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Curvature-Dependent Cavity-Nanoparticle Scaffold-Based Clusters with LSPR Enhancement as SERS Substrates

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Abstract

Tunable local surface plasmon resonance (LSPR) enhancement properties of cavity-nanoparticle scaffold-based clusters were investigated via finite-difference time-domain (FDTD) simulations. Hollow Au-cylinder-based and hollow Au-sphere-based nanocomposites models were presented with calculated optical spectra, near-field distribution, and average enhancement. Focusing on surface curvature, concave and convex Au-surface/Au-nanoparticles were built for further understanding on the local shape dependency in complicate scaffold-based clusters. Tunable near-field enhancement contributions and scaffold-dependency were discussed for potential in plasmonic applications such as surface-enhanced Raman spectroscopy (SERS), LSPR sensor, and nanoantenna.

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Data Availability

The data that support the findings of this study are available from the corresponding author upon reasonable request.

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Funding

This work was supported by the National Natural Science Foundation of China (22005013, 51872011, and 51902011).

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Authors and Affiliations

  1. Key Laboratory of Bio-Inspired Smart Interfacial Science and Technology of Ministry of Education, School of Chemistry, Beihang University, Beijing, 100191, China

    Tingting You, Yukun Gao, Huaxiang Chen & Penggang Yin

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  1. Tingting You
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  2. Yukun Gao
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  3. Huaxiang Chen
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  4. Penggang Yin
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The manuscript was written through contributions of all authors. All authors have given approval to the final version of the manuscript.

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Correspondence to Huaxiang Chen or Penggang Yin.

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You, T., Gao, Y., Chen, H. et al. Curvature-Dependent Cavity-Nanoparticle Scaffold-Based Clusters with LSPR Enhancement as SERS Substrates. Plasmonics 16, 1231–1239 (2021). https://doi.org/10.1007/s11468-021-01396-8

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  • DOI: https://doi.org/10.1007/s11468-021-01396-8

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