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Russian Journal of General Chemistry

, Volume 75, Issue 11, pp 1774–1781 | Cite as

A Voltammetric Study of the Chemosensor Activity of Aminoanthracene Derivatives

  • I. A. Profatilova
  • A. A. Bumber
  • I. E. Tolpygin
  • V. P. Rybalkin
  • T. N. Gribanova
  • I. E. Mikhailov
  • V. A. Bren'
Article

Abstract

The redox activity of potent chemosensors based on anthryl-containing diamines, thioureas, and ureas in the absence and in the presence of complexing metal cations in solution was studied by cyclic and differential pulse voltammetry. The free energy of intramolecular electron transfer was calculated. The experimental conclusions were confirmed by ab initio RHF/6-31G** calculations. A correlation was found between the electrochemical and photophysical data for the compounds studied.

Keywords

Urea Free Energy Electron Transfer Diamine Thiourea 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© MAIK "Nauka/Interperiodica" 2005

Authors and Affiliations

  • I. A. Profatilova
    • 1
  • A. A. Bumber
    • 2
  • I. E. Tolpygin
    • 1
  • V. P. Rybalkin
    • 2
  • T. N. Gribanova
    • 2
  • I. E. Mikhailov
    • 1
  • V. A. Bren'
    • 2
  1. 1.Southern Scientific CenterRussian Academy of SciencesRostov-on-DonRussia
  2. 2.Research Institute of Physical and Organic ChemistryRostov State UniversityRostov-on-DonRussia

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