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Metallurgical and Materials Transactions A

, Volume 49, Issue 5, pp 1851–1858 | Cite as

Experimental Investigation of Phase Equilibria in the Ho-Ti-Si Ternary System at 973 K (700 °C)

  • Feng Han
  • Yongzhong Zhan
Article
  • 74 Downloads

Abstract

Phase equilibrium relations of the Ho-Ti-Si ternary system at 973 K (700 °C) were experimentally researched by means of X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy-dispersive spectrometer (EDS). The isothermal section of the system at 973 K (700 °C) consists of 14 three-phase regions, 27 two-phase regions, and 14 single-phase regions. The phases Ti5Si3, Ti5Si4, TiSi, TiSi2, Ho5Si3, Ho5Si4, HoSi, αHoSi2-b, and βHoSi2-a are proved to exist at 973 K (700 °C). Previously reported HoTiSi and Ho2Ti3Si4 ternary compounds were confirmed to exist at this temperature. The solubility of Ho in the intermediate phases (i.e., TiSi2, TiSi, Ti5Si4, and Ti5Si3) at the Ti-Si side is extremely small. The maximum solubilities of Ti in HoSi2-b, Ho5Si4, and Ho5Si3 are confirmed to be 8.0, 7.2, and 6.0 at. pct, respectively.

Notes

Acknowledgments

This research work is supported by the National Natural Science Foundation of China (51761002), the National Key R&D Program of China (2016YFB0301400), and the Training Plan of High-Level Talents of Guangxi University (2015).

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Copyright information

© The Minerals, Metals & Materials Society and ASM International 2018

Authors and Affiliations

  1. 1.College of Resources, Environment and MaterialsGuangxi UniversityNanningPeople’s Republic of China

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