Russian Journal of General Chemistry

, Volume 74, Issue 9, pp 1313–1316 | Cite as

Rhodium(I) pentasubstituted cationic complexes on the basis of 1,2-O-Alkylidene-3,5,6-O-phosphinetriyl-α-D-glucofuranose

  • A. M. Koroteev
  • A. T. Teleshov
  • M. P. Koroteev
  • E. E. Nifant’ev


Reaction of 1,2-O-alkylidene-α-D-glucofuranose 3,5,6-phosphites with dicarbonylrhodium(I) acetylacetonate was studied. The structure of the reaction products is determined by the reagent ratio. At a 5:1 molar ratio, the step ligand-exchange process yields chiral complexes of the [RhL5]+acac type. Dynamics of and anion exchange in these complexes are considered.


Anion Exchange Acac Rhodium Acetylacetonate Cationic Complex 
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Copyright information

© MAIK “Nauka/Interperiodica” 2004

Authors and Affiliations

  • A. M. Koroteev
    • 1
  • A. T. Teleshov
    • 1
  • M. P. Koroteev
    • 1
  • E. E. Nifant’ev
    • 1
  1. 1.Moscow State Pedagogical UniversityMoscowRussia

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