Abstract
This article deals with analytical chemistry devoted to nano-objects. A short review presents nano-objects, their singularity in relation to their dimensions, genesis, and possible transformations. The term nano-object is then explained. Nano-object characterization activities are considered and a definition of nanoanalytics is proposed. Parameters and properties for describing nano-objects on an individual scale and on the scale of a population are also presented. They enable the specificities of analytical activities to be highlighted in terms of multi-criteria description strategies and observation scale. Special attention is given to analytical methods, their dimensioning and validation.
Similar content being viewed by others
References
Amarjargal A, Tijing LD, Pant HR, Park C-H, Kim CS (2012) Simultaneous synthesis of TiO2 microrods in situ decorated with Ag nanoparticles and their bactericidal efficiency. Curr Appl Phys 12:1106–1112
Anderson W, Kozak D, Coleman VA, Jämting AK, Trau M (2013) A comparative study of submicron sizing platforms: accuracy, precision and resolution analysis of polydisperse particle size distributions. J Colloid Interface Sci 405:322–330
Antoniak C, Spasova M, Trunova A, Fauth K, Farle M, Wende H (2009) Correlation of magnetic moments and local structure of FePt nanoparticles. J Phys: Conference Series 190:1–11
Baalousha M, Motelica-Heino M, Galaup S, Le Coustumer P (2005) Supramolecular structure of humic acids by TEM with improved sample preparation and staining. Microsc Res Tech 66:299–306
Baalousha M, Kammer FV, Motelica-Heino M, Baborowski M, Hofmeister C, Le Coustumer P (2006) Size-based speciation of natural colloidal particles by flow field flow fractionation, inductively coupled plasma-mass spectrometry, and transmission electron microscopy/X-ray energy dispersive spectroscopy: colloid
s-trace element interaction. Environ Sci Technol 40:2156–2162Beija M, Salvayre R, Lauth-de Viguerie N, Marty J-D (2012) Colloidal systems for drug delivery: from design to therapy. Trends Biotechnol 30(9):485–496
Bian S-W, Mudunkotuwa IA, Rupasinghe T, Grassian VH (2011) Aggregation and dissolution of 4 nm ZnO nanoparticles in aqueous environments: influence of pH, ionic strength, size, and adsorption of humic acid. Langmuir 27:6059–6068
Boyd RD, Pichaimuthu SK, Cuenat A (2011) New approach to inter-technique comparisons for nanoparticle size measurements using atomic force microscopy, nanoparticle tracking analysis and dynamic light scattering. Colloids Surf A Physichem Eng Asp 387:35–42
Buffle J, van Leeuwen HP (eds) (1992) Environmental particles. Environmental Analytical and Physical Chemistry Series, CRC Press
Buchberger W, Lindner W (2010) Editorial: Euroanalysis XV, 2009: the European conference on analytical chemistry. Anal Bioanal Chem 397(1):5–6
Busch J, Meichner T, Potthoff A, Bleyl S, Georgi A, Macknenzie K, Trabitzsch R, Werban U, Oswald SE (2015) A field investigation on the transport of carbon-supported nanoscale zero-valent iron (nZVI) in groundwater. J Contam Hydrol 181:59–68
Buzea C, Pacheco II, Robbie K (2007) Nanomaterials and nanoparticles: sources and toxicity. Biointerphases 2(4):17–71
Caballero-Díaz E, Valcárcel Cases M (2016) Analytical methodologies for nanotoxicity assessment. TrAC Trends Anal Chem 84:160–171
Chang M-H, Dosev D, Kennedy IM (2007) ζ-potential analyses using micro-electrical field flow fractionation with fluorescent nanoparticles. Sensors Actuators 124(1):172–178
Chauhan S, Kumar M, Chhoker S, Kaytal SC (2017) A comparative study on structural, vibrational, dielectric and magnetic properties of microcrystalline BiFeO3, nanocrystalline BiFeO3 and core-shell structured BiFeO3@SiO2 nanoparticles. J Alloys Compounds 666:454–467
Chevigny C, Dalmas F, Di Cola E, Gigmes D, Bertin D, Boue F, Jestin J (2011) Polymer-grafted-nanopartciles nanocomposites: dispersion, grafted chain conformation, and rheological behavior. Mcromolecules 44(1):122–133
Ciobanu CS, Iconaru SL, Le Coustumer P, Predoi D (2013) Vibrational investigations of silver-doped hydroxyapatite with antibacterial properties. J Spectroscopy:1:1–1:5
Contado C, Blo G, Conato C, Dondi F, Beckett R (2003) Experimental approaches for size-based metal speciation in rivers. J Environ Monit 5(6):845–851
Contado C, Pagnoni A (2010) TiO2 nano- and micro-particles in commercial foundation creams: field flow-fractionation techniques together with ICO-AES and SQW voltammetry for their characterisation. Anal Meth 2(8):1112–1124
Contado C (2017) Field flow fractionation techniques to explore the “nano-world”. Anal Bianal Chem 409(10):2501–2518
De Jalon EG, Blanco-Prieto MJ, Ygartua P, Santoyo S (2001) PLGA microparticles: possible vehicles for topical drug delivery. Int J Pharm 226(1–2):181–184
Donovan AR, Adams CD, Ma Y, Stephan C, Eichholz T, Shi H (2016) Single particle ICP-MS characterization of titanium dioxide, silver, and gold nanoparticles during drinking water treatment. Chemosphere 144: 148–153
Dubascoux S, Le Hecho I, Potin-Gautier M, Lespes G (2008) On-line and off-line quantification of trace elements associated with colloids by As-Fl-FFF and ICP-MS. Talanta 77:60–65
Dwivedi AD, Dubey SP, Sillanpää M, Kwon Y-N, Lee C, Varma RS (2015) Fate of engineered nanoparticles: implications in the environment. Coord Chem Rev 287:64–68
Edwards T, Gale BK, Frazier AB (2001) Micro scale sample preparation systems for biological analysis. Biomed Microdevices 3(3):211–218
El Hadri H, Gigault J, Chery P, Potin-Gautier M, Lespes G (2014) Optimization of flow field-flow fractionation for the characterization of natural colloids. Anal Bioanal Chem 406:1639–1649
Fadeel B, Garcia-Bennett AE (2010) Better safe than sorry: understanding the toxicological properties of inorganic nanoparticles manufactured for biomedical applications. Adv Drug Deliv Rev 62(3):362–374
Faucher S, Lespes G (2017) Field flow fractionation methods for the characterization of natural nanoparticles in waters and soils. Field flow fractionation: principles and applications, Wiley-VCH, in press
Faucher S, Charron G, Sivry Y, Lespes G (2017) Characterizing nanoscale objects: how can flow field-flow fractionation meet this challenge, SEP19, 28–30th of March 2017, Paris, France
Ferreira da Silva B, Pérez S, Gardinalli P, Singhal RK, Mozeto AA, Barcelo D (2011) Analytical chemistry of metallic nanoparticles in natural environments. Trends Anal Chem 30(3):528–540
Ferrouillat S, Bontemps A, Poncelet O, Soriano O, Gruss J-A (2013) Influence of nanoparticle shape on convestive heat transfer and energetic performance of water-based SiO2 and ZnO nanofluids. Appl Therm Eng 51:839–851
Freiman S, Hooker S, Migler K, Arapalli S (2008) Measurement issues in single wall carbon nanotubes, NIST Materials Science and Engineering Laboratory and NASA-DSC, Special publication 960–19
Gavankar S, Suh S, Keller AF (2012) Life cycle assessment at nanoscale: review and recommandation. Int J Life Cycle Assess 17:295–303
Gavilan H, Posth O, Bogart LK, Steinhoff U, Gutiérrez L, Morales MP (2017) How shape and internal structure affect the magnetic properties of anisometric magnetite nanoparticles. Acta Materials 125:416–424
Gigault J, Gale BK, Le Hecho I, Lespes G (2011) Nanoparticle characterization by cyclical electrical field-flow fractionation. Anal Chem 83:6565–6572
Giri PK, Bhattacharyya S, Singh DK, Kesavamoorthy R, Panigrahi BK, Nair KGM (2007) Correlation between microstructure and optical properties of ZnO nanoparticles synthetized by ball milling. J Appl Phys 102(9):93515
Green MJ, Behabtu N, Pasquali M, Adams WW (2009) Nanotubes as polymers. Polymer 50(21):4979–4997
Grolimund D, Barmettler K, Borkovec M (2007) Colloidal facilitated transport in natural porous media: Fundamental phenomena and modelling. Colloidal transport in porous media. F. H. Frimmel, F. V. D. Kammer and H. C. Flemming. Berlin, Springer 291
Harmand B (1996) Contribution à la compréhension des processus de transport de colloïdes en milieu naturel poreux ou fracturé. Application à la rétention de particules de latex dans un sable, Thèse de doctorat de l’Institut National polytechnique de Lorraine, p 271
Hirano S (2009) A current overview of health effect research on nanoparticles. Environ Health Prev Med 14(4):223–225
Hetzer B, Burcza A, Gräf V, Walz E, Greiner R (2017) Online-coupling of AF4 and single particle-ICPMS as an analytical approach for the selective detection of nanosilver release from model food packaging films into food simulants. Food Control 80: 113–124
ISO/NP TS 800000-4 4: 2011(en) Nanotechnologies-Vocabulary-Part 4: Nanostructured materials (2011) 7pp
ISO/TS 80004-2: 2015 Nanotechnologies-Vocabulary-Part 2: Nano-objects (2015) 10 pp
Ju-Nam Y, Lead JR (2008) Properties, sources, pathways, and fate of nanoparticles in the environment, manufactured nanoparticles: an overview of their chemistry, interactions and potential environmental implications. Sci Total Environ 400(1–3):396–414
Ju-Nam Y, Lead JR (2016), Manufactured nanoparticles: an overview of their chemistry, interactions and potential environmental implications. Engineered nanoparticles and the Environment: Biophysicochemical Processes and Toxicity, Wiley & Sons, vol 1, 8: 95–117
Kaptay G (2012) On the size and shape dependence of the solubility of nano-particles in solutions. Int J Pharm 430:253–257
Kestens V, Bozatzidis V, De Tmmerman P-J, Ramaye Y, Roebben G (2017) Validation of a particle tracking analysis method for the size determination of nano- and micro-particle, J Nanopart Res 19:271 (16pp)
Kiseleva IN (2007) The annual session of the council. J Anal Chem 62:906–908
Klucakova M, Kalina M (2015) Composition, particle size, charge, and colloidal stability of pH-fractionated humic acids. J Soils Sediments 15:1900–1908
Kretzschmar R, Sticher H, Hesterberg D (1997) Effects of adsorbed humic acid on surface charge and floculation of kaolinite. Soil Sci Soc Am J 61:101–108
Kumar A, Dhawan A (2013) Genotoxic and carcinogenic potential of engineered nanoparticles: an update. Arch Toxicol 87:1883–1900
Kumar S, Nehra M, Deep A, Kedia D, Dilbaghi N, Kim K-H (2017) Quantum-sized nanomaterials for solar cell applications. Renew Sust Energ Rev 73:821–839
Kystek P, Bäuerlein PS, kooij PJF (2015) Analytical assesment about simultaneous quantification of releasable phramaceutical relevant inorganic nanoparticles in tap water and domestic waste water. J Pharm Biomed Anal 106:116–123
Laborda F, Bolea E, Jimez-Lamana J (2016) Single particle inductively coupled plasma mass spectrometry for the analysis of inorganic engineered nanoparticles in environmental samples. Trends in Environmental Analytical Chemistry 9:15–23
Leach RK, Claverley J, Giusca C, Jones CW, Nimishakavi L, Sun W, Tedaldi M, Yacoot A (2012) Advances in engineering nanometrology at the National Physical Laboratory. Meas Sci Technol 23(7):074002
Le Coustumer P, Monthioux M, Oberlin A (1993) Understanding Nicalon fibre. J Eur Ceram Soc 11:95–103
Lee S, Bi X, Reed RB et al (2014) Nanoparticle size detection lim- its by single particle ICP-MS for 40 elements. Environ Sci Technol 48:10291–10300
Lemine OM, Bououdina MSM, Al-Saie AM, Shafi M, Khatab A, Al-hilali M, Henini M (2011) Synthesis, structural, magnetic and optical properties of nanocrystalline ZnFe2O4. Phys B: Cond Mat 406:1989–1994
Lespes G (2016a) Nanoparticles in environment and health effect. Metallomics: Analytical Techniques and Speciation Methods. In: Metallomics. Wiley-VCH Verlag GmbH & Co. KGaA, pp 319–337. https://doi.org/10.1002/9783527694907.ch11
Lespes G (2016b) Nanoparticules et particules colloïdales. L’analyse de l’eau, Dunod, Part 1 A3–4: 73–81
Lespes G, Gigault J (2011) Hyphenated analytical techniques for multidimensional characterization of submicron particles: a review. Anal Chim Acta 692:26–41
Li W, He Y, Wu J, Xu J (2012) Extraction and characterization of natural soil nanoparticles from Chinese soils. J Soil Sci 63(5):754–761
Liu J, Detrembleur C, Mornet S, Jérôme C, Duguet E (2015) Design of hybrid nanovehicles for remotely triggered drug release: an overview. J Mater Chem B 3:6117–6147
Liz-Marzan LM (2004) Nanomaterials: formation and color. Mater Today 7(2):26–31
Lojkowski W, Turan R, Proykiva A, Daniszewska A (Eds) (2006) Nanometrology, Nanoforum report on nanotechnology in Europe, nanoparticlesorg, P 127
Loosli F, Le Coustumer P, Stoll S (2013) TiO2 nanoparticles aggregation and disaggregation in presence of alginate and Suwannee River humic acids. pH and concentration effects on nanoparticle stability. Water Res 47:6052–6063
Loosli F, Le Coustumer P, Stoll S (2015) Effect of electrolyte valency, alginate concentration and pH on engineered TiO2 nanoparticle stability in aqueous solution. Sci Total Environ 535:28–34
Lozano-Perez S, de Castro Bernal V, Nicholls RJ (2009) Achieving sub-nanometre particle mapping with energy-filtered TE. Ultramicroscopy 109:1217–1228
Lysenko VG, Soloviov VV, Lukinovivh PN, Zolotarevskii SY, Gubskii KL (2011) Nanometrology and features of metrological assurance of measurements of the roughness and relief parameters of nanostructured surfaces. Meas Tech 53:1215–1221
Lòpez Martinez MC, Rodes V, Garcia de la Torre J (1984) Estimation of the shape and size of fibrinogen in solution from its hydrodynamic properties using theories for bead models and cylinders. Int J Biol Macromol 6:261–265
Maurice PA, and Hochella MF (2008) Nanoscale particles and processes: a new dimension in soil science, vol. 100, Academic Press 123–153
McCarthy JF, Zachara JF (1989) Subsurface transport of contaminants. Environ Sci Technol 23(5):496–502
Mitrano DM, Barber A, Bednar A, Westerhoff P, Higgins CP, Ranville JF (2012) Silver nanoparticlecharacterization using single particle ICP-MS (SP-ICP-MS) and asymmetrical flow field flow fractionation ICP-MS (AF4-ICP-MS). J Anal At Spectrom 27: 1131–1142
Moore D (2002) Analytical chemistry—a discipline at the heart of IUPAC. Chem Int 24(4):1–9
Moskal A, Payatakes AC (2006) Estimation of the diffusion coefficient of aerosol particle aggregates using Brownian simulation in the continuum regime. Aerosol Sci 37:1081–1101
Navarro E, Baun A, Behra R, Hartmann NB, Filser J, Miao A-J, Quigg A, Santschi PH, Sigg L (2008) Environmental behaviour and ecotoxicity of engineered nanoparticles to algae, plants, and fungi. Ecotoxicology 17:372–386
Nowack B, Bucheli TD (2007) Occurrence, behavior and effects of nanoparticles in the environment. Env Poll 150:5–22
Oxley MP, Lupini AR, Pennycook S (2016) Ultra-high resolution electron microscopy. Rep Prog Phys 80(2):026101. https://doi.org/10.1088/1361-6633/80/2/026101
Palomino D, Yamunake C, Le Coustumer P, Stoll S (2013) Stability of TiO2 nanoparticles in presence of fulvic acids, importance of pH. J Colloid Sci Biotechnol 2(1):1–8
Pan B, Xing B (2012) Applications and implications of manufactured nanoparticles in soil: a review. Eur J Soil Sci 63:437–456
Peeters K, Lespes G, Zuliani T, Scancar J, Milacic R (2016) The fate of iron nanoparticles in environmental waters treated with nanoscale zero-valent iron, feONPs and Fe3O4NPs. Wat Res 94:315–327
Pelley AJ, Tufenkji N (2008) Effect of particle size and natural organic matter on the migration of nano- and microscale latex particles in saturated porous media. J Coll Interf Sci 321:74–83
Pitkänen L, Striegel AM (2016) Size-exclusion chromatography of metal nanoarticles and quantum dots. Trends Analyt Chem 80:311–320
Ryan JN, Elimelech M (1996) Colloid mobilization and transport in groundwater, colloids surfaces. Physicochem Eng Asp 107:1–56
Sadik OA, Kariuki V, Okello V, Bushlyar V (2014) Current and emerging technologies for the characterization of nanomaterials. ACS Sustain Chem 2:1707–1716
Saito R, Fujita M, Dresselhaus G, Dresselhaus M (1992) Electronic structure of chiral graphen tubules. Appl Phys Lett 60(18):2204–2206
Soulé S, Bulteau A-L, Faucher S, Haye B, Aimé C, Allouche J, Dupin J-C, Lespes G, Coradin T, Martinez H (2016) Design and cellular fate of bioinspired Au-Ag Nanoshells@hybrid silica nanoparticles. Langmuir 32:10073–10082
Santos Silva H, Rivaton A, Bégué D, Hiorns RC (2015) Correlating geometry of multidiemensional carbon allotropes molecules and stability. Org Electron 26:395–399
Schurtenberg P, Newman ME (1993) Characterization of biological and environmental particles using static and dynamic light scattering. In: Buffle J, van Leeuwen HP (eds) Environmental particles, Vol. 2, IUPAC environmental analytical and physical chemistry series. Lewis, Boca Raton, pp 37–115
Sedykh EM, Zuev BK, Gorkin PA (2011) Moscow workshop on analytical chemistry in 2010. J Anal Chem 66(9):876–879
Stone V, Nowack B, Baun A, van den Brink N, von der Kammer F, Dusinska M, Handy R, Hankin S, Hassellov M, Joner E, Fernandes TF (2010) Nanomaterials for environmental studies: classification, reference material issues, and strategies for physic-chemical characterisation. Sci Total Environ 408:1745–1754
Van Tendeloo G, Bals S, Van Aert S, Verbeecl J, Van Dyck D (2012) Advanced electron microscopy for advanced materials. Adv Mater 24:5655–5675
Thomas JM, Leary RK, Eggeman AS, Midgley PA (2015) The rapidly changing face of electron microscopy. Chem Phys Lett 631-632:103–113
Till U, Gaucher M, Amouroux B, Gineste S, Lonetti B, Marty J-D, Mingotaud C, Bria CRM, Ratanathanawongs Williams SK, Violleau F, Mingotaud A-F (2017) Frit inlet field-flow fractionation techniques for the characterization of polyion complex self-assemblies. J Chromatogr A 1481:101–110
Tri N, Caldwell K, Beckett R (2000) Development of electrical field-flow fractionation. Anal Chem 72(8):1823–1829
Valcárcel M, Simonet BM, Cárdenas S (2008) Analytical nanoscience and nanotechnology today and tomorrow. Anal Bioanal Chem 391(5):1881–1887
Van Hee P, Hoeben MA, van der Lans RGJM, van der Wielen LAM (2006) Strategy for selection of methods for separation of bioparticles from particle mixture. Biotechnol Bioeng 94(4):689–709
Wang C, Chi M, Wang G, van der Vliet D, Li D, More K, Wang H-H, Schlueter JA, Markovic NM, Stamenkovic VR (2011) Correlation between surface chemistry and electrocatalytic properties of monodisperses PtxNi1-X nanoparticles, Adv Funct Mater 21(1): 147–152
Zattoni A, Roda B, Borghi F, Marassi V, Reschiglian P (2014) Flow field-flow fractionation for the analysis of nanoparticles used in drug delivery. J Pharm Biomed Anal 87:53–61
Zolotov YA (2007) Analytical chemistry: the day today. J Anal Chem 62:912–917
Zolotov YA (2010) Nanoanalytics. J Anal Chem 65:1207–1208
Author information
Authors and Affiliations
Corresponding author
Additional information
Responsible editor: Philippe Garrigues
Rights and permissions
About this article
Cite this article
Faucher, S., Le Coustumer, P. & Lespes, G. Nanoanalytics: history, concepts, and specificities. Environ Sci Pollut Res 26, 5267–5281 (2019). https://doi.org/10.1007/s11356-018-1646-6
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11356-018-1646-6