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Russian Journal of General Chemistry

, Volume 75, Issue 3, pp 370–374 | Cite as

Synthesis and Molecular Structure of Substituted 4-[N-Phenyl-N-(2-chloroethyl)amino]-1,4-dihydro-1,2,4λ5-diazaphosphorines

  • Yu. G. Trishin
  • T. V. Gonchar
  • V. I. Namestnikov
  • A. I. Stash
  • V. E. Zavodnik
  • V. K. Bel’skii
Article
  • 27 Downloads

Abstract

The reaction of 3-phenyl-2-phenylethynyl-1,3,2λ3-oxazaphospholidine with nitrilimines is a multistep process involving formation of the diazaphosphorine ring and cleavage of the oxazaphospholidine ring. The final products are the substituted 4-[N-phenyl-N-(2-chloroethyl)amino]-1,4-dihydro-1,2,4λ5-diazaphosphorines. According to X-ray structural data obtained for 4-[N-phenyl-N-(2-chloroethyl)amino]-1,4-dihydro- 1,5-diphenyl-3-ethoxycarbonyl-1,2,4λ5-diazaphosphorine, the heteroring of these compounds has the conformation of a flattened P-envelope.

Keywords

Structural Data Molecular Structure Dihydro Multistep Process Diazaphosphorine 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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REFERENCES

  1. 1.
    Trishin, Yu.G., Gonchar, T.V., and Namestnikov, V.I., Zh. Obshch. Khim., 2004, vol. 74, no.10, p. 1752.Google Scholar
  2. 2.
    Senyukh, S.V., Namestnikov, V.I., Trishin, Yu.G., and Chistokletov, V.N., Zh. Obshch. Khim., 1990, vol. 60, no.10, p. 1926.Google Scholar
  3. 3.
    Nifant’ev, E.E. and Vasyanina, L.K., Spektroskopiya YaMR 31 P (31P NMR Spectroscopy), Moscow: Mosk. Gos. Ped. Inst., 1986.Google Scholar
  4. 4.
    Erofeeva, M.P., Trishin, Yu.G., and Chistokletov, V.N., Zh. Obshch. Khim., 1989, vol. 59, no.9, p. 2146; Namestnikov, V.I., Trishin, Yu.G., Tamm, L.A., and Chistokletov, V.N., Zh. Obshch. Khim., 1990, vol. 60, vol. 3, p. 510; Trishin, Yu.G., Afanasov, A.F., Litvinov, I.A., Naumov, V.A., and Chistokletov, V.N., Zh. Obshch. Khim., 1990, vol. 60, no. 11, p. 2446.Google Scholar
  5. 5.
    Pudovik, A.N., Pudovik, M.A., Shulyndina, O.S., and Nagaeva, Kh.Kh., Zh. Obshch. Khim., 1970, vol. 40, no.7, p. 1477.Google Scholar

Copyright information

© MAIK “Nauka/Interperiodica” 2005

Authors and Affiliations

  • Yu. G. Trishin
    • 1
  • T. V. Gonchar
    • 1
  • V. I. Namestnikov
    • 1
  • A. I. Stash
    • 1
  • V. E. Zavodnik
    • 1
  • V. K. Bel’skii
    • 1
  1. 1.St. Petersburg State Technological University of Plant PolymersSt. PetersburgRussia

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