Abstract
Transformations of epoxide derived from nopol in the presence of natural askanite-bentonite clay were studied. The major products of the isomerization in the cold are diols possessing a p-menthane skeleton, which are readily converted into bicyclic ethers when the reaction is carried out at room temperature.
Similar content being viewed by others
REFERENCES
Il’ina, I.V., Korchagina, D.V., Salakhutdinov, N.F., and Barkhash, V.A., Russ. J. Org. Chem., 2000, vol. 36, p. 1446.
Bain, J.P., J. Am. Chem. Soc., 1946, vol. 68, p. 638.
Volcho, K.P., Tatarova, L.E., Korchagina, D.V., Salakhutdinov, N.F., and Barkhash, V.A., Russ. J. Org. Chem., 2000, vol. 36, p. 32.
Yarovaya, O.I., Korchagina, D.V., Gatilov, Yu.V., and Barkhash, V.A., Russ. J. Org. Chem., 2002, vol. 38, p. 810.
Chapuis, C. and Brauchli, R., Helv. Chim. Acta, 1992, vol. 75, p. 1527.
Bost, J.J., Kepner, R.E., and Webb, A.D., J. Org. Chem., 1957, vol. 22, p. 51.
Adachi, K., Nippon Kagaku Zasshi, 1971, vol. 92, p. 654; Chem. Abstr., 1972, vol. 76, no. 59 286.
Bohlmann, F., Zeistery, R., and Klein, E., Org. Magn. Reson., 1975, vol. 7, p. 426.
Author information
Authors and Affiliations
Additional information
Translated from Zhurnal Organicheskoi Khimii, Vol. 40, No. 10, 2004, pp. 1483–1487.
Original Russian Text Copyright © 2004 by Il’ina, Volcho, Korchagina, Salakhutdinov, Barkhash.
Rights and permissions
About this article
Cite this article
Il’ina, I.V., Volcho, K.P., Korchagina, D.V. et al. Transformations of epoxide derived from nopol over askanite-bentonite clay. Russ J Org Chem 40, 1432–1436 (2004). https://doi.org/10.1007/s11178-005-0036-y
Received:
Issue Date:
DOI: https://doi.org/10.1007/s11178-005-0036-y