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Concentration dependence of the viscosity of tert-butanol-water mixtures: Physical experiment and computer simulation

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Abstract

The concentration dependence of the viscosity of tert-butanol-water mixtures in the range of tert-butanol mole fractions from 0 to 0.02 was studied experimentally and by computer simulation. The methods of potentials of mean force and statistical geometry were successfully applied to analysis of physical factors responsible for the extrema in the composition-property dependences. The maximum in the concentration dependence of the viscosity is due to association of solvent molecules.

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Authors and Affiliations

  1. Institute of Solution Chemistry, Russian Academy of Sciences, Ivanovo, Russia

    I. A. Luk’yanchikova, D. V. Ivlev, M. G. Kiselev & G. A. Al’per

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  1. I. A. Luk’yanchikova
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  2. D. V. Ivlev
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  3. M. G. Kiselev
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  4. G. A. Al’per
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Translated from Zhurnal Obshchei Khimii, Vol. 74, No. 8, 2004, pp. 1250–1256.

Original Russian Text Copyright © 2004 by Luk’yanchikova, Ivlev, Kiselev, Al’per.

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Luk’yanchikova, I.A., Ivlev, D.V., Kiselev, M.G. et al. Concentration dependence of the viscosity of tert-butanol-water mixtures: Physical experiment and computer simulation. Russ J Gen Chem 74, 1156–1162 (2004). https://doi.org/10.1007/s11176-005-0129-x

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  • DOI: https://doi.org/10.1007/s11176-005-0129-x

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