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Heterocycles Synthesis Based on Arylation Products of Unsaturated Compounds: XII. Reactions of 2-Aryl-1,4-benzoquinones with Dithiol Compounds

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Abstract

Reactions of 2-aryl-1,4-benzoquinones with disodium (2,2-dicyano-1,1-ethylene)dithiolate gave rise either to 1,3-benzodithiol or 1,3-benzoxathiol depending on the character of the aryl substituent. 2-Aryl-1,4-benzoquinones reacted with 3-methylsulfanyl-3-sulfanyl-2-cyanoacrylamide with a higher selectivity: 2-(7-Aryl-5-hydroxy-1,3-benzoxathiol-2-ylidene)-2-cyanoacetamides were obtained in a high yield.

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Authors and Affiliations

  1. Ivan Franko Lvov National University, Lvov, 79005, Ukraine

    N. D. Obushak, R. L. Martyak & V. S. Matiichuk

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  1. N. D. Obushak
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  2. R. L. Martyak
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  3. V. S. Matiichuk
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__________

Translated from Zhurnal Organicheskoi Khimii, Vol. 41, No. 5, 2005, pp. 762–766.

Original Russian Text Copyright © 2005 by Obushak, Martyak, Matiichuk.

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Obushak, N.D., Martyak, R.L. & Matiichuk, V.S. Heterocycles Synthesis Based on Arylation Products of Unsaturated Compounds: XII. Reactions of 2-Aryl-1,4-benzoquinones with Dithiol Compounds. Russ J Org Chem 41, 748–752 (2005). https://doi.org/10.1007/s11178-005-0238-3

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  • DOI: https://doi.org/10.1007/s11178-005-0238-3

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