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Russian Journal of General Chemistry

, Volume 75, Issue 5, pp 734–738 | Cite as

Addition of Tetrachloromethane to Alkenes, Catalyzed by Pt(II) Complexes

  • A. G. Zazybin
  • Yu. R. Khusnutdinova
  • O. L. Osipova
  • B. N. Solomonov
Article

Abstract

Platinum(II) complexes [dichlorobis(triphenylphosphine)platinum(II), dichlorobis(tri-m-tolylphosphine)platinum(II), dichloro(2,9-dimethyl-1,10-N, N′-phenanthroline)platinum(II), etc.] showed catalytic activity in addition of tetrachloromethane across the double bond in 1-hexene, 1-heptene, 1-octene, 1-decene, and cyclohexene. The stability of the platinum catalysts was evaluated by GLC, gas chromatography-mass spectrometry, and 31P NMR and IR spectroscopy; the kinetic relationships of the addition reactions were determined. A reaction mechanism involving formation of trichloromethyl radical was suggested. A correlation was revealed for the first time between the catalytic activity of platinum, palladium, and rhodium complexes and the capability of these complexes to generate hexachloroethane.

Keywords

Platinum Catalytic Activity Palladium Cyclohexene Rhodium 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© MAIK “Nauka/Interperiodica” 2005

Authors and Affiliations

  • A. G. Zazybin
    • 1
  • Yu. R. Khusnutdinova
    • 1
  • O. L. Osipova
    • 1
  • B. N. Solomonov
    • 1
  1. 1.Kazan State UniversityKazan, TatarstanRussia

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