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Synthesis and Molecular Structure of Substituted 4-[N-Phenyl-N-(2-chloroethyl)amino]-1,4-dihydro-1,2,4λ5-diazaphosphorines

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Abstract

The reaction of 3-phenyl-2-phenylethynyl-1,3,2λ3-oxazaphospholidine with nitrilimines is a multistep process involving formation of the diazaphosphorine ring and cleavage of the oxazaphospholidine ring. The final products are the substituted 4-[N-phenyl-N-(2-chloroethyl)amino]-1,4-dihydro-1,2,4λ5-diazaphosphorines. According to X-ray structural data obtained for 4-[N-phenyl-N-(2-chloroethyl)amino]-1,4-dihydro- 1,5-diphenyl-3-ethoxycarbonyl-1,2,4λ5-diazaphosphorine, the heteroring of these compounds has the conformation of a flattened P-envelope.

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Authors and Affiliations

  1. St. Petersburg State Technological University of Plant Polymers, St. Petersburg, Russia

    Yu. G. Trishin, T. V. Gonchar, V. I. Namestnikov, A. I. Stash, V. E. Zavodnik & V. K. Bel’skii

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  1. Yu. G. Trishin
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  2. T. V. Gonchar
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  3. V. I. Namestnikov
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  4. A. I. Stash
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  5. V. E. Zavodnik
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  6. V. K. Bel’skii
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__________

Translated from Zhurnal Obshchei Khimii, Vol. 75, No. 3, 2005, pp. 406–410.

Original Russian Text Copyright © 2005 by Trishin, Gonchar, Namestnikov, Stash, Zavodnik, Bel’skii

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Trishin, Y.G., Gonchar, T.V., Namestnikov, V.I. et al. Synthesis and Molecular Structure of Substituted 4-[N-Phenyl-N-(2-chloroethyl)amino]-1,4-dihydro-1,2,4λ5-diazaphosphorines. Russ J Gen Chem 75, 370–374 (2005). https://doi.org/10.1007/s11176-005-0233-y

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  • DOI: https://doi.org/10.1007/s11176-005-0233-y

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