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Russian Journal of Organic Chemistry

, Volume 41, Issue 5, pp 694–702 | Cite as

Reactions of Isomeric Arylchloropyruvates and Glycidates with Hydrazines

  • V. A. Mamedov
  • L. V. Mustakimova
  • A. T. Gubaidullin
  • I. A. Litvinov
  • Ya. A. Levin
Article

Abstract

Reactions of arylchloropyruvic acids esters with aryl- and hetarylhydrazines give rise to pyrazolinedione hydrazones as a result of a tandem condensation of the substituted hydrazines with arylchloropyruvates. In contrast to this process in reaction with hydrazine hydrate a ready reduction unexpectedly occurs by Kizhner-Wolff mechanism affording 3-hydroxydihydrocinnamic acid hydrazide as the principal product. The isomeric arylglycidate reacts along the same pattern.

Keywords

Ester Hydrate Organic Chemistry Hydrazine Acid Ester 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© MAIK “Nauka/Interperiodica” 2005

Authors and Affiliations

  • V. A. Mamedov
    • 1
  • L. V. Mustakimova
    • 1
  • A. T. Gubaidullin
    • 1
  • I. A. Litvinov
    • 1
  • Ya. A. Levin
    • 1
  1. 1.Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific CenterRussian Academy of SciencesKazanRussia

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