Abstract
Decomposition of methyl 5-(4-nitrophenoxy)tetrazole-2-carboxylate in dimethyl sulfoxide at room temperature yields a mixture of 1-methylsulfanylmethyl-5-(4-nitrophenoxy)tetrazole, 1- and 2-methyl-5-(4-nitrophenoxy)tetrazoles, and 5-(4-nitrophenoxy)tetrazole. Methyl 5-aryloxytetrazole-2-carboxylates containing electron-donor substituents in the aryloxy group do not give rise to the corresponding products under analogous conditions. The reactions of 5-aryloxytetrazoles [Ar = 4-O2NC6H4, C6H5, 2,6-(MeO)2C6H3] with dimethyl sulfoxide in the presence of acetic anhydride lead to mixtures of 1- and 2-methylsulfanylmethyl-5-aryloxytetrazoles whose yield and ratio depend on the substituent in the aryloxy group. The structure of 1-methylsulfanylmethyl-5-(4-nitrophenoxy)tetrazole was studied by X-ray analysis, two-dimensional NMR spectroscopy (HSQC, HMBC, NOESY), and quantum-chemical methods (ab initio, AM1, PM3). A highly selective procedure was developed for the synthesis of 5-(4-nitrophenoxy)tetrazole.
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REFERENCES
Singh, H., Chawla, A., Kapoor, V., Paul, D., and Malkurta, R., Prog. Med. Chem., 1980, vol. 77, p. 151.
Dabbagh, H.A. and Karimzadeh, R., Molecules, 2002, vol. 7, p. 189.
Dabbagh, H.A. and Gaelee, S., J. Org. Chem., 1996, vol. 61, p. 3439.
Dabbagh, H.A., Mansoori, Y., Jafari, M., and Rostami, M., J. Chem. Res., Synop., 2000, p. 442.
Huff, B.F., LeTourneau, M.E., Staszak, M.A., and Ward, J.A., Tetrahedron Lett., 1996, vol. 37, p. 3655.
Olofson, R.A. and Kendall, R.V., J. Org. Chem., 1970, vol. 35, p. 2246.
Isida, T., Akiyama, T., Nabika, K., Sisido, K., and Kosima, S., Bull. Chem. Soc. Jpn., 1973, vol. 46, p. 2176.
Nelson, J.H., Schmitt, D.L., Henry, R.A., Moore, D.W., and Jonassen, H.B., Inorg. Chem., 1970, vol. 9, p. 2678.
Ofele, K. and Kreiter, C.G., Chem. Ber., 1972, vol. 105, p. 529.
Markgraf, J.H., Brown, H.S., Kaplinsky, M.W., and Peterson, R.G., J. Org. Chem., 1964, vol. 29, p. 2629.
Hobbs, P.D. and Magnus, P.D., J. Chem. Soc., Perkin Trans. 1, 1973, p. 469.
Dabbagh, H.A. and Modarresi-Alam, A.R., J. Chem. Res., Synop., 2000, p. 44.
Dabbagh, H.A. and Lwowski, W., J. Org. Chem., 2000, vol. 65, p. 7284.
Dabbagh, H.A. and Mansoori, Y., Russ. J. Org. Chem., 2001, vol. 37, p. 1771.
Pfitzner, K.E. and Moffatt, J.G., J. Am. Chem. Soc., 1963, vol. 85, p. 3027.
Burdon, M.G. and Moffatt, J.G., J. Am. Chem. Soc., 1967, vol. 89, p. 4725.
Pfitzner, K.E., Marino, J.P., and Olofson, R.A., J. Am. Chem. Soc., 1965, vol. 87, p. 4658.
Moffatt, J.G., J. Org. Chem., 1971, vol. 36, p. 1909.
Hayashi, Y. and Oda, R., J. Org. Chem., 1967, vol. 32, p. 457.
Huang, S.L., Omura, K., and Swern, D., J. Org. Chem., 1976, vol. 41, p. 3329.
Mancuso, A.J., Huang, S.-L., and Swern, D., J. Org. Chem., 1978, vol. 43, p. 2480.
Gassman, P.G. and Gruetzmacher, G., J. Am. Chem. Soc., 1973, vol. 95, p. 588.
Gassman, P.G. and van Bergen, T.J., J. Am. Chem. Soc., 1973, vol. 95, p. 590.
Martin, D. and Weise, A., Chem. Ber., 1966, vol. 99, p. 317.
Hatman, W.W. and Dreger, E.E., Org. Synth., 1943, collect. vol. 2, p. 150.
Grigate, E. and Putter, R., Chem. Ber., 1964, vol. 97, p. 3012.
Sheldrick, G.M., SHELXL97, Gottingen: Univ. of Gottingen, 1997.
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From Zhurnal Organicheskoi Khimii, Vol. 41, No. 7, 2005, pp. 1076–1084.
Original English Text Copyright © 2005 by Dabbagh, Noroozi Pesyan, Bagheri, Takemo, Hayashi.
The original article was submitted in English.
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Dabbagh, H.A., Noroozi Pesyan, N., Bagheri, A. et al. Reaction of 5-Aryloxytetrazoles with Dimethyl Sulfoxide and DMSO-Acetic Anhydride. Structure and Quantum-Chemical Calculations of 1-Methylsulfanylmethyl-5-(4-nitrophenoxy)tetrazole. Russ J Org Chem 41, 1055–1063 (2005). https://doi.org/10.1007/s11178-005-0293-9
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DOI: https://doi.org/10.1007/s11178-005-0293-9