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Generalization of Data on Solvent Effect on Formation of Charge-Transfer Complexes Using Linear Multiparameter Equations

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Abstract

The correlation analysis of data on the equilibrium constants of formation of various charge-transfer complexes (K e) in various solvents shows that the solvent polarity alone does not provide sufficiently reliable description of the process. An adequate correlation between K e and solvent properties can be obtained only with combined consideration of the capability of solvents for specific and nonspecific solvation.

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Authors and Affiliations

  1. Division of Physical Chemistry and Technology of Fossil Fuels, Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Lvov, Ukraine

    R. G. Makitra, I. P. Polyuzhin & I. P. Shevchuk

  2. Lvovskaya Polytechnika National University, Lvov, Ukraine

    R. G. Makitra, I. P. Polyuzhin & I. P. Shevchuk

Authors
  1. R. G. Makitra
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  2. I. P. Polyuzhin
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  3. I. P. Shevchuk
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__________

Translated from Zhurnal Obshchei Khimii, Vol. 75, No. 2, 2005, pp. 201–204.

Original Russian Text Copyright © 2005 by Makitra, Polyuzhin, Shevchuk.

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Makitra, R.G., Polyuzhin, I.P. & Shevchuk, I.P. Generalization of Data on Solvent Effect on Formation of Charge-Transfer Complexes Using Linear Multiparameter Equations. Russ J Gen Chem 75, 177–180 (2005). https://doi.org/10.1007/s11176-005-0194-1

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  • DOI: https://doi.org/10.1007/s11176-005-0194-1

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