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Synthesis and performance of La2O3@MWCNT composite materials as Pt-free counter electrodes for dye-sensitized solar cells

  • Kezhong Wu
  • Jiajing Zhao
  • Yuanyuan Xiong
  • Bei Ruan
  • Mingxing Wu
Original Paper


Pt-free composite counter electrode (CE) composed of La2O3 was successfully synthesized by a simple pyrolysis of Lanthanum acetate hydrate (La(CH3COO)3·xH2O) in a high-temperature solid phase. Furthermore, three proportion composite catalysts of La2O3@MWCNTs based on La2O3 and multiwall carbon nanotubes (MWCNTs) were prepared and characterized as Pt-free catalysts for CE in dye-sensitized solar cells (DSSCs). The morphology and structure of La2O3@MWCNT composites were determined by scanning electron microscopy and X-ray diffraction. The electrochemical performance of La2O3@MWCNT composite catalysts for CEs was determined by photocurrent-voltage measurements, cyclic voltammetry, electrochemical impedance spectroscopy, and Tafel polarization. The experimental results showed that the power conversion efficiencies of 5.20, 5.12, and 4.70% were obtained for La2O3: MWCNTs with mass ratios of 5:1, 3:1, and 1:1 as counter electrode towards the reduction of I3/I ions respectively in the encapsulation of DSSC batteries, which were higher than that of MWCNTs (3.94%) and La2O3 (0.77%) electrode under the similar conditions. The enhanced electrode performance was attributed to relatively larger surface area and higher conductivity of La2O3@MWCNT composite catalysts.


Dye-sensitized solar cell Counter electrode Lanthanum oxide Composite material Power conversion efficiency 


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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  • Kezhong Wu
    • 1
  • Jiajing Zhao
    • 1
  • Yuanyuan Xiong
    • 1
  • Bei Ruan
    • 1
  • Mingxing Wu
    • 1
  1. 1.Key Laboratory of Inorganic Nano-materials of Hebei Province, Department of Chemistry and Material ScienceHebei Normal UniversityShijiazhuangPeople’s Republic of China

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