Russian Journal of General Chemistry

, Volume 75, Issue 10, pp 1584–1593 | Cite as

Formation of Exciplexes in Films of Polyimides, Polyamides, and Polyquinazolones Derived from Aromatic and Heteroaromatic Diamines

  • N. I. Rtishchev
  • G. I. Nosova
  • N. A. Solovskaya
  • K. A. Romashkova
  • V. V. Kudryavtsev


The emission bands exchibited by films of polyimides derived from 1,3-bis(3,4-dicarboxyphenoxy)benzene dianhydride, hexafluoroisopropylidenedibenzene-3,3′,4,4′-tetracarboxylic dianhydride, and aromatic and heteroaromatic diamines, and also of polyamides and polyquinazolones derived from the same amines are exciplex bahnds. With polyamides, complexes in the ground state are formed. The fluorescence of the photoconductivity sensitizer Rhodamine 6G is quenched in films of these polymers by the exciplex mechanism.


Polymer Benzene Diamine Rhodamine Polyimide 
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Copyright information

© MAIK "Nauka/Interperiodica" 2005

Authors and Affiliations

  • N. I. Rtishchev
    • 1
  • G. I. Nosova
    • 2
  • N. A. Solovskaya
    • 2
  • K. A. Romashkova
    • 2
  • V. V. Kudryavtsev
    • 2
  1. 1.St. Petersburg State Institute of TechnologyTechnical UniversitySt. PetersburgRussia
  2. 2.Institute of Macromolecular CompoundsRussian Academy of SciencesSt. PetersburgRussia

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