Russian Journal of Organic Chemistry

, Volume 41, Issue 10, pp 1473–1480 | Cite as

Polynomial Dependence for the Calculation of Vaporization Enthalpies of Organophosphorus Compounds

  • E.V. Sagadeev
  • Yu. G. Safina
  • R. A. Cherkasov


Enthalpies of vaporization of organic phosphorus compounds are related to the normal-pressure boiling points through a polynomial dependence. Each class of organophosphorus compounds is characterized by its own specific parameters of the general dependence. The polynomial dependences may be used for the calculation of vaporization enthalpies of organophosphorus compounds with different modes of phosphorus coordination.


Phosphorus Enthalpy Organic Chemistry Boiling Boiling Point 
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  1. 1.
    Cox, J.D. and Pilcher, Y., Thermochemistry of Organic and Organometallic Compounds, London: Academic, 1970.Google Scholar
  2. 2.
    Solomonov, B.N. and Konovalov, A.I., Usp. Khim., 1991, vol. 60, p. 45.Google Scholar
  3. 3.
    Fuchs, R., Chambers, E., and Stephenson, W.K., Can. J. Chem., 1987, vol. 65, p. 2624.Google Scholar
  4. 4.
    Lebedev, Yu.A. and Miroshnichenko, E.A., Termokhimiya paroobrazovaniya organicheskikh veshchestv (Thermochemistry of Vaporization of Organic Substances), Moscow: Nauka, 1981.Google Scholar
  5. 5.
    Sagadeev, E.V. and Safina, Yu.G., Zh. Fiz. Khim., 2002, vol. 76, p. 1565.Google Scholar
  6. 6.
    Sagadeev, E.V. and Safina, Yu.G., Zh. Fiz. Khim., 2005, vol. 79, p. 427.Google Scholar
  7. 7.
    Ovchinnikov, V.V., Kudryavtsev, V.Yu., Lapteva, L.I., Khazieva, L.R., and Konovalov, A.I., Dokl. Ross. Akad. Nauk, 1997, vol. 354, p. 502.Google Scholar
  8. 8.
    Ovchinnikov, V.V., Khazieva, L.R., Lapteva, L.I., and Konovalov, A.I., Izv. Ross. Akad. Nauk, Ser. Khim., p. 32.Google Scholar
  9. 9.
    Ovchinnikov, V.V., Khazieva, L.R., Lapteva, L.I., and Konovalov, A.I., J. Mol. Liq., 2001, vol. 91, p. 47.Google Scholar
  10. 10.
    Lapteva, L.I., Doctoral (Chem.) Dissertation, Kazan, 2001.Google Scholar
  11. 11.
    Benson, S.W., Cruickshank, F.R., Golden, D.M., Haugen, G.R., O'Neal, H.E., Rodgers, A.S., Shaw, R., and Walsh, R., Chem. Rev., 1969, vol. 69, p. 279.CrossRefGoogle Scholar
  12. 12.
    Morachevskii, A.G. and Sladkov, I.B., Termodinamicheskie raschety v metallurgii (Thermodynamic Calculations in Metallurgy), Moscow: Metallurgiya, 1985.Google Scholar
  13. 13.
    Evers, E.C., Street, E.H., and Jung, S.L., J. Am. Chem. Soc., 1951, vol. 73, p. 5088.Google Scholar
  14. 14.
    Sagadeev, E.V. and Safina, Yu.G., Zh. Fiz. Khim., 2004, vol. 78, p. 2147.Google Scholar
  15. 15.
    Van Wazer, J.R., Phosphorus and Its Compounds, New York: Interscience, 1958, vol. 1; 1961, vol. 2.Google Scholar
  16. 16.
    Purdela, D. and Vilceanu, R., Chimia Compulsor Organici ai Fosforului si ai Acizilor lui, Bucuresti: Acad. Republicii Socialiste Romania, 1965.Google Scholar
  17. 17.
    Hartley, S.B., Holmes, W.S., Jaques, J.K., Mole, M.P., and McCoubrey, J.C., Quart. Rev. Chem. Soc., 1963, vol. 17, p. 204.CrossRefGoogle Scholar
  18. 18.
    Arshad, M. and Beg, A., Bull. Chem. Soc. Jpn., 1967, vol. 40, p. 15.Google Scholar
  19. 19.
    Laboratorni technika organicke chemie, Keil, B., Ed., Praha: Ceskoslovenske Akademie Ved, 1963.Google Scholar
  20. 20.
    Grigor'ev, A.A., Kondrat'ev, Yu.V., and Suvorov, A.V., Zh. Obshch. Khim., 1984, vol. 54, p. 1935.Google Scholar
  21. 21.
    Kirklin, D.R. and Domalski, E.S., J. Chem. Thermodyn., 1988, vol. 20, p. 743.Google Scholar
  22. 22.
    Ovchinnikov, V.V., Safina, Yu.G., Cherkasov, R.A., and Pudovik, A.N., Zh. Obshch. Khim., 1988, vol. 58, p. 2081.Google Scholar
  23. 23.
    Ovchinnikov, V.V., Makeeva, T.B., Lapteva, L.I., and Konovalov, A.I., Thermochim. Acta, 1996, vol. 277, p. 145.CrossRefGoogle Scholar
  24. 24.
    Reid, R.C., Prausnitz, J.M., and Sherwood, T.K., The Properties of Gases and Liquids, New York: McGraw-Hill, 1977, 3rd ed.Google Scholar
  25. 25.
    Sagadeev, E.V. and Barabanov, V.P., Zh. Fiz. Khim., 2004, vol. 78, p. 2119.Google Scholar

Copyright information

© MAIK "Nauka/Interperiodica" 2005

Authors and Affiliations

  • E.V. Sagadeev
    • 1
  • Yu. G. Safina
    • 1
  • R. A. Cherkasov
    • 2
  1. 1.Kazan State Technological UniversityKazan, TatarstanRussia
  2. 2.Kazan State UniversityKazan, TatarstanRussia

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