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Source identification and spatial distribution of metals in soils in a typical area of the lower Yellow River, eastern China

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Abstract

In this study, 234 soil samples were recently collected from Gaoqing County (a typical area of the lower Yellow River) to determine the contents of As, Cd, Cr, Cu, Hg, Ni, Pb, and Zn. Multivariate statistical analyses such as correlation analysis, principal components analysis, and one-way ANOVA were applied to identify the source of metals in the soil. Geostatistical methods were used to analyze the spatial structure and distribution of the metals. The results indicated that the mean contents of all metals exceeded the background value of the lower Yellow River, especially for As, Cu, and Hg (1.23, 1.20, and 1.29 times that of the BV, respectively), indicating that these metals were enriched in the study area to different degrees. The results derived from multivariate analysis suggested that As, Cd, Cr, Cu, Ni, Pb, and Zn were mainly controlled by the combination of human activities and soil parent material, and the human activities included industrial emissions, traffic emissions, and agricultural practices. In addition, Hg mainly originated from anthropogenic inputs, such as textile printing, plastics processing, and petrochemical engineering. The contents of metals in different types of land use and parent materials are clearly different. The mean content for eight elements in urban construction land was significantly higher than that of the other land use types; in addition to Hg, the mean content of the other elements was the highest in the lacustrine deposit. The elements of As, Cd, Cr, Cu, Ni, Pb, and Zn had similar hotspots in the urban area, indicating the significant human influence. In addition, these seven metals showed high values in the southeast lacustrine deposit area. The high-value areas of Hg were concentrated in the southwest and northeast study area, which were consistent with the spatial pattern of the industrial sites.

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References

  • Acosta JA, Faz A, Martinez-Martinez S (2010) Identification of heavy metal sources by multivariable analysis in a typical Mediterranean city (SE Spain). Environ Monit Assess 169(14):519–530

    Article  CAS  Google Scholar 

  • Bednářová Z, Kalina J, Hájek O (2016) Spatial distribution and risk assessment of metals in agricultural soils. Geoderma 284:113–121

    Article  CAS  Google Scholar 

  • Bo LJ, Wang DJ, Li TL, Li Y, Zhang G, Wang C, Zhang SQ (2015) Accumulation and risk assessment of heavy metals in water, sediments, and aquatic organisms in rural rivers in the Taihu Lake region, China. Environ Sci Pollut Res 22:6721–6731

    Article  CAS  Google Scholar 

  • Bonanno G, Borg JA, Di Martino V (2017) Levels of heavy metals in wetland and marine vascular plants and their biomonitoring potential: a comparative assessment. Sci Total Environ 576:796–806

    Article  CAS  Google Scholar 

  • Cai LM, Ma J, Zhou YZ (2008) Multivariate geostatistics and GIS-based approach to study the spatial distribution and sources of heavy metals in agricultural soil in the Pearl River Delta, China. Environ Sci 29(12):3496–3502

    CAS  Google Scholar 

  • Cai LM, Xu ZC, Ren MZ, Guo Q, Hu X, Hu G, Wan H, Peng P (2012) Source identification of eight hazardous heavy metals in agricultural soils of Huizhou, Guangdong Province, China. Ecotoxicol Environ Saf 78:2–8

    Article  CAS  Google Scholar 

  • Chen TB, Zheng YM, Lei M, Huang ZC, Wu HT, Chen H, Fan KK, Yu K, Wu X, Tian QZ (2005) Assessment of heavy metal pollution in surface soils of urban parks in Beijing, China. Chemosphere 60(4):542–551

    Article  CAS  Google Scholar 

  • Chen XD, Lu XW, Yang G (2012) Sources identification of heavy metals in urban topsoil from inside the Xi’an Second Ringroad, NW China using multivariate statistical methods. Catena 98:73–78

    Article  CAS  Google Scholar 

  • Cheng QL, Wang RL, Huang WH, Wang WL, Li XD (2015) Assessment of heavy metal contamination in the sediments from the Yellow River Wetland National Nature Reserve (the Sanmenxia section), China. Environ Sci Pollut Res 22:8586–8593

    Article  CAS  Google Scholar 

  • Cui YJ, Zhu YG, Zhai RH, Chen DY, Huang YZ, Qiu Y, Liang JZ (2004) Transfer of metals from soil to vegetables in an area near a smelter in Nanning, China. Environ Int 30(6):785–791

    Article  CAS  Google Scholar 

  • Dai B, Lv JS, Zhan JC (2015) Assessment of sources, spatial distribution and ecological risk of heavy metals in soils in a typical industry-based City of Shandong Province, eastern China. Environ Sci 36(2):507–515 (in Chinese)

    Google Scholar 

  • Facchinelli A, Sacchi E, Mallen L (2001) Multivariate statistical and GIS-based approach to identify heavy metal sources in soils. Environ Pollut 114:313–324

    Article  CAS  Google Scholar 

  • Franco-Uria A, Lopez-Mateo C, Roca E (2009) Source identification of heavy metals in pastureland by multivariate analysis in NW Spain. J Hazard Mater 165:1008–1015

    Article  CAS  Google Scholar 

  • Han DM, Cheng JP, Hu XF, Jiang ZY (2017) Spatial distribution, risk assessment and source identification of heavy metals in sediments of the Yangtze River Estuary, China. Mar Pollut Bull 115:141–148

    Article  CAS  Google Scholar 

  • Hu Y, Cheng H (2016) A method for apportionment of natural and anthropogenic contributions to heavy metal loadings in the surface soils across large-scale regions. Environ Pollut 214:400–409

    Article  CAS  Google Scholar 

  • Huang SS, Liao QL, Hua M (2007) Survey of heavy metal pollution and assessment of agricultural soil in Yangzhong district, Jiangsu Province, China. Chemosphere 67:2148–2155

    Article  CAS  Google Scholar 

  • Li W, Xu B, Song Q (2014) The identification of ‘hotspots’ of heavy metal pollution in soil–rice systems at a regional scale in eastern China. Sci Total Environ 472:407–420

    Article  CAS  Google Scholar 

  • Li HH, Chen LJ, Yu L (2017) Pollution characteristics and risk assessment of human exposure to oral bio accessibility of heavy metals via urban street dusts from different functional areas in Chengdu, China. Sci Total Environ 586:1076–1084

    Article  CAS  Google Scholar 

  • Liu JL, Feng XB, Yin RS, Zhu W, Li ZG (2011) Mercury distributions and mercury isotope signatures in sediments of Dongjiang, the Pearl River Delta, China. Chem Geol 287:81–89

    Article  CAS  Google Scholar 

  • Liu Y, Ma ZW, Lv JS (2016) Identifying sources and hazardous risks of heavy metals in topsoils of rapidly urbanizing East China. J Geogr Sci 26:735–749

    Article  Google Scholar 

  • Lu AX, Wang JH, Qin XY (2012) Multivariate and geostatistical analyses of the spatial distribution and origin of heavy metals in the agricultural soils in Shunyi, Beijing, China. Sci Total Environ 425:66–74

    Article  CAS  Google Scholar 

  • Lu Y, Zhu F, Chen J (2007) Chemical fractionation of heavy metals in urban soils of Guangzhou, China. Environ Monit Assess 134: 429–439

  • Lu J, Li A, Huang P (2017) Distribution, sources and contamination assessment of heavy metals in surface sediments of the South Yellow Sea and northern part of the East China Sea. Mar Pollut Bull 124(1): 470–479

    Article  CAS  Google Scholar 

  • Lv JS, Zhang ZL, Liu Y, Dai JR, Wang X (2012) Sources identification and hazardous risk delineation of heavy metals contamination in Rizhao City. Acta Geograph Sin 67(7):971–984

    Google Scholar 

  • Lv JS, Liu Y, Zhang ZL (2013) Factorial kriging and stepwise regression approach to identify environmental factors influencing spatial multi-scale variability of heavy metals in soils. J Hazard Mater 261:387–397

    Article  CAS  Google Scholar 

  • Lv JS, Zhang ZL, Li S et al (2014a) Assessing spatial distribution, sources, and potential ecological risk of heavy metals in surface sediments of the Nansi Lake, Eastern China. J Radioanal Nucl Chem 299(3):1671–1681

    Article  CAS  Google Scholar 

  • Lv JS, Liu Y, Zhang ZL (2014b) Multivariate geostatistical analyses of heavy metals in soils: spatial multi-scale variations in Wulian, Eastern China. Ecotoxicol Environ Saf 107:140–147

    Article  CAS  Google Scholar 

  • Lv J, Liu Y, Zhang Z (2015a) Distinguishing anthropogenic and natural sources of trace elements in soils undergoing recent 10-year rapid urbanization: a case of Donggang, Eastern China. Environ Sci Pollut Res 22(14):10539–10550

    Article  CAS  Google Scholar 

  • Lv JS, Zhang ZL, Liu Y (2015b) Identifying the origins and spatial distributions of heavy metals in soils of Ju county (Eastern China) using multivariate and geostatistical approach. J Soils Sediments 15:163–178

    Article  CAS  Google Scholar 

  • Ma XL, Zuo H, Tian MJ, Zhang LY, Meng J, Zhou XN (2016) Assessment of heavy metals contamination in sediments from three adjacent regions of the Yellow River using metal chemical fractions and multivariate analysis techniques. Chemosphere 144:264–272

    Article  CAS  Google Scholar 

  • Mico C, Recatala L, Peris A, Sanchez J (2006) Assessing heavy metalsources in agricultural soils of an European Mediterranean area bymultivariate analysis. Chemosphere 65:863–872

  • Naji A, Sohrabi T (2015) Distribution and contamination pattern of heavy metals from surface sediments in the southern part of Caspian Sea, Iran. Chem Spec Bioavailab 27(1):29–43

    Article  CAS  Google Scholar 

  • Nanos N, Rodríguez Martín JA (2012) Multiscale analysis of heavy metal contents in soils: spatial variability in the Duero river basin (Spain). Geoderma 189:554–562

    Article  CAS  Google Scholar 

  • Pan HY, Lu XW, Lei K (2017) A comprehensive analysis of heavy metals in urban road dust of Xi'an, China: contamination, source apportionment and spatial distribution. Sci Total Environ 609:1361–1369

    Article  CAS  Google Scholar 

  • Rinklebe J, Shaheen SM (2017) Geochemical distribution of Co, Cu, Ni, and Zn in soil profiles of Fluvisols, Luvisols, Gleysols, and Calcisols originating from Germany and Egypt. Geoderma 307:122–138

    Article  CAS  Google Scholar 

  • Rodríguez Martín JA, Nanos N (2016) Soil as an archive of coal-fired power plant mercury deposition. J Hazard Mater 308:131–138

    Article  CAS  Google Scholar 

  • Rodríguez Martín JA, Arias ML, Grau Corbi JM (2006) Heavy metals contents in agricultural top soils in the Ebro basin (Spain). Application of the multivariate geostatistical methods to study spatial variations. Environ Pollut 144:1001–1012

    Article  CAS  Google Scholar 

  • Rodríguez Martín JA, Ramos-Miras JJ, Boluda R (2013) Spatial relations of heavy metals in arable and greenhouse soils of a Mediterranean environment region (Spain). Geoderma 200:180–188

    Article  CAS  Google Scholar 

  • Rodríguez JA, Nanos N, Grau JM, Gil L (2008) Multiscale analysis of heavy metal contents in Spanish agricultural topsoils. Chemosphere 70:1085–1096

    Article  CAS  Google Scholar 

  • Saleem M, Iqbal J, Shah MH (2013) Study of seasonal variations and risk assessment of selected metals in sediments from Mangla Lake, Pakistan. J Geochem Explor 125:144–152

    Article  CAS  Google Scholar 

  • Sollitto D, Romic M, Castrignano A (2010) Assessing heavy metal contamination in soils of the Zagreb region (Northwest Croatia) using multivariate geostatistics. Catena 80:182–194

    Article  CAS  Google Scholar 

  • Stafilov T, Sajn R, Alijagic J (2013) Distribution of arsenic, antimony, and thallium in soil in Kavadarci and its surroundings, Republic of Macedonia. Soil Sediment Contam 22:105–118

    Article  CAS  Google Scholar 

  • State Environmental Protection Administration of China (1997) Environmental quality standard for soils (GB15618–1995). Standards Press of China, Beijing

    Google Scholar 

  • Sun Y, Zhou Q, Xie X (2010) Spatial, sources and risk assessment of heavy metal contamination of urban soils in typical regions of Shenyang, China. J Hazard Mater 174(1):455–462

    Article  CAS  Google Scholar 

  • Sun CY, Liu JS, Wang Y (2013) Multivariate and geostatistic analysis of the spatial distribution and sources of heavy metals in agricultural soil in Dehui, Northeast China. Chemosphere 92(5):517–523

    Article  CAS  Google Scholar 

  • Wang GY, Pan M, Liu XD (1992) On the relationship between the concentrations of elements in soil and the types of soil-forming parent material in Shandong Province, China. Acta Acta Sci Nat Univ Pekin 28(4):475–485 (in Chinese)

    CAS  Google Scholar 

  • Wang X, Sato T, Xing B (2005) Health risks of heavy metals to the general public in Tianjin, China via consumption of vegetables and fish. Sci Total Environ 350(1):28–37

    Article  CAS  Google Scholar 

  • Wang JJ, Zhao HW, Zhong XP, Kong SF, Liu YS, Zeng H (2011) Investigation of mercury levels in soil around a municipal solid waste incinerator in Shenzhen, China. Environ Earth Sci 64:1001–1010

    Article  CAS  Google Scholar 

  • Wang CL, Xia XQ, Zhao XQ (2012) Distribution and migration regularity of soil heavy metal pollution along the Xiaoqing watershed, Shandong Province. Geol China 39(2):530–538 (in Chinese)

    CAS  Google Scholar 

  • Wang F, Wu QY, Lv JS (2016) Spatial characteristics and environmental risk of heavy metals in typical gold mining area of Shandong Province. Environ Sci 37(8):3144–3150 (in Chinese)

    Google Scholar 

  • Xu XD, Cao ZM, Zhang ZX (2016) Spatial distribution and pollution assessment of heavy metals in the surface sediments of the Bohai and Yellow Seas. Mar Pollut Bull 110:596–602

    Article  CAS  Google Scholar 

  • Yalcin MG, Tumuklu A, Sonmez M (2010) Application of multivariate statistical approach to identify heavy metal sources in bottom soil of the Seyhan River (Adana), Turkey. Environ Monit Assess 164:311–322

    Article  CAS  Google Scholar 

  • Yang P G, Mao R Z, Shao H B, Gao Y (2009) An investigation on the distribution of eight hazardous heavy metals in the suburban farmland of China. J Hazard Mater 167: 1246-1251

  • Yuan X, Zhang L, Li J, Wang C (2014) Sediment properties and heavy metal pollution assessment in the river, estuary and lake environments of a fluvial plain, China. Catena 119:52–60

    Article  CAS  Google Scholar 

  • Zhang CS (2006) Using multivariate analyses and GIS to identify pollutants and their spatial patterns in urban soils in Galway, Ireland. Environ Pollut 142:501–511

    Article  CAS  Google Scholar 

  • Zhang CS, Tang Y, Luo L, Xu WL (2009) Outlier identification and visualization for Pb concentrations in urban soils and its implications for identification of potential contaminated land. Environ Pollut 157:3083–3090

    Article  CAS  Google Scholar 

  • Zhao Y, Wang ZG, Sun WX (2010) Spatial interrelations and multi-scale sources of soil heavy metal variability in a typical urban-rural transition area in Yangtze River Delta region of China. Geoderma 156:216–227

    Article  CAS  Google Scholar 

  • Zhu JX, Wang QF, Yu HL (2016) Heavy metal deposition through rainfall in Chinese natural terrestrial ecosystems: evidences from national-scale network monitoring. Chemosphere 164:128–133

    Article  CAS  Google Scholar 

Download references

Funding

This study was jointly supported by the National Natural Science Foundation of China (No.41601549, 41701604), Natural Science Foundation of Shandong Province (No.ZR2016DQ11), and Open Foundation of Estuarine and Coastal State Key Laboratory (SKLEC-KF201710).

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Authors and Affiliations

  1. College of Geography and Environment, Shandong Normal University, Jinan, 250014, China

    Jianshu Lv & Yuanhe Yu

  2. State Key Laboratory of Estuarine and Coastal Research, East China Normal University, Shanghai, 200062, China

    Jianshu Lv

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  1. Jianshu Lv
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  2. Yuanhe Yu
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Correspondence to Jianshu Lv.

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Responsible editor: Severine Le Faucheur

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Lv, J., Yu, Y. Source identification and spatial distribution of metals in soils in a typical area of the lower Yellow River, eastern China. Environ Sci Pollut Res 25, 21106–21117 (2018). https://doi.org/10.1007/s11356-018-2256-z

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