Russian Journal of General Chemistry

, Volume 75, Issue 4, pp 549–560 | Cite as

Specific Features of Reaction of 2-R-Benzo[e][1,3,2]dioxaphosphinin-4-ones with Perfluorodiacetyl. Synthesis and Steric Structure of 4′,5′-Bis(trifluoromethyl)-4-oxo-2-(2,2,3,3-tetrafluoropropoxy)-2λ 5-spiro[benzo[e][1,3,2]dioxaphosphinine-2,2′-[1,3,2]dioxaphosphole]

  • I. V. Konovalova
  • V. F. Mironov
  • G. A. Ivkova
  • E. R. Zagidullina
  • A. T. Gubaidullin
  • I. A. Litvinov
  • M. A. Kurykin


2-R-benzo[e][1,3,2]dioxaphosphinin-4-ones react with perfluorodiacetyl under mild conditions to form relatively labile spirophosphoranes containing a 1,3,2-dioxaphosphole ring. These compounds gradually convert to more stable 2-R-4,5-bis(trifluoromethyl)-1,3,2λ5-dioxaphosphole 2-oxides and diastereometic 2-R-4-(trifluoroacetyl)-4-(trifluoromethyl)benzo[f][1,3,2λ5]dioxaphosphepine 2-oxides, whose structure was confirmed by means of NMR and IR spectroscopy. The structure of 4′,5′ -bis(trifluoromethyl)-4-oxo-2-(2,2,3,3-tetrafluoropropoxy)-2λ 5-spiro[benzo[e][1,3,2]dioxaphosphinine-2,2′-[1,3,2]dioxaphosphole] was confirmed by X-ray diffraction analysis.


Spectroscopy Diffraction Analysis Mild Condition Trifluoromethyl Trifluoroacetyl 
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Copyright information

© MAIK “Nauka/Interperiodica” 2005

Authors and Affiliations

  • I. V. Konovalova
    • 1
  • V. F. Mironov
    • 1
    • 2
  • G. A. Ivkova
    • 1
  • E. R. Zagidullina
    • 1
  • A. T. Gubaidullin
    • 2
  • I. A. Litvinov
    • 2
  • M. A. Kurykin
    • 3
  1. 1.Kazan State UniversityKazan, TatarstanRussia
  2. 2.Arbuzov Institute of Organic and Physical Chemistry, Kazan Research CenterRussian Academy of SciencesKazan, TatarstanRussia
  3. 3.Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussia

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