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Effect of Phase Composition of Superconductor Y3Ba5Cu8O18+δ on Its Conducting Characteristics

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Theoretical and Experimental Chemistry Aims and scope

The effect of the method of synthesis on the crystallographic parameters, electrical properties, and oxygen nonstoichiometry of superconducting cuprate with nominal composition Y3Ba5Cu8O18+δ was investigated. The samples were synthesized by a solid state reaction (sample A), by coprecipitation of the hydroxocarbonates (sample B), and by the sol–gel technique (sample C). According to data from X-ray diffraction (XRD) and the temperature dependence of the specific resistance a single-phase superconductor is formed in the sol–gel method and has the highest critical temperature for transition to the superconducting state (Tc = 95 K), whereas samples A and B contain impurity phases and have lower critical temperatures for transition (92 and 87 K, respectively).

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Authors and Affiliations

  1. Taras Shevchenko National University of Kyiv, Vul. L’va Tolstoho, 12, Kyiv, 01033, Ukraine

    A. O. Pilipenko, S. A. Nedilko, A. G. Dziazko & I. V. Fesich

Authors
  1. A. O. Pilipenko
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  2. S. A. Nedilko
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  3. A. G. Dziazko
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  4. I. V. Fesich
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Correspondence to A. O. Pilipenko.

Additional information

Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 52, No. 6, pp. 342-347, November-December, 2016.

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Pilipenko, A.O., Nedilko, S.A., Dziazko, A.G. et al. Effect of Phase Composition of Superconductor Y3Ba5Cu8O18+δ on Its Conducting Characteristics. Theor Exp Chem 52, 342–348 (2017). https://doi.org/10.1007/s11237-017-9488-8

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  • DOI: https://doi.org/10.1007/s11237-017-9488-8

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