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Preparation of Nano-composites Membranes with Graphic Oxides and Polylactic Acid

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Abstract

Organic polymer materials were used as a layer of adhesive into the graphene sheet between the layers to enhance the interaction force between the nano-structure to achieve excellent mechanical properties and barrier properties. PLA with good flowability and easy processing was selected. The mechanical properties and barrier properties of the graphene-based composites were improved by the use of PLA for good flowability, making it easy to enter the GO layer as a binder. Three methods of preparation of GO / PLA homogeneous composite membranes were designed by vacuum filtration. The experimental results show that the injection of PLA as a molecular binder into the GO layer can effectively mimic the nano-structure, and enhance the intergranular force of the graphene molecules and the compatibility with the polymer matrix.

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References

  1. Gao W, Singh N, Song L, et al. Direct Laser Writing of Micro-supercapacitors on Hydrated Graphite Oxide Films[J]. Nature Nanotechnology, 2011, 6(8): 496–500

    Article  Google Scholar 

  2. Cao Y, Feng J, Wu P. Preparation of Organically Dispersible Graphene Nanosheet Powders through a Lyophilization Method and Their Poly (lactic acid) Composites[J]. Carbon, 2010, 48(13): 3834–3839

    Article  Google Scholar 

  3. Xu Z, Gao C. Graphene Chiral Liquid Crystals and Macroscopic Assembled Fibres[J]. Nature Communications, 2011, 2: 571

    Article  Google Scholar 

  4. Paci JT, Belytschko T, Schatz GC. Computational Studies of the Structure, Behavior Upon Heating, and Mechanical Properties of Graphite Oxide[J]. The Journal of Physical Chemistry C, 2007, 111(49): 18099–18111

    Article  Google Scholar 

  5. Suk JW, Piner RD, An J, et al. Mechanical Properties of Monolayer Graphene Oxide[J]. ACS Nano, 2010, 4(11): 6557–6564

    Article  Google Scholar 

  6. Medhekar NV, Ramasubramaniam A, Ruoff RS, et al. Hydrogen Bond Networks in Graphene Oxide Composite Paper: Structure and Mechanical Properties[J]. Acs Nano, 2010, 4(4): 2300–2306.

    Article  Google Scholar 

  7. An Z, Compton OC, Putz KW, et al. Bio-inspired Borate Cross-linking in Ultra-stiff Graphene Oxide Thin Films[J]. Advanced Materials, 2011, 23(33): 3842–3846

    Google Scholar 

  8. Gao Y, Liu LQ, Zu SZ, et al. The Effect of Interlayer Adhesion on the Mechanical Behaviors of Macroscopic Graphene Oxide Papers[J]. ACS nano, 2011, 5(3): 2134–2141

    Article  Google Scholar 

  9. Park S, Lee KS, Bozoklu G, et al. Graphene Oxide Papers Modified by Divalent Ions-enhancing Mechanical Properties via Chemical Cross-linking[J]. ACS Nano, 2008, 2(3): 572–578

    Article  Google Scholar 

  10. Xu Z, Sun H, Zhao X, et al. Ultrastrong Fibers Assembled from Giant Graphene Oxide Sheets[J]. Advanced Materials, 2013, 25(2): 188–193

    Article  Google Scholar 

  11. Zhu J, Zhu L, Lu Z, et al. Selectively Expanding Graphene Oxide Paper for Creating Multifunctional Carbon Materials[J]. The Journal of Physical Chemistry C, 2012, 116(43): 23075–23082

    Article  Google Scholar 

  12. Dikin DA, Stankovich S, Zimney EJ, et al. Preparation and Characterization of Graphene Oxide Paper[J]. Nature, 2007, 448(7152): 457–460

    Article  Google Scholar 

  13. Chen C, Yang QH, Yang Y, et al. Self-Assembled Free-Standing Graphite Oxide Membrane[J]. Advanced Materials, 2009, 21(29): 3007–3011

    Article  Google Scholar 

  14. Chen H, Müller MB, Gilmore K J, et al. Mechanically Strong, Electrically Conductive, and Biocompatible Graphene Paper[J]. Advanced Materials, 2008, 20(18): 3557–3561

    Article  Google Scholar 

  15. Zhu Y, Murali S, Cai W, et al. Graphene and Graphene Oxide: Synthesis, Properties, and Applications[J]. Advanced Materials, 2010, 22(35): 3906–3924

    Article  Google Scholar 

  16. Compton OC, Cranford SW, Putz KW, et al. Tuning the Mechanical Properties of Graphene Oxide Paper and Its Associated Polymer Nanocomposites by Controlling Cooperative Intersheet Hydrogen Bonding[J]. ACS nano, 2012, 6(3): 2008–2019

    Article  Google Scholar 

  17. Lee H, Dellatore SM, Miller WM, et al. Mussel-inspired Surface Chemistry for Multifunctional Coatings[J]. Science, 2007, 318(5849): 426–430

    Article  Google Scholar 

  18. Wang Q, Mynar JL, Yoshida M, et al. High-water-content Mouldable Hydrogels by Mixing Clay and a Dendritic Molecular Binder[J]. Nature, 2010, 463(7279): 339–343

    Article  Google Scholar 

  19. Mukherjee R, Thomas AV, Krishnamurthy A, et al. Photothermally Reduced Graphene as High-power Anodes for Lithium-ion Batteries[J]. Acs Nano, 2012, 6(9): 7867–7878

    Article  Google Scholar 

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Correspondence to Zongyan Wang  (王宗彦).

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Funded by the National Natural Science Foundation of China (No. 51675491)

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He, Y., Wang, Z. Preparation of Nano-composites Membranes with Graphic Oxides and Polylactic Acid. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 33, 995–998 (2018). https://doi.org/10.1007/s11595-018-1924-7

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  • DOI: https://doi.org/10.1007/s11595-018-1924-7

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