Ionics

, Volume 23, Issue 11, pp 3085–3096 | Cite as

Hybrid anion exchange membrane of hydroxyl-modified polysulfone incorporating guanidinium-functionalized graphene oxide

  • Yanxiang Liu
  • Jian Dai
  • Kuibo Zhang
  • Lingling Ma
  • Naeem Akhtar Qaisrani
  • Fengxiang Zhang
  • Gaohong He
Original Paper

Abstract

Incorporating nanofillers is an effective method to balance conductivity and mechanical strength of anion exchange membranes (AEMs). In this work, a series of AEMs were prepared via embedding guanidinium-functionalized graphene oxide (GGO) into un-quaternized, diethanolamine-modified polysulfone (HPSf). The improved hydrophilicity of HPSf allows for better compatibility between GGO and polymer and also gives higher water uptake, which is beneficial for facilitating ion transport and alleviating hydroxide attack. AEM of HPSf embedding an optimized amount of GGO (0.88 mmol g−1) exhibits the highest conductivity of 11 mS cm−1 at 30 °C, which is 38% higher than that of pristine PSf-GGO membrane. It also possesses excellent anti-swelling stability (9% swelling ratio at 60 °C). When treated with 1 M NaOH at 60 °C for 120 h, HPSf-GGO-25% experienced a conductivity decay by 25%. Our work provides a route to fabrication of hybrid AEMs with improved interface properties and well-balanced conductivity and robustness.

Keywords

Anion exchange membrane Graphene oxide Guanidinium 

Notes

Acknowledgements

We gratefully acknowledge the financial supports from the National Natural Science Foundation of China (grant no. 21276252), the Basic Research Fund of Central Universities China (grant no. DUT14RC (3) 20), the financial support of State Key Laboratory of Fine Chemicals (Panjin) (grant no. JH2014009), and the Natural Science Foundation of Liaoning Province (2015020630).

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Copyright information

© Springer-Verlag Berlin Heidelberg 2017

Authors and Affiliations

  • Yanxiang Liu
    • 1
  • Jian Dai
    • 1
  • Kuibo Zhang
    • 1
  • Lingling Ma
    • 1
  • Naeem Akhtar Qaisrani
    • 1
  • Fengxiang Zhang
    • 1
  • Gaohong He
    • 1
  1. 1.State Key Laboratory of Fine Chemicals, School of Chemical and Petroleum EngineeringDalian University of TechnologyPanjinChina

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