Advertisement

Russian Journal of General Chemistry

, Volume 75, Issue 7, pp 1074–1076 | Cite as

Properties of Onium Salts of Phosphorus and Nitrogen

  • M. Zh. Ovakimyan
  • S. K. Barsegyan
  • N. M. Kikoyan
  • M. G. Indzhikyan
Article

Abstract

Ammonium and phosphonium halides when heated with excess dimethyl or diethyl phosphite can undergo anion exchange as a result of alkylation of halide ions with dialkyl phosphites. Experimental data were obtained, that cast some doubt in the commonly accepted opinion that reactions of tertiary amines and phosphines with dihalides in apolar media result in exclusive formation of monosalts.

Keywords

Nitrogen Experimental Data Ammonium Phosphorus Dimethyl 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

REFERENCES

  1. 1.
    Torgomyan, A.M., Ovakimyan, M.Zh., and Indzhikyan, M.G., Arm. Khim. Zh., 1977, vol. 30, no.5, p. 439.Google Scholar
  2. 2.
    Babayan, A.T., Indzhikyan, M.G., and Gegelyan, Zh.G., Zh. Org. Khim., 1966, vol. 2, no.12, p. 2117.Google Scholar
  3. 3.
    Babayan, A.T., Martirosyan, G.T., Gyul’nazaryan, A.H., and Arakelyan, N.M., Arm. Khim. Zh., 1972, vol. 25, no.2, p. 123.Google Scholar

Copyright information

© MAIK “Nauka/Interperiodica” 2005

Authors and Affiliations

  • M. Zh. Ovakimyan
    • 1
  • S. K. Barsegyan
    • 1
  • N. M. Kikoyan
    • 1
  • M. G. Indzhikyan
    • 1
  1. 1.Institute of Organic ChemistryNational Academy of Sciences of ArmeniaErevanArmenia

Personalised recommendations