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Ionics

, Volume 23, Issue 11, pp 3037–3044 | Cite as

Sulfonated poly(phenylene oxide)/Ti3+/TiO2 nanotube arrays membrane/electrode with high performances for lithium ion battery

  • Jixiang Duan
  • Hongying Hou
  • Xianxi Liu
  • Qishu Liao
  • Song Liu
  • Yuan Yao
Original Paper
  • 194 Downloads

Abstract

Sulfonated poly(phenylene oxide) (SPPO) film was electrodeposited on Ti3+-doped TiO2 nanotube arrays (Ti3+/TiO2NT) electrode via the electropolymerization of sulfonated phenol. The as-synthesized SPPO/Ti3+/TiO2NT membrane/electrode was investigated in terms of SEM, FESEM, EDX, FTIR, XPS, galvanostatic charge/discharge, and cycle voltammetry (CV). As expected, the porous SPPO film did form on the surface of Ti3+/TiO2NT electrode; furthermore, the resultant SPPO/Ti3+/TiO2NT membrane/electrode delivered higher electrochemical performances than PPO/Ti3+/TiO2NT, mainly attributed to the contributions of the ionic conductivity induced by –SO3H groups within SPPO.

Keywords

Sulfonated phenol Ti3+-doped TiO2 nanotube arrays Ionic conductivity Electrodeposition Lithium ion battery 

Notes

Acknowledgements

This work was financially supported by the National Natural Science Foundation of China (Grant No.51363011), the 46th Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry in China (6488-20130039), the 19th Young Academic and Technical Leaders of Yunnan Province in China andthe Program of High-level Introduced Talent of Yunnan Province in China (10978125).

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Copyright information

© Springer-Verlag Berlin Heidelberg 2017

Authors and Affiliations

  • Jixiang Duan
    • 1
  • Hongying Hou
    • 1
  • Xianxi Liu
    • 2
  • Qishu Liao
    • 1
  • Song Liu
    • 1
  • Yuan Yao
    • 1
  1. 1.Faculty of Material Science and EngineeringKunming University of Science and TechnologyKunmingChina
  2. 2.Faculty of Mechanical and Electrical EngineeringKunming University of Science and TechnologyKunmingChina

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