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Mizoroki–Heck cross-coupling reactions using palladium immobilized on DABCO-functionalized silica

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Abstract

A heterogeneous palladium catalyst supported on silica modified by DABCO has been prepared by post-synthetic modification of silica gel. This heterogeneous catalytic system exhibits high activity and stability in the Mizoroki–Heck cross-coupling reaction of various aryl halides with olefins. The reaction proceeds efficiently under efficiently under mild mild reaction conditions and high yield, with the formation of E-isomers selectively. Moreover, we successfully established a gram-scale synthesis, and the catalyst was reused for up to ten catalytic cycles.

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Acknowledgements

Author Sanjay Jadhav thanks the University Grants Commission, New Delhi, India, for the award of SAP-BSR fellowship.

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Authors and Affiliations

  1. Department of Chemistry, Shivaji University, Kolhapur, M.S., 416004, India

    Sanjay Jadhav & Rajashri Salunkhe

  2. Department of Chemistry, P.D.V.P. College, Tasgaon, M.S., 416312, India

    Seema Patil & Arjun Kumbhar

  3. Department of Chemistry, Yashvantrao Chavan Institute of Science, Satara, M.S., 415001, India

    Santosh Kamble

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  1. Sanjay Jadhav
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  2. Seema Patil
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  3. Arjun Kumbhar
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  4. Santosh Kamble
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  5. Rajashri Salunkhe
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Correspondence to Rajashri Salunkhe.

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Jadhav, S., Patil, S., Kumbhar, A. et al. Mizoroki–Heck cross-coupling reactions using palladium immobilized on DABCO-functionalized silica. Transit Met Chem 44, 507–514 (2019). https://doi.org/10.1007/s11243-019-00308-4

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