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State of Chromium in Solid Solutions of Complex Bismuth Niobates Bi2BaCrxNb2-x O9(0.01 < x < 0.3)

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Abstract

Magnetic susceptibility and electric properties of complex bismuth niobates with the layered perovskite structure, containing chromium(III) atoms in niobium(V) sites, were studied. Clusters of chromium(III) atoms with a high antiferromagnetic exchange parameter (−45 cm−1) were found, whose formation along the c axis of the structure is associated with the presence of vacancies in the oxygen sublattice.

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Authors and Affiliations

  1. St. Petersburg State University, St. Petersburg, Russia

    N. V. Chezhina, I. V. Piir & N. A. Zhuk

  2. Syktyvkar State University, Syktyvkar, Komi Republic, Russia

    N. V. Chezhina, I. V. Piir & N. A. Zhuk

Authors
  1. N. V. Chezhina
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  2. I. V. Piir
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  3. N. A. Zhuk
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__________

Translated from Zhurnal Obshchei Khimii, Vol. 75, No. 1, 2005, pp. 24–28.

Original Russian Text Copyright © 2005 by Chezhina, Piir, Zhuk.

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Chezhina, N.V., Piir, I.V. & Zhuk, N.A. State of Chromium in Solid Solutions of Complex Bismuth Niobates Bi2BaCrxNb2-x O9(0.01 < x < 0.3). Russ J Gen Chem 75, 21–24 (2005). https://doi.org/10.1007/s11176-005-0165-6

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  • DOI: https://doi.org/10.1007/s11176-005-0165-6

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