Skip to main content
Log in

Bipolar Resistive Switching Effect in BiFeO3/Nb:SrTiO3 Heterostructure by RF Sputtering at Room Temperature

  • Advanced Materials
  • Published:
Journal of Wuhan University of Technology-Mater. Sci. Ed. Aims and scope Submit manuscript

Abstract

The (001) oriented BiFeO3 thin film was deposited on the Nb: SrTiO3 substrate by radio frequency magnetron sputtering technology, and the bipolar resistive switching effect was observed in the BiFeO3/Nb: SrTiO3 heterostructure. The results showed that the ratio between the high resistance and low resistance was more than two orders at a reading pulse of -0.5 V and it exhibited excellent retention over 3600 s. The current density-voltage characteristic was dominated by the space-charge-limited conduction. The resistive switching effect of the structure was attributed to the trapping/detrapping of the charge carriers.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Waser R, Dittmann R, Staikov G,et al. Redox–Based Resistive Switching Memories–Nanoionic Mechanisms, Prospects, and Challenges[J]. Adv. Mater., 2009, 21: 2632–21 2632

    Article  Google Scholar 

  2. Wang L, Yang CH, and Wen J. Physical Principles and Current Status of Emerging Non–Volatile Solid State Memories[J]. Electron. Mater. Lett,. 2015, 11: 4 505–4 543

    Article  Google Scholar 

  3. Xia QF, Robinett W, Cumbie MW, et al. Memristor–CMOS Hybrid Integrated Circuits for Reconfigurable Logic[J]. Nano Lett., 2009, 9: 10 3640–10 3640

    Google Scholar 

  4. Hill NA. Why Are There So Few Magnetic Ferroelectrics[J]. J. Phys. Chem. B, 2000, 31: 49 6694–49 6709

    Google Scholar 

  5. Yang CH, Seidel J, Kim S Y, et al. Electric Modulation of Conduction in Multiferroic Ca–doped BiFeO3 Films[J]. Nature Materials, 2009, 8: 6 485–6 493

    Google Scholar 

  6. Wu SX, Ren LZ, Yu FM, et al. Colossal Resistance Switching in Pt/BiFeO3/Nb:SrTiO3 Memristor[J]. Appl. Phys. A, 2014, 116: 4 1741–4 1745

    Google Scholar 

  7. Hu ZQ, Li Q, Li MY, et al. Ferroelectric Memristor based on Pt/Bi–FeO3/Nb–Doped SrTiO3 Heterostructure[J]. Appl. Phys. Lett., 2013, 102: 10 076502–10 493

    Google Scholar 

  8. Zhu XJ, Zhu F, Li M, et al. Microstructure Dependence of Leakage and Resistive Switching Behaviours in Ce–Doped BiFeO3 Thin Films[J]. J. Phys. D: Appl. Phys. 2011, 44: 415104–415104

    Article  Google Scholar 

  9. Chen S W, Wu JM. Unipolar Resistive Switching Behavior of BiFeO3 Thin Films Prepared by Chemical Solution Deposition[J]. Thin Solid Films, 2010, 519: 1 499–1504

    Google Scholar 

  10. Tang XW, Zhu XB, Dai JM, et al. Evolution of the Resistive Switching in Chemical Solution Deposited–Derived BiFeO3 Thin Films with Dwell Time and Annealing Temperature[J]. J. Appl. Phys., 2013, 113: 4 403–4 403

    Google Scholar 

  11. Luo JM, Lin SP, Zheng Y, et al. Nonpolar Resistive Switching in Mn–Doped BiFeO3 Thin Films by Chemical Solution Deposition[J]. Appl. Phys. Lett., 2012, 101: 6 2032–6 2032

    Google Scholar 

  12. Zhang LX, Chen J, Cao JL, et al. Large Resistive Switching and Switchable Photovoltaic Response in Ferroelectric Doped Bi–FeO3–Based Thin Films by Chemical Solution Deposition[J]. J. Mater. Chem. C, 2015, 3: 18 4706–18 4712

    Google Scholar 

  13. Katiyar RK, Sharma Y, Barrionuevo Diestra DG, et al. Unipolar Resistive Switching in Planar Pt/BiFeO3/Pt Structure[J]. AIP Advances, 2015, 5: 3 103509–6350

    Article  Google Scholar 

  14. Lee D, Baek SH, Kim TH, et al. Polarity Control of Carrier Injection at Ferroelectric/Metal Interfaces for Electrically Switchable Diode and Photovoltaic Effect[J]. Phys. Rev. B, 2011, 84: 125305–125305

    Article  Google Scholar 

  15. Deng HL, Zhang M, Li T, et al. Magnetization and Resistance Switchings Induced by Electric Field in Epitaxial Mn:ZnO/BiFeO3 Multiferroic Heterostructures at Room Temperature[J]. ACS Appl. Mater. Interfaces, 2016, 8: 6–6

    Article  Google Scholar 

  16. Lee JH, Jeon JH, Yoon C, et al. Intrinsic Defect–Mediated Conduction and Resistive Switching in Multiferroic BiFeO3 Thin Films Epitaxially Grown on SrRuO3 Bottom Electrodes[J]. Appl. Phys. Lett., 2016, 108: 11 1062–11 1087

    Google Scholar 

  17. Jiménez D, Miranda E, Tsurumaki–Fukuchi A, et al. Multilevel Recording in Bi–Deficient Pt/BFO/SRO Heterostructures Based on Ferroelectric Resistive Switching Targeting High–Density Information Storage in Nonvolatile Memories[J]. Appl. Phys. Lett., 2013, 103: 26 2161–26 4597

    Article  Google Scholar 

  18. Jiang AQ, Wang C, Jin KJ, et al. A Resistive Memory in Semiconducting BiFeO3 Thin–Film Capacitors[J]. Adv. Mater. 2015, 23: 10 1277–10 1281

    Google Scholar 

  19. Shang DS, Wang Q, Chen LD, et al. Effect of Carrier Trapping on the Hysteretic Current–Voltage Characteristics in Ag/La0.7Ca0.3MnO3/Pt Heterostructure[J]. Phys. Rev. B, 2006, 73: 245427–245427

    Article  Google Scholar 

  20. Gao CX, Lv FZ, Zhang P, et al. Tri–State Bipolar Resistive Switching Behavior in a Hydrothermally Prepared Epitaxial BiFeO3 Film[J]. J. Alloys Compd. 2015, 649: 694–698

    Article  Google Scholar 

  21. Lee JH, Jeon JH, Yoon C, et al. Intrinsic Defect–Mediated Conduction and Resistive Switching in Multiferroic BiFeO3 Thin Films Epitaxially Grown on SrRuO3 Bottom Electrodes[J]. Appl. Phys. Lett., 2016, 108: 11 1062–11 1087

    Google Scholar 

  22. Yang H, Luo HM, Wang H, et al. Rectifying Current–Voltage Characteristics of BiFeO3/Nb–Doped SrTiO3 Heterojunction[J]. Appl. Phys. Lett., 2008, 92: 10 124–10 127

    Google Scholar 

  23. Qu TL, Zhao YG, Xie D, et al. Resistance Switching and White–Light Photovoltaic Effects in BiFeO3/Nb–SrTiO3 Heterojunctions[J]. Appl. Phys. Lett., 2011, 98: 17 1719–17 1719

    Google Scholar 

  24. Thakre A, Borkar H, Singha B P Kumar. A Electroforming Free High Resistance Resistive Switching of Graphene Oxide Modified Polar–PVDF[J]. RSC Adv., 2015, 5: 71 57406–71 57413

    Article  Google Scholar 

  25. Ni MC, Guo SM, Tian HF, et al. Electroforming Free High Resistance Resistive Switching of Graphene Oxide Modified Polar–PVDF[J]. Appl. Phys. Lett., 2007, 91: 183502–183502

    Article  Google Scholar 

  26. Chang ST, Lee JY. Electrical Conduction Mechanism in High–Dielectric–Constant (Ba–0.5,Sr–0.5)TiO3 Thin Films[J]. Appl. Phys. Lett., 2002, 80: 4 655–4 657

    Google Scholar 

  27. Zhang HJ, Zhang XP, Shi JP, Effect of Oxygen Content and Superconductivity on the Nonvolatile Resistive Switching in YBa2 Cu3 O6+x/Nb–Doped SrTiO3 Heterojunction[J]. Appl. Phys. Lett., 2009, 94: 9 833

    Google Scholar 

  28. Stolichnov I, Tagantsev A. Space–Charge Influenced–Injection Model for Conduction in Pb (Zrx Ti1−x)O3 Thin Films[J]. J. Appl. Phy., 1998, 84: 6 3216–6 3225

    Article  Google Scholar 

  29. Tang XG, Wang J, Zhang YW, et al. Leakage Current and Relaxation Characteristics of Highly (111)–Oriented Lead Calcium Titanate Thin Films[J]. J. Appl. Phys., 2003, 94: 8 5163–8 5166

    Google Scholar 

  30. Yan ZB, Liu JM. Coexistence of High Performance Resistance and Capacitance Memory Based on Multilayered Metal–Oxide Structures[J]. Sci. Rep., 2013, 3: 8 2482–8 2482

    Google Scholar 

  31. Deng HL, Zhang M, Wei JZ, et al. Nonvolatile Bipolar Resistive Switching in Ba–Doped BiFeO3 Thin Films[J]. Solid–State Electronics, 2015, 109: 72–75

    Article  Google Scholar 

  32. Liu WW, Jia CH, Zhang Q, et al. Mechanism of Rectification and Two–Type Bipolar Resistance Switching Behaviors of Pt/Pb(Zr0.52Ti0.48)O3 /Nb:SrTiO3[J]. J. Phys. D: Appl. Phys,. 2015, 48: 485102–485102

    Article  Google Scholar 

  33. Miranda E, Jimenez D, Tsurumaki–Fukuchi A, et al. Modeling of Hysteretic Schottky Diode–Like Conduction in Pt/BiFeO3/SrRuO3 Switches[J]. Appl. Phys. Lett., 2014, 105: 8 125305–8 1281

    Article  Google Scholar 

  34. Li H, Jin KX, Yang SH, et al. Ultraviolet Photovoltaic Effect in Bi–FeO3/Nb–SrTiO3 Heterostructure[J]. J. Appl. Phys., 2012, 112: 8 392–8 392

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Hui Zhu  (朱慧).

Additional information

Funded by the National Natural Science Foundation of China( Nos. 61201046 and 61306057), the Beijing Natural Science Foundation of China(Nos. 4162013, 2132023 and 4164082), the Beijing Postdoctoral Research Foundation(No. 2015ZZ-33), the Scientific Research Project of Beijing Educational Committee(No. KM201610005005), and the Scientific Research Foundation for Returned Overseas Chinese Scholars, State Education Ministry

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Wang, P., Zhu, H., Zhang, Y. et al. Bipolar Resistive Switching Effect in BiFeO3/Nb:SrTiO3 Heterostructure by RF Sputtering at Room Temperature. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 33, 1360–1364 (2018). https://doi.org/10.1007/s11595-018-1975-9

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11595-018-1975-9

Key words

Navigation