Skip to main content
Log in

Electroless Ni-P deposition on magnesium alloy from a sulfate bath

  • Published:
Journal of Wuhan University of Technology-Mater. Sci. Ed. Aims and scope Submit manuscript

Abstract

A technology for electroless Ni-P deposition on AZ91D from a low cost plating bath containing sulfate nickel was proposed. The seal pretreatment was employed before the electroless Ni-P deposition for the sake of occluding the micro holes of the cast magnesium alloy and interdicting the bubble formation in the Ni-P coating during plating process. And pickling pretreatment can provide a better adhesion between the Ni-P deposition and AZ91D substrate. The deposition speed of the Ni-P coating is 29 μm/h. The technology is employed to AZ91D magnesium alloy automobile parts and can provide high hardness and high wear-resistant. The weight losses of Ni-P plated and heat-treated Ni-P plated magnesium alloy specimen are only about 1/6 and 1/10 that of bare magnesium alloy specimen after 10 min abrasion wear, respectively. The hardness of the electroless Ni-P plated brake pedal support brackets is 674.1 VHN and 935.7 VHN after 2 hours heat treatments at 180 °. The adhesion of Ni-P coatings on magnesium alloy substrates meets the demands of ISO Standards 2819. The technology is environment friendly and cannot cause hazard to environment because of absence of chromate in the whole process.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. S Ignat, P Sallamand, D Grevey, et al. Magnesium Alloys Laser (Nd:YAG) Cladding and Alloying with Side Injection of Aluminum Powder[J]. Appl. Surf. Sci., 2004, 225(1–4): 124–134

    Article  CAS  Google Scholar 

  2. Z G Chen, Z Q Zhang, H K Yi. Effects of Trace Silver and Magnesium on the Microstructure and Mechanical Properties of Al-Cu-Li Alloys[J]. J. Wuhan University of Technology-Mater. Sci. Ed., 2005, 20(1): 9–12

    CAS  Google Scholar 

  3. L N Hu, X F Bian, Y F Duan. Hydrogen Content and Porosity Behavior of Hypereutectic Aluminum-silicon Alloy with Phosphorus[J]. J. Wuhan University of Technology-Mater. Sci. Ed., 2004, 19(4): 65–68

    CAS  Google Scholar 

  4. H Watari, K Davey, M T Rasgado, et al. Semi-solid Manufacturing Process of Magnesium Alloys by Twinroll Casting[J]. J. Mater. Process. Technol., 2004, 155–156: 1 662–1 667

    Google Scholar 

  5. Q Shen, L M Zhang, H Tan, et al. Preparation of Mg-Ti System Alloy and FGM with Density Gradient by Spark Plasma Sintering Technique[J]. J. Wuhan University of Technology-Mater. Sci. Ed., 2004, 19(1): 58–60

    Article  CAS  Google Scholar 

  6. Z H Xiao, J R Luo, S S Wu, et al. Performance of Semi-solid Slurry Produced by Twin-screw Stirring Mixer and Rheodiecasting Process of AZ91D Alloy[J]. J. Wuhan University of Technology-Mater. Sci. Ed., 2004, 19(3): 81–85

    CAS  Google Scholar 

  7. D Hawke, D L Albright. A Phosphate-Permanganate Conversion Coating for Magnesium[J]. Met. Finish., 1995, 93(10): 34–38

    Article  CAS  Google Scholar 

  8. H Umehara, M Takaya, S Terauchi. Chrome-free Surface Treatments for Magnesium Alloy[J]. Surf. Coat. Technol., 2003, 169–170: 666–669

    Article  CAS  Google Scholar 

  9. Z C Kwo, S S Teng. Conversion-coating Treatment for Magnesium Alloys by a Permanganate-Phosphate Solution[J]. Mater. Chem. Phys., 2003, 80(1): 191–200

    Article  CAS  Google Scholar 

  10. E H Han, W Q Zhou, D Y Shan, et al. Corrosion and Protection of Magnesium Alloy AZ31D by a New Conversion Coating[J]. Mater. Sci. Forum, 2003, 419(4): 879–883

    Article  Google Scholar 

  11. L Kouisni, M Azzi, M Zertoubi. Phosphate Coatings on Magnesium Alloy AM60 Part 1: Study of the Formation and the Growth of Zinc Phosphate Films[J]. Surf. Coat. Technol., 2004, 185(1): 58–67

    Article  CAS  Google Scholar 

  12. L Kouisni, M Azzi, F Dalard, et al. Phosphate Coatings on Magnesium Alloy AM60 Part 2: Electrochemical Behavior in Borate Buffer Solution[J]. Surf. Coat. Technol., 2005, 192(2–3): 239–246

    CAS  Google Scholar 

  13. L Y Niu, Z H Jiang, G Y Li, et al. A Study and App1ication of Zinc Phosphate Coating on AZ91D Magnesium Alloy[J]. Surf. Coat. Technol., 2006,200(9):3 021–3 026

    Article  CAS  Google Scholar 

  14. C D Gu, J S Lian, G Y Li, et al. Electroless Ni-P Plating on AZ91D Magnesium Alloy from a Sulfate Solution[J]. J. Alloy. Compd., 2005, 391: 104–109

    Article  CAS  Google Scholar 

  15. C D Gu, J S Lian, G Y Li, et al. High Corrosion-resistant Ni-P/Ni/Ni-P Multilayer Coating on Steel[J]. Surf. Coat. Technol., 2005, 197(1): 61–67

    CAS  Google Scholar 

  16. K Sharma, M R Suresh, H Bhojraj, et al. Electroless Nickel Plating on Magnesium Alloy[J]. Met. Finish., 1998, 96(3): 10–18

    Article  Google Scholar 

  17. H W Huo, Y Li and F H Wang. Corrosion of AZ91D Magnesium Alloy with a Chemical Conversion Coating and Electroless Nickel Layer[J]. Corros. Sci., 2004, 46(6): 1 467–1 477

    CAS  Google Scholar 

  18. R Ambat and W Zhou. Electroless Nickel-Plating on AZ91D Magnesium Alloy: Effect of Substrate Microstructure and Deposition Parametersp[J]. Surf. Coat. Technol., 2004, 179(2–3): 124–134

    Article  CAS  Google Scholar 

  19. ASTM Standards B733-1997. Standard Specification for Autocatalytic (Electroless) Nickel-Phosphorus Coatings on Metal [S], 1997

  20. ISO Standards 2819-1980. Metallic Coatings on Metallic Substrates-Electrodeposited and Chemically Deposited Coatings-Review of Methods Available for Testing Adhesion[S], 1980

  21. Z Abdel Hamid and M T Abou Elkhair. Development of Electroless Nickel-phosphorous Composite Deposits for Wear Resistance of 6061 Aluminum Alloy[J]. Mater. Lett., 2002, 57(3): 720–726

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Lian Jianshe.

Additional information

Supported by Foundation of National Key Basic Research and Development Program (No.2004CB619301) and Project 985-Automotive Engineering of Jilin University

Rights and permissions

Reprints and permissions

About this article

Cite this article

Li, G., Niu, L., Jiang, Q. et al. Electroless Ni-P deposition on magnesium alloy from a sulfate bath. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 23, 60–64 (2008). https://doi.org/10.1007/s11595-006-1060-7

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11595-006-1060-7

Key words

Navigation