Abstract
In this investigation, we have attempted a novel solution-based strategy to prepare nanostructured silicon oxide@nickel oxide (SiO2@NiO) composite by incorporating NiO into the matrix of the laboratory glass-waste-derived SiO2. The crystal structure and surface functional groups of the prepared composite were investigated by X-ray diffraction (XRD), Raman and Fourier transformed infrared (FT-IR) spectroscopic studies. The morphology of the SiO2@NiO composite examined by scanning electron microscope (SEM) showed uniform distribution of spherical particles with pore size in the range of 120–160 nm. High-resolution transmission electron microscope (HR-TEM) analysis revealed the presence of hollow transparent spherical SiO2 grains entrenched with ultrafine NiO particles homogenously. The electrochemical performance of the SiO2@NiO composite as anode material for lithium storage was tested by assembling a CR2032-type coin cell. The cyclic voltammetry studies revealed the excellent electrochemical performance of the SiO2@NiO composite electrode. It is found that the fabricated half-cell delivered a reversible capacity as high as 1000 mA h g−1 at 0.2 C with remarkable Coulombic efficiency of 99%. The SiO2@NiO heterostructure electrode exhibited an appreciable capacity retention of 80% (780 mA h g−1) even at the end of 100th charge/discharge cycle. The excellent electrochemical performance of the SiO2@NiO anode could be attributed to the simultaneous reactions of Li with SiO2, Si, and NiO involving both alloying and conversion mechanisms.
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References
Su X, Wu Q, Li J, Xiao X, Lott A, Lu W, Sheldon BW, Wu J (2014) Silicon-based nanomaterials for lithium-ion batteries: a review. Adv Energy Mater 4:1300882
Armand M, Tarascon J-M (2008) Building better batteries. Nature 451:65, 652, 657
Notter DA, Gauch M, Widmer R, Wäger P, Stamp A, Zah R, Althaus H-J (2010) Contribution of Li-ion batteries to the environmental impact of electric vehicles. Environ Sci Technol 44:6550–6556
Zhou L, Zhang K, Hu Z, Tao Z, Mai L, Kang YM, Chou SL, Chen J (2018) Recent developments on and prospects for electrode materials with hierarchical structures for lithium-ion batteries. Adv Energy Mater 8:1701415
Duraisamy E, Gurunathan P, Das HT, Ramesha K, Elumalai P (2017) [Co (salen)] derived Co/Co3O4 nanoparticle@ carbon matrix as high-performance electrode for energy storage applications. J Power Sources 344:103–110
Weppner W (2003) Engineering of solid state ionic devices. Ionics 9:444–464
Kammampata SP, Thangadurai V (2018) Cruising in ceramics-discovering new structures for all-solid-state-batteries-fundamentals, materials, and performances. Ionics 24:639–660
Mauger A, Julien CM (2017) Critical review on lithium-ion batteries: are they safe? Sustainable? Ionics 23:1933–1947
Chang W-S, Park C-M, Kim J-H, Kim Y-U, Jeong G, Sohn H-J (2012) Quartz (SiO2): a new energy storage anode material for Li-ion batteries. Energy Environ Sci 5:6895–6899
Zhou X, Yin YX, Wan LJ, Guo YG (2012) Self-assembled nanocomposite of silicon nanoparticles encapsulated in graphene through electrostatic attraction for lithium-ion batteries. Adv Energy Mater 2:1086–1090
Favors Z, Wang W, Bay HH, George A, Ozkan M, Ozkan CS (2014) Stable cycling of SiO2 nanotubes as high-performance anodes for lithium-ion batteries. Sci Rep 4:4605
Lee G, Kim S, Kim S, Choi J (2017) SiO2/TiO2 composite film for high capacity and excellent cycling stability in lithium-ion battery anodes. Adv Funct Mater 27:1703538
Gao B, Sinha S, Fleming L, Zhou O (2001) Alloy formation in nanostructured silicon. Adv Mater 13:816–819
Sun Q, Zhang B, Fu Z-W (2008) Lithium electrochemistry of SiO2 thin film electrode for lithium-ion batteries. Appl Surf Sci 254:3774–3779
Li X, Dhanabalan A, Meng X, Gu L, Sun X, Wang C (2012) Nanoporous tree-like SiO2 films fabricated by sol–gel assisted electrostatic spray deposition. Micropo Mesopor Mat 151:488–494
Yan N, Wang F, Zhong H, Li Y, Wang Y, Hu L, Chen Q (2013) Hollow porous SiO2 nanocubes towards high-performance anodes for lithium-ion batteries. Sci Rep 3:1568
Zhang J, Zhang X, Zhang C, Liu Z, Zheng J, Zuo Y, Xue C, Li C, Cheng B (2017) Facile and efficient synthesis of a microsized SiOx/C core–shell composite as anode material for lithium ion batteries. Energy Fuel 31:8758–8763
Wang Y, Zhou W, Zhang L, Song G, Cheng S (2015) SiO2@ NiO core–shell nanocomposites as high performance anode materials for lithium-ion batteries. RSC Adv 5:63012–63016
Wang J, Bao W, Ma L, Tan G, Su Y, Chen S, Wu F, Lu J, Amine K (2015) Scalable preparation of ternary hierarchical silicon oxide–nickel–graphite composites for lithium-ion batteries. ChemSusChem 8:4073–4080
Prasath A, Elumalai P (2016) Extraction of nanostructured SiO2 from glass waste: a potential anode source for lithium–ion batteries. Chemistry Select 1:3363–3366
Soumyadipta R, Srabanti G, Sayantani C, Soumya SM, Moulikac SP, Subhash CB (2013) Controlled synthesis of spin glass nickel oxide nanoparticles and evaluation of their potential antimicrobial activity: a cost effective and eco-friendly approach. RSC Adv 3:19348–19356
Lee LE, Wachs EI (2008) In situ Raman spectroscopy of SiO2-supported transition metal oxide catalysts: an isotopic 18O-16O exchange study. J Phys Chem C 112:6487–6498
Das HT, Mahendraprabhu K, Maiyalagan T, Elumalai P (2017) Performance of solid-state hybrid energy-storage device using reduced graphene-oxide anchored sol-gel derived Ni/NiO nanocomposite. Sci Rep 7:15342
Ren Y, Li M (2016) Facile synthesis of SiOx@ C composite nanorods as anodes for lithium ion batteries with excellent electrochemical performance. J Power Sources 306:459–466
Liu H, Wang G, Liu J, Qiao S, Ahn H (2011) Highly ordered mesoporous NiO anode material for lithium ion batteries with an excellent electrochemical performance. J Mater Chem 21:3046–3052
Acknowledgements
The authors acknowledge the Central Instrumentation Facility of Pondicherry University.
Funding
AS receives from the Science and Engineering Research Board (SERB), Government of India, the National Post-Doctoral Fellowship (PDF/2016/002815). PE receives from the SERB, Government of India, the research grant EMR/2016/001305.
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Prasath, A., Selva Sharma, A. & Elumalai, P. Nanostructured SiO2@NiO heterostructure derived from laboratory glass waste as anode material for lithium-ion battery. Ionics 25, 1015–1023 (2019). https://doi.org/10.1007/s11581-019-02879-9
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DOI: https://doi.org/10.1007/s11581-019-02879-9