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Russian Journal of General Chemistry

, Volume 74, Issue 10, pp 1496–1500 | Cite as

Novel acyclic and macrocyclic highly unsaturated silahydrocarbons

  • O. G. Yarosh
  • L. V. Zhilitskaya
  • N. K. Yarosh
  • E. E. Istomina
  • A. I. Albanov
  • Yu. A. Chuvashev
  • M. G. Voronkov
Article

Abstract

Two novel silicon-containing acetylenic synthons, 1-[dimethyl(ethynyl)silyl]-2-[ethynyl(methyl)-(vinyl)silyl]ethyne and bis[(ethynyldimethylsilyl)ethynyl](methyl)vinylsilane, were obtained by the reaction of diethynyl(methyl)vinylsilane with ethylmagnesium bromide and ethynylfluorodimethylsilane. The reaction of magnesium derivatives of the products and diethynyl(methyl)vinylsilane with organylhalosilanes gave macrocyclic polyunsaturated silahydrocarbons containing numerous endo- and exocyclic miltiple bonds.

Keywords

Methyl Magnesium Bromide Dimethyl Vinyl 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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REFERENCES

  1. 1.
    Yarosh, O.G., Ivanova, Z.G., Burnasheva, T.D., and Voronkov, M.G., Izv. Akad. Nauk SSSR, Ser. Khim., 1984, no. 11, p. 2614.Google Scholar
  2. 2.
    Yarosh, O.G., Voronkov, M.G., and Brodskaya, E.I., Usp. Khim., 1995, vol. 64, no.9, p. 896.Google Scholar
  3. 3.
    Yarosh, O.G., Bystrova, V.V., Albanov, A.I., Klyba, L.V., and Voronkov, M.G., Zh. Obshch. Khim., 2001, vol. 71, no.12, p. 1974.Google Scholar
  4. 4.
    Komarov, N.V. and Yarosh, O.G., Zh. Obshch. Khim., 1967, vol. 37, no.1, p. 264.Google Scholar
  5. 5.
    Yarosh, O.G., Voronkov, M.G., and Tsetlina, E.O., Izv. Akad. Nauk SSSR, Ser. Khim., 1976, no. 7, p. 1633.Google Scholar

Copyright information

© MAIK “Nauka/Interperiodica” 2004

Authors and Affiliations

  • O. G. Yarosh
    • 1
  • L. V. Zhilitskaya
    • 1
  • N. K. Yarosh
    • 1
  • E. E. Istomina
    • 1
  • A. I. Albanov
    • 1
  • Yu. A. Chuvashev
    • 1
  • M. G. Voronkov
    • 1
  1. 1.Favorskii Irkutsk Institute of Chemistry, Siberian BranchRussian Academy of SciencesIrkutskRussia

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