Abstract
Two methods of recovering nitrogen from liquid side streams are presented in this paper. The first method was demonstrated at an ammonia stripping plant treating 5–7 m3/h sludge water at the wastewater treatment plant (WWTP) Kloten-Opfikon (CH). In addition to the usual stripping and scrubbing columns, a third column had been added in order strip CO2, thus reducing the NaOH-demand of the subsequent ammonia stripping. At first, just the stripping plant was put into operation and optimized without any pre-treatment of the supernatant. Next, the CO2-stripper column was activated and optimized by gas measurements to minimize free ammonia losses, heat losses, and energy consumption. Key operational aspects of the plant were evaluated. Finally, up to 1.4 m3/h source-separated urine was successfully fed into the stripping facility. The second ammonia removal method using hydrophobic hollow fiber membranes was tested in two small pilot systems by different manufacturers in 2012 and 2013 at WWTP Neugut. In this technology, free ammonia gas in the sludge liquid diffuses at pH >9.3 from the sludge liquid through the air-filled pores of the microporous hydrophobic membrane into concentrated sulfuric acid flowing through the hollow fibers, forming ammonium sulfate. The small pore size and the hydrophobic nature of the membrane prevent the liquid phase from entering into the pores due to the surface tension effect. Practical experience regarding operational parameters like wastewater flow rate, pH, temperature, ammonia concentration, fouling and precipitations processes, optimal flow schemes, and process configurations was collected.
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Acknowledgments
This work was supported by the EU ROUTES project (Contract No 265156, FP7 2007-2013, THEME [ENV.2010.3.1.1-2] Innovative system solutions for municipal sludge treatment and management).
The authors would like to express their thanks to the operators of the wastewater treatment plants Kloten/Opfikon, Neugut, and Altenrhein for their support of our research.
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Boehler, M.A., Heisele, A., Seyfried, A. et al. (NH4)2SO4 recovery from liquid side streams. Environ Sci Pollut Res 22, 7295–7305 (2015). https://doi.org/10.1007/s11356-014-3392-8
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DOI: https://doi.org/10.1007/s11356-014-3392-8