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Russian Journal of General Chemistry

, Volume 74, Issue 9, pp 1356–1358 | Cite as

Reactivity of N-(chlorodimethylgermyl)methyl and N-(chlorodimethylsilyl)methyl derivatives of lactams and amides toward Grignard reagents

  • S. Yu. Bylikin
  • A. G. Shipov
  • E. P. Kramarova
  • O. B. Artamkina
  • Vad. V. Negrebetskii
  • Yu. I. Baukov
Article
  • 24 Downloads

Abstract

N-[(Chlorodimethylgermyl)methyl]lactams and -amides containing a five-coordinate germanium atom react with Grignard reagents chemoselectively by the Ge-Cl bond to form four-coordinate germanium compounds. The method of competitive reactions was used to establish that respective five-coordinate germanium and silicon compounds are almost equally reactive toward Grignard reagents but much more reactive than model four-coordinate germanium and silicon compounds.

Keywords

Methyl Silicon Amide Germanium Lactam 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© MAIK “Nauka/Interperiodica” 2004

Authors and Affiliations

  • S. Yu. Bylikin
    • 1
  • A. G. Shipov
    • 1
  • E. P. Kramarova
    • 1
  • O. B. Artamkina
    • 1
  • Vad. V. Negrebetskii
    • 1
  • Yu. I. Baukov
    • 1
  1. 1.Russian State Medical UniversityMoscowRussia

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