Russian Journal of General Chemistry

, Volume 75, Issue 2, pp 177–180 | Cite as

Generalization of Data on Solvent Effect on Formation of Charge-Transfer Complexes Using Linear Multiparameter Equations

  • R. G. Makitra
  • I. P. Polyuzhin
  • I. P. Shevchuk


The correlation analysis of data on the equilibrium constants of formation of various charge-transfer complexes (Ke) in various solvents shows that the solvent polarity alone does not provide sufficiently reliable description of the process. An adequate correlation between Ke and solvent properties can be obtained only with combined consideration of the capability of solvents for specific and nonspecific solvation.


Correlation Analysis Equilibrium Constant Solvent Polarity Solvent Effect Solvent Property 
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Copyright information

© MAIK “Nauka/Interperiodica” 2005

Authors and Affiliations

  • R. G. Makitra
    • 1
    • 2
  • I. P. Polyuzhin
    • 1
    • 2
  • I. P. Shevchuk
    • 1
    • 2
  1. 1.Division of Physical Chemistry and Technology of Fossil Fuels, Pisarzhevskii Institute of Physical ChemistryNational Academy of Sciences of UkraineLvovUkraine
  2. 2.Lvovskaya Polytechnika National UniversityLvovUkraine

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