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Russian Journal of General Chemistry

, Volume 75, Issue 6, pp 901–904 | Cite as

Determination of the Inductive Constant of the Succinimide Group from the Reaction Series of Thermolysis of Nitro Esters

  • T. K. Goncharov
  • V. V. Dubikhin
  • G. M. Nazin
  • B. S. Fedorov
  • A. V. Shastin
Article
  • 26 Downloads

Abstract

The inductive constant σ* of the succinimide group was determined using the previously obtained equation correlating the rate constant kl ofliquid-phase homolysis of the O-NO2 bond in nitro esters with the σ* constants of electronegative substituents. The kinetics of thermolysis of N-nitroxymethyl- and N-(2-nitroxyethyl)succinimide in the melt and solutions was studied manometrically. Adequate data for kl were obtained. The σ* constant of the succinimide group was determined to be 4.5. The σ* constants for the phthalimide group and some other imide substituents were determined by a similar procedure.

Keywords

Ester Imide Thermolysis Reaction Series Adequate Data 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© MAIK “Nauka/Interperiodica” 2005

Authors and Affiliations

  • T. K. Goncharov
    • 1
  • V. V. Dubikhin
    • 1
  • G. M. Nazin
    • 1
  • B. S. Fedorov
    • 1
  • A. V. Shastin
    • 1
  1. 1.Institute of Problems of Chemical PhysicsRussian Academy of SciencesChernogolovka, Moscow oblastRussia

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