Abstract
In this work, highly chemiluminescent magnetic mesoporous carbon with yolk-shell structure was synthesized by encapsulating N-(4-aminobutyl)-N-ethylisoluminol (ABEI) and Co2+ into the magnetic mesoporous carbon composites (Co2+-ABEI-Fe3O4@ void@C). The synthetic Co2+-ABEI-Fe3O4@void@C showed a good magnetic separation property, which could remove residual ABEI molecules and Co2+ in less than 3 min under an external magnet. Moreover, the synthetic Co2+-ABEI-Fe3O4@void@C demonstrated good chemiluminescence (CL) property and good stability when interacted with alkaline H2O2 solution. The CL intensity of such Co2+-ABEI-Fe3O4@void@C was about 120 times higher than that of ABEI-Fe3O4@void@C. The Co2+-ABEIFe3O4@ void@C also exhibited good electrochemiluminescence (ECL) property in alkaline solution. The outstanding CL/ECL performance of the Co2+-ABEI-Fe3O4@void@C was attributed to the Co2+ immobilized in the Co2+-ABEI-Fe3O4@void@C, which catalyzed the decomposition of H2O2 to generate O2•− and HO•, expediting the CL/ECL reaction. The synthetic Co2+-ABEI-Fe3O4@void@C may be of great application for the development of new methodologies in bioanalysis.
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Gu W, Deng X, Gu X, Jia X, Lou B, Zhang X, Li J, Wang E. Anal Chem, 2015, 87: 1876–1881
Justino CIL, Gomes AR, Freitas AC, Duarte AC, Rocha-Santos TAP. TrAC Trends Anal Chem, 2017, 91: 53–66
Li LL, Liu KP, Yang GH, Wang CM, Zhang JR, Zhu JJ. Adv Funct Mater, 2011, 21: 869–878
Urmann K, Walter JG, Scheper T, Segal E. Anal Chem, 2015, 87: 1999–2006
Wei Y, Sun H, Li J, Zhang Y, Li Y, Lin J, Wang T, Zhou M. J Electroanal Chem, 2017, 795: 123–129
Du D, Zou Z, Shin Y, Wang J, Wu H, Engelhard MH, Liu J, Aksay IA, Lin Y. Anal Chem, 2010, 82: 2989–2995
Han Z, Li F, Shu J, Gao L, Liu X, Cui H. ACS Appl Mater Interfaces, 2016, 8: 17454–17460
Dong S, Yuan Z, Zhang L, Lin Y, Lu C. Anal Chem, 2017, 89: 12520–12526
Qin Y, Liu N, Li H, Sun Y, Hu L, Zhao S, Han D, Liu Y, Kang Z, Niu L. J Phys Chem C, 2017, 121: 27546–27554
Vázquez-González M, Liao WC, Cazelles R, Wang S, Yu X, Gutkin V, Willner I. ACS Nano, 2017, 11: 3247–3253
Ismail NS, Le QH, Hasan Q, Yoshikawa H, Saito M, Tamiya E. Electrochim Acta, 2015, 180: 409–418
Wang J, Zhong W, Liu X, Yang T, Li F, Li Q, Cheng W, Gao C, Jiang Z, Jiang J, Cui H. Anal Chem, 2017, 89: 13518–13523
Shen W, Yu Y, Shu J, Cui H. Chem Commun, 2012, 48: 2894–2896
Xu S, Liu Y, Wang T, Li J. Anal Chem, 2011, 83: 3817–3823
Ding SN, Shan D, Cosnier S, Le Goff A. Chem Eur J, 2012, 18: 11564–11568
Haghighi B, Tavakoli A, Bozorgzadeh S. J Electroanal Chem, 2016, 762: 80–86
Zhang S, Zang L, Zhang X, Dai H, Xu G, Zhang Q, Yang C, Lin Y. Electrochim Acta, 2016, 196: 67–74
Lee JS, Joung HA, Kim MG, Park CB. ACS Nano, 2012, 6: 2978–2983
Liu X, Han Z, Li F, Gao L, Liang G, Cui H. ACS Appl Mater Interfaces, 2015, 7: 18283–18291
Li G, Yu X, Liu D, Liu X, Li F, Cui H. Anal Chem, 2015, 87: 10976–10981
Li J, Cao Y, Hinman SS, McKeating KS, Guan Y, Hu X, Cheng Q, Yang Z. Biosens Bioelectron, 2018, 100: 304–311
Afsharan H, Khalilzadeh B, Tajalli H, Mollabashi M, Navaeipour F, Rashidi MR. Electrochim Acta, 2016, 188: 153–164
Liu J, Yang HQ, Kleitz F, Chen ZG, Yang T, Strounina E, Lu GQM, Qiao SZ. Adv Funct Mater, 2012, 22: 591–599
Yue Q, Li J, Luo W, Zhang Y, Elzatahry AA, Wang X, Wang C, Li W, Cheng X, Alghamdi A, Abdullah AM, Deng Y, Zhao D. J Am Chem Soc, 2015, 137: 13282–13289
Wu XJ, Xu D. Adv Mater, 2010, 22: 1516–1520
Liu J, Qiao S, Budi Hartono S, Lu G. Angew Chem, 2010, 122: 5101–5105
Lin CH, Liu X, Wu SH, Liu KH, Mou CY. J Phys Chem Lett, 2011, 2: 2984–2988
Liu C, Li J, Qi J, Wang J, Luo R, Shen J, Sun X, Han W, Wang L. ACS Appl Mater Interfaces, 2014, 6: 13167–13173
Rai P, Yoon JW, Jeong HM, Hwang SJ, Kwak CH, Lee JH. Nanoscale, 2014, 6: 8292–8299
Wang Y, Gu H. Adv Mater, 2015, 27: 576–585
Chen Y, Chen H, Zeng D, Tian Y, Chen F, Feng J, Shi J. ACS Nano, 2010, 4: 6001–6013
Lee J, Park JC, Song H. Adv Mater, 2008, 20: 1523–1528
Kuo CH, Tang Y, Chou LY, Sneed BT, Brodsky CN, Zhao Z, Tsung CK. J Am Chem Soc, 2012, 134: 14345–14348
Lee I, Albiter MA, Zhang Q, Ge J, Yin Y, Zaera F. Phys Chem Chem Phys, 2011, 13: 2449–2456
Jiang Z, Zhu C, Wan W, Qian K, Xie J. J Mater Chem A, 2016, 4: 1806–1818
Li X, Gai F, Guan B, Zhang Y, Liu Y, Huo Q. J Mater Chem A, 2015, 3: 3988–3994
Shao Y, Zhou L, Bao C, Ma J. Carbon, 2015, 89: 378–391
Liu N, Wu H, McDowell MT, Yao Y, Wang C, Cui Y. Nano Lett, 2012, 12: 3315–3321
Wei Seh Z, Li W, Cha JJ, Zheng G, Yang Y, McDowell MT, Hsu PC, Cui Y. Nat Commun, 2013, 4: 1331
Sindoro M, Granick S. J Am Chem Soc, 2014, 136: 13471–13473
Yue Q, Zhang Y, Wang C, Wang X, Sun Z, Hou XF, Zhao D, Deng Y. J Mater Chem A, 2015, 3: 4586–4594
Yang R, Liu Y, Yan X, Liu S, Zheng H. J Mater Chem A, 2016, 4: 9807–9815
Gierszal KP, Jaroniec M. J Am Chem Soc, 2006, 128: 10026–10027
Ko TH, Kuo WS, Chang YH. J Appl Polym Sci, 2001, 81: 1084–1089
Centeno TA, Vilas JL, Fuertes AB. J Membrane Sci, 2004, 228: 45–54
Liu Y, Shen W, Li Q, Shu J, Gao L, Ma M, Wang W, Cui H. Nat Commun, 2017, 8: 1003
Shu J, Wang W, Cui H. Chem Commun, 2015, 51: 11366–11369
Acknowledgements
This work was supported by the National Natural Science Foundation of China (21475120, 21527807) and the National Key Research and Development Program of China (2016YFA0201300).
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Yang, R., Liu, S. & Cui, H. Highly chemiluminescent magnetic mesoporous carbon composites Fe3O4@void@C with yolk-shell structure. Sci. China Chem. 61, 1143–1150 (2018). https://doi.org/10.1007/s11426-018-9329-5
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DOI: https://doi.org/10.1007/s11426-018-9329-5