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Journal of Mountain Science

, Volume 15, Issue 2, pp 254–263 | Cite as

Spatial differentiation in stable isotope compositions of surface waters and its environmental significance in the Issyk-Kul Lake region of Central Asia

Article

Abstract

Stable isotope values of oxygen (18O) and hydrogen (2H) of surface waters were used to study the origin and environmental significances in the Issyk-Kul basin of Kyrgyzstan in Central Asia, which is the most important intermountain basin in the modern Tien Shan orogen. This study is the first analysis of hydrochemical spatial differentiation in the stable isotopes of surface waters in this watershed. 75 samples were collected from rivers, springs, lakes, rain and snow during the rainy season in July and August of 2016. Stable isotopes of 18O and 2H were studied for all samples, and cation ratios (Sr/Ca and Mg/Ca) were also determined for lake water samples. Stable isotope values from precipitation scattered around the Local Meteoric Water Line (determined from Urumqi Station of the global network of isotopes in precipitation (GNIP)), together with values of the Deuterium excess parameter (d) from 15.3‰ to 30.5‰, with an average of 19.8‰, indicating that the moisture sources are primarily from regions with low relative humidity. The δ18O and δ2H values were significantly different between the river and lake samples, indicating that regional evaporation caused the isotopic enrichment of lake water. Geospatial autocorrelation, measured by Moran’s I coefficient, indicated weak spatial autocorrelation within stable isotopes of oxygen and hydrogen in the surface waters of the studied area, which is primarily an effect of climate during the water chemistry evolution. The cation ratios Sr/Ca and Mg/Ca in lake water samples were not correlated with the concentration of total dissolved solids, but did show correlation with stable isotopic values, which is significant for paleoenvironmental reconstruction.

Keywords

Spatial differentiation Stable isotope Moisture Sources Geospatial autocorrelation Issyk-Kul Lake Central Asia 

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Notes

Acknowledgments

We thank Prof. WU Jing-lu and Dr. Abdyzhapar SALAMAT for their assistance in field work. This paper was supported by the Science and Technology Service Network Fund Project in the Chinese Academy of Sciences (TSS-2015-014-FW- 1-2), National Natural Science Foundation of China (U1603242; 41471173), West Light Foundation of the Chinese Academy of Sciences (2016-QNXZ-A- 4) and Youth Innovation Promotion Association, Chinese Academy of Sciences (2014390)

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11629_2017_4499_MOESM1_ESM.pdf (94 kb)
Spatial differentiation in stable isotope compositions of surface waters and its environmental significance in the Issyk-Kul Lake region of Central Asia

References

  1. Aizen VB, Aizen EM, Melack JM, et al. (1997) Climatic and hydrologic changes in the Tien Shan, central Asia. Journal of Climate 10: 1393–1404. https://doi.org/10.1175/1520-0442(1997)010<1393:CAHCIT>2.0.CO;2CrossRefGoogle Scholar
  2. Alymkulova B, Abuduwaili J, Issanova G, et al. (2016) Consideration of Water Uses for Its Sustainable Management, the Case of Issyk-Kul Lake, Kyrgyzstan. Water 8: 298. https://doi.org/10.3390/w8070298CrossRefGoogle Scholar
  3. Anselin L, Syabri I, Kho Y (2006) GeoDa: An Introduction to Spatial Data Analysis. Geographical Analysis 38: 5–22. https://doi.org/10.1111/j.0016-7363.2005.00671.xCrossRefGoogle Scholar
  4. Ayana EK, Ceccato P, Fisher JR, et al. (2016) Examining the relationship between environmental factors and conflict in pastoralist areas of East Africa. Science of The Total Environment 557: 601–611. https://doi.org/10.1016/j. scitotenv.2016.03.102CrossRefGoogle Scholar
  5. Bai J, Chen X, Li J, Y et al. (2011) Changes in the area of inland lakes in arid regions of central Asia during the past 30 years. Environmental monitoring and assessment 178: 247–256. https://doi.org/10.1007/s10661-010-1686-yCrossRefGoogle Scholar
  6. Beniston M, Stoffel M (2014) Assessing the impacts of climatic change on mountain water resources. Science of the Total Environment 493: 1129–1137. https://doi.org/10.1016/j. scitotenv.2013.11.122CrossRefGoogle Scholar
  7. Bershaw J, Saylor JE, Garzione CN, et al. (2016). Stable isotope variations (δ18O and δD) in modern waters across the Andean Plateau. Geochimica et Cosmochimica Acta 194: 310–324. https://doi.org/10.1016/j.gca.2016.08.011CrossRefGoogle Scholar
  8. Cao L, Caldeira K, Jain AK (2007) Effects of carbon dioxide and climate change on ocean acidification and carbonate mineral saturation. Geophysical Research Letters 34: L05607. https://doi.org/10.1029/2006GL028605Google Scholar
  9. Craig H (1961) Isotopic variations in meteoric waters. Science 133: 1702–1703. https://doi.org/10.1126/science.133.3465. 1702CrossRefGoogle Scholar
  10. Dansgaard W (1964) Stable isotopes in precipitation. Tellus 16: 436–468. https://doi.org/10.1111/j.2153-3490.1964.tb00181.xCrossRefGoogle Scholar
  11. De Grave J, Glorie S, Buslov MM, et al. (2013) Thermo-tectonic history of the Issyk-Kul basement (Kyrgyz Northern Tien Shan, Central Asia). Gondwana Research 23: 998–1020. https://doi.org/10.1016/j.gr.2012.06.014CrossRefGoogle Scholar
  12. Dodd J, Crisp E (1982) Non-linear variation with salinity of Sr/Ca and Mg/Ca ratios in water and aragonitic bivalve shells and implications for paleosalinity studies. Palaeogeography, Palaeoclimatology, Palaeoecology 38: 45–56. https://doi.org/10.1016/0031-0182(82)90063-3CrossRefGoogle Scholar
  13. Droogers P, Allen RG (2002) Estimating Reference Evapotranspiration Under Inaccurate Data Conditions. Irrigation and Drainage Systems 16: 33–45. https://doi.org/10.1023/a:1015508322413CrossRefGoogle Scholar
  14. Ferronskii V et al. (2003) Variations in the hydrological regime of Kara-Bogaz-Gol Gulf, Lake Issyk-Kul, and the Aral Sea assessed based on data of bottom sediment studies. Water Resources 30: 252–259. https://doi.org/10.1023/A:1023826011601CrossRefGoogle Scholar
  15. Froehlich K, Kralik M, Papesch W, et al. (2008) Deuterium excess in precipitation of Alpine regions–moisture recycling. Isotopes in Environmental and Health Studies 44: 61–70 https://doi.org/10.1080/10256010801887208CrossRefGoogle Scholar
  16. Gat JR (1996) Oxygen and hydrogen isotopes in the hydrologic cycle. Annual Review of Earth and Planetary Sciences 24:225–262. https://doi.org/10.1146/annurev.earth.24.1.225CrossRefGoogle Scholar
  17. Getis A, Ord JK (1992) The Analysis of Spatial Association by Use of Distance Statistics. Geographical Analysis 24: 189–206. https://doi.org/10.1111/j.1538-4632.1992.tb00261.xCrossRefGoogle Scholar
  18. Giralt S, Julià R, Klerkx J, et al. (2004) 1,000-year environmental history of Lake Issyk-Kul. In: Nihoul JCJ, Zavialov PO, Micklin PP (eds.), Dying and Dead Seas Climatic Versus Anthropic Causes. Springer, Netherlands. pp 253–285Google Scholar
  19. Gosling SN, Arnell NW (2016) A global assessment of the impact of climate change on water scarcity. Climatic Change 134: 371–385. https://doi.org/10.1007/s10584-013-0853-xCrossRefGoogle Scholar
  20. Grosjean M et al. (2001) A 22,000 14C year BP sediment and pollen record of climate change from Laguna Miscanti (23S), northern Chile. Global and Planetary Change 28: 35–51. https://doi.org/10.1016/S0921-8181(00)00063-1CrossRefGoogle Scholar
  21. Grosswald M, Kuhle M, Fastook J (1994) Würm glaciation of Lake Issyk-Kul area, Tian Shan Mts.: a case study in glacial history of Central Asia. GeoJournal 33: 273–310. https://doi.org/10.1007/BF00812878CrossRefGoogle Scholar
  22. Hargreaves GH (1994) Defining and using reference evapotranspiration. Journal of Irrigation and Drainage Engineering 120: 1132–1139. https://doi.org/10.1061/(ASCE)0733-9437(1994)120:6(1132)CrossRefGoogle Scholar
  23. Hargreaves GL, Hargreaves GH, Riley JP (1985) Agricultural benefits for Senegal River basin. Journal of irrigation and Drainage Engineering 111: 113–124. https://doi.org/10.1061/(ASCE)0733-9437(1985)111:2(113)CrossRefGoogle Scholar
  24. Hofer M et al. (2002) Rapid deep-water renewal in Lake Issyk-Kul (Kyrgyzstan) indicated by transient tracers. Limnology and Oceanography 47: 1210–1216. https://doi.org/10.4319/lo. 2002.47.4.1210CrossRefGoogle Scholar
  25. Horita J, Wesolowski DJ (1994) Liquid-vapor fractionation of oxygen and hydrogen isotopes of water from the freezing to the critical temperature. Geochimica et Cosmochimica Acta 58: 3425–3437. https://doi.org/10.1016/0016-7037(94) 90096-5CrossRefGoogle Scholar
  26. Horne D, Holmes J, Rodriguez-Lazaro J, et al. (2012) Ostracoda as proxies for Quaternary climate change. Elsevier, Amsterdam.Google Scholar
  27. Huo Z, Dai X, Feng S, et al. (2013) Effect of climate change on reference evapotranspiration and aridity index in arid region of China. Journal of Hydrology 492: 24–34. https://doi.org/10.1016/j.jhydrol.2013.04.011CrossRefGoogle Scholar
  28. IAEA (2014) IAEA/GNIP precipitation sampling guide (V2.02 September 2014). http://www-naweb.iaea.org/napc/ih/documents/other/gnip_manual_v2.02_en_hq.pdf (Accessed on 7 July 2017)Google Scholar
  29. Jin L, Chen F, Morrill C, et al. (2012) Causes of early Holocene desertification in arid central Asia. Clim Dyn 38: 1577–1591. https://doi.org/10.1007/s00382-011-1086-1CrossRefGoogle Scholar
  30. Kebede S, Travi Y, Rozanski K. (2009). The δ18O and δ2H enrichment of Ethiopian lakes. Journal of Hydrology 365: 173–182. https://doi.org/10.1016/j.jhydrol.2008.11.027CrossRefGoogle Scholar
  31. Klerx J, Imanackunov B (2002) Lake Issyk-Kul: its natural environment. Springer, Netherlands.CrossRefGoogle Scholar
  32. Koster RD, de Valpine DP, Jouzel J (1993) Continental water recycling and H218O concentrations. Geophysical Research Letters 20: 2215–2218. https://doi.org/10.1029/93GL01781CrossRefGoogle Scholar
  33. Lyons W, Welch K, Bonzongo J-C, et al. (2001) A preliminary assessment of the geochemical dynamics of Issyk-Kul Lake, Kirghizstan. Limnology and oceanography 46: 713–718. https://doi.org/10.4319/lo.2001.46.3.0713CrossRefGoogle Scholar
  34. Ma L, Wu J, Abuduwaili J (2016) Hydrochemical and isotopic characters of surface water in agricultural oases of the Tianshan Mountains, Northwest China. Arid Land Research and Management 30: 37–48. https://doi.org/10.1080/15324982.2015.1056326CrossRefGoogle Scholar
  35. Mayr C, Lücke A, Stichler W, et al. (2007). Precipitation origin and evaporation of lakes in semi-arid Patagonia (Argentina) inferred from stable isotopes (δ18O, δ2H). Journal of Hydrology 334: 53–63. https://doi.org/10.1016/j.jhydrol. 2006.09.025CrossRefGoogle Scholar
  36. Qian H, Wu J, Zhou Y, et al. (2014). Stable oxygen and hydrogen isotopes as indicators of lake water recharge and evaporation in the lakes of the Yinchuan Plain. Hydrological processes 28:3554–3562. https://doi.org/10.1002/hyp.9915CrossRefGoogle Scholar
  37. Ricketts RD, Johnson TC, Brown ET, et al. (2001) The Holocene paleolimnology of Lake Issyk-Kul, Kyrgyzstan: Trace element and stable isotope composition of ostracodes. Palaeogeography, Palaeoclimatology, Palaeoecology 176: 207–227. https://doi.org/10.1016/S0031-0182(01)00339-XCrossRefGoogle Scholar
  38. Romanovsky VV, Tashbaeva S, Crétaux J-F, et al. (2013) The closed Lake Issyk-Kul as an indicator of global warming in Tien-Shan. Natural Science 5: 32106. https://doi.org/10.4236/ns.2013.55076CrossRefGoogle Scholar
  39. Sahin S (2012) An aridity index defined by precipitation and specific humidity. Journal of Hydrology 444: 199–208. https://doi.org/10.1016/j.jhydrol.2012.04.019CrossRefGoogle Scholar
  40. Salamat Au, Abuduwaili J, Shaidyldaeva N (2015) Impact of climate change on water level fluctuation of Issyk-Kul Lake. Arabian Journal of Geosciences 8: 5361–5371. https://doi. org/10.1007/s12517-014-1516-6CrossRefGoogle Scholar
  41. Salvati L, Sateriano A, Zitti M (2013) Long-term land cover changes and climate variations–A country-scale approach for a new policy target. Land Use Policy 30: 401–407. https://doi. org/10.1016/j.landusepol.2012.04.012CrossRefGoogle Scholar
  42. Savvaitova K, Petr T (1999) Fish and fisheries in Lake Issyk-Kul (Tien Shan), River Chu and Pamir Lakes. Fish and Fisheries at Higher Altitudes: Asia, FAO Fisheries Technical Paper 385: 168–187.Google Scholar
  43. Shabunin GD, Shabunin AG (2002) Climate and physical properties of water in Lake Issyk-Kul. In: Klerkx J, Imanackunov B (eds.), Lake Issyk-Kul: Its Natural Environment, vol 13. NATO Science Series IV Earth and Environmental Sciences. pp 3–11.Google Scholar
  44. Stefánsson A, Gíslason SR, Arnórsson S (2001) Dissolution of primary minerals in natural waters: II. Mineral saturation state. Chemical Geology 172: 251–276. https://doi.org/10.1016/S0009-2541(00)00262-XCrossRefGoogle Scholar
  45. Taylor S, Feng X, Kirchner JW, et al. (2001). Isotopic evolution of a seasonal snowpack and its melt. Water Resources Research 37: 759–769. https://doi.org/10.1029/2000WR900341CrossRefGoogle Scholar
  46. Vollmer MK, Weiss RF, Williams RT, et al. (2002) Physical and chemical properties of the waters of saline lakes and their importance for deep-water renewal: Lake Issyk-Kul, Kyrgyzstan. Geochimica Et Cosmochimica Acta 66: 4235–4246. https://doi.org/10.1016/s0016-7037(02)01052-9CrossRefGoogle Scholar
  47. Vörösmarty CJ, Green P, Salisbury J, et al. (2000) Global water resources: vulnerability from climate change and population growth. Science 289: 284–288. https://doi.org/10.1126/science.289.5477.284CrossRefGoogle Scholar
  48. White CJ, Tanton TW, Rycroft DW (2014) The impact of climate change on the water resources of the Amu Darya basin in central Asia. Water Resources Management 28: 5267–5281. https://doi.org/10.1007/s11269-014-0716-xCrossRefGoogle Scholar
  49. Williams M, Konovalov V (2008) Central Asia temperature and precipitation data, 1879–2003. http://nsidc.org/data/docs/noaa/g02174_central_asia_data (Accessed on 26 April 2017)Google Scholar
  50. Williams W (1966) The relationship between salinity and Sr/Ca in the lake water. Australian Journal of Marine and Freshwater Research 17:169–176.CrossRefGoogle Scholar
  51. Xu Q, Hoke GD, Liu-Zeng J, et al. (2014) Stable isotopes of surface water across the Longmenshan margin of the eastern Tibetan Plateau. Geochemistry, Geophysics, Geosystems 15: 3416–3429. https://doi.org/10.1002/2014GC005252CrossRefGoogle Scholar
  52. Zhang E, Shen J, Wang S, et al. (2004) Quantitative reconstruction of the paleosalinity at Qinghai Lake in the past 900 years. Chinese Science Bulletin 49: 730–734. https://doi.org/10.1007/BF03184273CrossRefGoogle Scholar
  53. Zhou H, Yang X, Zhao S, et al. (2016) Spatial epidemiology and risk factors of pulmonary tuberculosis morbidity in Wenchuan earthquake-stricken area. Journal of Evidence-Based Medicine 9: 69–76. https://doi.org/10.1111/jebm.12196CrossRefGoogle Scholar

Copyright information

© Science Press, Institute of Mountain Hazards and Environment, CAS and Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  1. 1.State Key Laboratory of Desert and Oasis Ecology, Xinjiang Institute of Ecology and GeographyChinese Academy of SciencesUrumqiChina
  2. 2.CAS Research Center for Ecology and Environment of Central AsiaUrumqiChina

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