. Lu, K. Chen, W. Wang, and B. Jiang: Metall. Mater. Trans. B, 2014, vol. 45B, pp. 1496–1509.

    Article  Google Scholar 

  20. 20.

    L. Zhou, H. Li, W. Wang, D. Xiao, L. Zhang, and J. Yu: Metall. Mater. Trans. B, 2018, vol. 49B, pp. 2232–2240.

    Article  Google Scholar 

  21. 21.

    H. Kim and I. Sohn: ISIJ Int., 2011, vol. 51, pp. 1–8.

    CAS  Article  Google Scholar 

  22. 22.

    D. Xiao, W. Wang, and B. Lu: Metall. Mater. Trans. B, 2015, vol. 46B, pp. 873–881.

    Article  Google Scholar 

  23. 23.

    W. Yan, W. Chen, Y. Yang, C. Lippold, and A. Mclean: ISIJ Int., 2015, vol. 55, pp. 1000–1009.

    CAS  Article  Google Scholar 

  24. 24.

    Y.-B. Kang, M.-S. Kim, S.-W. Lee, J.-W. Cho, M.-S. Park, and H.-G. Lee: Metall. Mater. Trans. B, 2013, vol. 44B, pp. 309–316.

    Article  Google Scholar 

  25. 25.

    M.-S. Kim and Y.-B. Kang: Calphad, 2018, vol. 61, pp. 105–115.

    CAS  Article  Google Scholar 

  26. 26.

    J. Li, B. Kong, L. Jiang, D. Jia, S. Ren, J. Yang, Q. Liu, Q. Shu, and K. Chou: High Temp. Mater. Process., 2018, vol. 37, pp. 981–985.

    CAS  Article  Google Scholar 

  27. 27.

    J. Yang, J. Zhang, O. Ostrovski, C. Zhang, and D. Cai: Metall. Italiana, vol. 1, 2019, pp. 12–19.

    Google Scholar 

  28. 28.

    T.-I. Chung, J.-W. Cho, and Y.-B. Kang: Metall. Mater. Trans. B, 2016, vol. 47B, pp. 779–787.

    Article  Google Scholar 

  29. 29.

    C. W. Bale, E. Bélisle, P. Chartrand, S. A. Decterov, G. Eriksson, A. E. Gheribi, K. Hack, I. H. Jung, Y. B. Kang, J. Melançon, A. D. Pelton, S. Petersen, C. Robelin, J. Sangster, P. Spencer, and M.-A. Van Ende: Calphad, 2016, vol. 54, pp. 35–53.

    CAS  Article  Google Scholar 

  30. 30.

    W.-Y. Kim, A.D. Pelton, and S. Decterov: Int. J. Mat. Res., 2012, vol. 103, pp. 313–328.

    CAS  Article  Google Scholar 

  31. 31.

    K. C. Mills and C.-Å. Däcker: in The Casting Powders Book, Springer, Cham, pp. 19–58, 2017.

    Google Scholar 

  32. 32.

    L. T. Hoai and J. Lee: J. Mater. Sci., 2012, vol. 47, pp. 8303–8307.

    CAS  Article  Google Scholar 

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This research was financially supported by POSCO, Republic of Korea.

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Correspondence to Youn-Bae Kang.

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Manuscript submitted March 26, 2019.

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Kim, M., Park, M. & Kang, Y. A Reaction Between High Mn–High Al Steel and CaO-SiO2-Type Molten Mold Flux: Reduction of Additive Oxide Components in Mold Flux by Al in Steel. Metall Mater Trans B 50, 2077–2082 (2019). https://doi.org/10.1007/s11663-019-01658-1

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