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β-Diketonates of Cyclopalladated Arylazonaphthalenes: Synthesis, Characterization and Redox Activity

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Abstract

The synthesis of monomeric mixed species of the type [PdLK] (L = cyclopalladated arylazonaphthalenes) have been achieved by splitting the halogeno-bridge in [Pd2L2Cl2] by β-diketones (HK). The compounds have been characterized on the basis of spectral (IR, UV–VIS, FAB mass, 1H and 13C{1H}NMR) and elemental analysis data. Some of the [PdLK] cyclometallates occur as isomeric mixtures whose composition have been established by 1H-NMR data. Electron transfer properties of the cyclopalladates in DMF have been thoroughly examined using cyclic voltammetry.

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Authors and Affiliations

  1. Department of Chemistry, University of North Bengal, Siliguri, Darjeeling, 734013, India

    Rupa Bhawmick, Purak Das, Suvra Acharya, Achintesh Narayan Biswas & Pinaki Bandyopadhyay

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  1. Rupa Bhawmick
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  2. Purak Das
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  3. Suvra Acharya
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  4. Achintesh Narayan Biswas
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  5. Pinaki Bandyopadhyay
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Correspondence to Pinaki Bandyopadhyay.

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Bhawmick, R., Das, P., Acharya, S. et al. β-Diketonates of Cyclopalladated Arylazonaphthalenes: Synthesis, Characterization and Redox Activity. Transition Met Chem 31, 495–499 (2006). https://doi.org/10.1007/s11243-006-0024-2

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