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Russian Journal of General Chemistry

, Volume 75, Issue 7, pp 1098–1107 | Cite as

Reaction of Organoelement Hydrides R3EH (E = Si, Ge) with Metal tert-Butylate (M = Al, Ti)-tert-Butyl Hydroperoxide Oxidative Systems

  • L. P. Stepovik
  • M. V. Gulenova
  • I. M. Martynova
  • N. S. Skvortsov
  • V. K. Cherkasov
Article

Abstract

Trialkyl(aryl)silanes and -germanes effectively react with metal (Al, Ti) tert-butylate-tert-butyl-hydroperoxide under mild conditions (room temperature, benzene or tetrachloromethane) mainly by the element-hydrogen bond. The character of the products depends on the nature of the element, the structure of the radical bound to it, and the solvent. The process is radical in nature. It includes the stages of formation of element-centered radicals and their reaction with the oxygen generated by the system. The intermediate organometallic peroxides can also acts as oxidants for the element (Si, Ge)-hydrogen bonds.

Keywords

Oxygen Hydrogen Peroxide Silane Benzene 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© MAIK “Nauka/Interperiodica” 2005

Authors and Affiliations

  • L. P. Stepovik
    • 1
  • M. V. Gulenova
    • 1
  • I. M. Martynova
    • 1
  • N. S. Skvortsov
    • 1
  • V. K. Cherkasov
    • 2
  1. 1.Lobachevskii Nizhny Novgorod State UniversityNizhny NovgorodRussia
  2. 2.Razuvaev Institute of Organometallic ChemistryRussian Academy of SciencesNizhny NovgorodRussia

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