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Polynomial Dependence for the Calculation of Vaporization Enthalpies of Organophosphorus Compounds

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Abstract

Enthalpies of vaporization of organic phosphorus compounds are related to the normal-pressure boiling points through a polynomial dependence. Each class of organophosphorus compounds is characterized by its own specific parameters of the general dependence. The polynomial dependences may be used for the calculation of vaporization enthalpies of organophosphorus compounds with different modes of phosphorus coordination.

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Dedicated to Full Member of the Russian Academy of Sciences N.S. Zefirov on His 70th Anniversary

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Translated from Zhurnal Organicheskoi Khimii, Vol. 41, No. 10, 2005, pp. 1503–1510.

Original Russian Text Copyright © 2005 by Sagadeev, Safina, Cherkasov.

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Sagadeev, E., Safina, Y.G. & Cherkasov, R.A. Polynomial Dependence for the Calculation of Vaporization Enthalpies of Organophosphorus Compounds. Russ J Org Chem 41, 1473–1480 (2005). https://doi.org/10.1007/s11178-005-0369-6

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  • DOI: https://doi.org/10.1007/s11178-005-0369-6

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