Skip to main content
SpringerLink
Log in

Assembling of transitional metal CuII and MnII with 4-pyridin-2-yl-pyrimidine-2-sulfonate adjusted by anions

  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

Abstract

Reactions of sodium 4-pyridin-2-yl-pyrimidine-2-sulfonate (NaL) with CuII and MnII ions in water produced a zig-zag chain polymer, [CuL(NCS)] n (1), and a dinuclear complex, [Mn2L2Cl2(H2O)2] (2), respectively. It is observed that counteranions and hydrogen bonds play basic roles in the resulting structure in which 3D networks were formed through intermolecular hydrogen bonding.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Moulton B. and Zaworotko M.J. (2001). Chem. Rev. 101: 1629

    Article  PubMed  CAS  Google Scholar 

  2. Bu X.H., Chen W., Lu S.L., Zhang R.H., Liao D.Z., Bu W.M., Shionoya M., Brisse F. and Ribas J. (2001). Angew. Chem. Int. Ed. Engl. 40: 3201

    Article  CAS  Google Scholar 

  3. Bradshaw D., Claridge J.B., Cussen E.J., Prior T.J. and Rosseinsky M.J. (2005). Acc. Chem. Res. 38: 273

    Article  PubMed  CAS  Google Scholar 

  4. Mitiz D.B., Wang S., Field C.A., Chess C.A. and Guloy A.M. (1995). Science 267: 1473

    Article  ADS  Google Scholar 

  5. Wang S., Mitiz D.B., Field C.A., Chess C.A. and Guloy A.M. (1995). J. Am. Chem. Soc. 117: 5297

    Article  CAS  Google Scholar 

  6. Su W.P., Hong M.C., Weng J.B., Cao R. and Lu S.F. (2000). Angew. Chem. Int. Ed. Engl. 39: 2911

    Article  PubMed  CAS  Google Scholar 

  7. J.S. Miller and A.J. Epstein, Chem. Commun., 1319 (1998).

  8. Hoskins B.F. and Robson R. (1990). J. Am. Chem. Soc. 112: 1546

    Article  CAS  Google Scholar 

  9. Carlucci L., Ciani G., Proserpio D.M. and Sironi A. (1995). J. Am. Chem. Soc. 117: 4562

    Article  CAS  Google Scholar 

  10. Park K.M., Moon S.T., Kang Y.J., Kim H.J., Seo J. and Lee S.S. (2006). Inorg. Chem. Commun. 9: 671

    Article  CAS  Google Scholar 

  11. Zhang X.J., Zhou X.P. and Li D. (2006). Cryst. Growth Des. 6: 1440

    Article  CAS  Google Scholar 

  12. H.B. Zhu, H.Z. Dong, W. Huang and S.H. Gou, J. Mol. Struct. DOI: 10.1016/j.molstruc.2006.07.023.

  13. Siemens, SAINT v4 Software Reference Manual, Siemens Analytical X-Ray Systems, Inc., Madison, Wisconsin, USA, (1996).

  14. G.M. Sheldrick, SADABS, Program for Empirical Absorption Correction of Area Dectector Data, Univ. of Gottingen, Germany, (1996).

  15. Siemens, SHELXTL, Version 5 Reference Manual, Siemens Analytical X-Ray Systems, Inc., Madison, Wisconsin, USA, (1996).

  16. T.S. Lobana, I. Kinoshita, K. Kimura, T. Nishioka, D. Shiomi and K. Isobe, Eur. J. Inorg. Chem., 356 (2004).

  17. Shi X.S., Liu C.S., Li J.R., Guo Y., Zhou J.N. and Bu X.H. (2005). J. Mol. Struct. 754: 71

    Article  CAS  Google Scholar 

  18. (a) E. Sinn, J. Chem. Soc., Dalton Trans., 162 (1975). (b) F.H. Köhler, N. Hebendanz, U. Thewalt, B. Kanellakopulos and R. Klenze, Angew. Chem. Int. Ed. Engl., 23, 721 (1984). (c) A. Garoufis, S. Kasselouri, S. Boyatzis and C. P. Raptopoulou,Polyhedron., 18, 1615 (1999). (d) G.A. Albada, A. Mohamadou, W.L. Driessen, R. Gelder, S.Tanase and J. Reedijk. Polyhedron., 23, 2387 (2004).

Download references

Author information

Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, 210093, China

    Huaze Dong, Xia Liu, Juan Yang, Zhaolian Chu, Wei Huang & Shaohua Gou

Authors
  1. Huaze Dong
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Xia Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Juan Yang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Zhaolian Chu
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Wei Huang
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Shaohua Gou
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Shaohua Gou.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Dong, H., Liu, X., Yang, J. et al. Assembling of transitional metal CuII and MnII with 4-pyridin-2-yl-pyrimidine-2-sulfonate adjusted by anions. Transition Met Chem 32, 518–522 (2007). https://doi.org/10.1007/s11243-007-0199-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11243-007-0199-1

Keywords

Search

Navigation