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Ligand controlled cobalt catalyzed regiodivergent 1,2-hydroboration of 1,3-dienes

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Abstract

Regiodivergent 1,2-hydroboration of 1,3-dienes with pinacolborane has been accomplished by well-defined cobalt complexes of different bidentate ligands. The iminopyridine-cobalt system is selective for Markovnikov 1,2-hydroboration to form allylboronates, while the FOXAP-cobalt (FOXAP=(S)-1-(diphenylphosphino)-2-[(S)-4-isopropyloxazolin-2-yl]ferrocene) catalyst effects the complementary anti-Markonikv 1,2-hydroboration to afford homoallyboronates with high regioselectivity.

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Acknowledgements

This work was supported by the National Key R&D Program of China (2016YFA0202900, 2015CB856600), the National Natural Science Foundation of China (21825109, 21432011, 21572255, 21732006), Chinese Academy of Sciences (XDB20000000, QYZDB-SSW-SLH016), and Science and Technology Commission Shanghai Municipality (17JC1401200).

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  1. These authors contributed equally to this work.

Authors and Affiliations

  1. State Key Laboratory of Organometallic Chemistry, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, Shanghai, 200032, China

    Sihan Peng, Guixia Liu & Zheng Huang

  2. School of Physical Science and Technology, Shanghai Tech University, Shanghai, 201210, China

    Ji Yang & Zheng Huang

Authors
  1. Sihan Peng
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  2. Ji Yang
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  3. Guixia Liu
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  4. Zheng Huang
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Correspondence to Guixia Liu or Zheng Huang.

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Peng, S., Yang, J., Liu, G. et al. Ligand controlled cobalt catalyzed regiodivergent 1,2-hydroboration of 1,3-dienes. Sci. China Chem. 62, 336–340 (2019). https://doi.org/10.1007/s11426-018-9418-7

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  • DOI: https://doi.org/10.1007/s11426-018-9418-7

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