It was shown that the epoxidation of 1-octene by tert-butyl hydroperoxide in the presence of Mo2B is accompanied by the formation of an amorphous oxygen-containing phase on its surface. It was established that this is the phase that catalyzes the reaction and determines its speed and selectivity.
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Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 54, No. 6, pp. 377-382, November-December, 2018.
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Nykypanchuk, M.V., Komarenskaya, Z.M. & Zhukrovskaya, M.O. Effect of the Phase Composition of Molybdenum Boride on its Catalytic Properties in the Epoxidation of 1-Octene by tert-Butyl Hydroperoxide. Theor Exp Chem 54, 407–413 (2019). https://doi.org/10.1007/s11237-019-09588-4
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DOI: https://doi.org/10.1007/s11237-019-09588-4