Russian Journal of General Chemistry

, Volume 74, Issue 9, pp 1313–1316 | Cite as

Rhodium(I) pentasubstituted cationic complexes on the basis of 1,2-O-Alkylidene-3,5,6-O-phosphinetriyl-α-D-glucofuranose

  • A. M. Koroteev
  • A. T. Teleshov
  • M. P. Koroteev
  • E. E. Nifant’ev


Reaction of 1,2-O-alkylidene-α-D-glucofuranose 3,5,6-phosphites with dicarbonylrhodium(I) acetylacetonate was studied. The structure of the reaction products is determined by the reagent ratio. At a 5:1 molar ratio, the step ligand-exchange process yields chiral complexes of the [RhL5]+acac type. Dynamics of and anion exchange in these complexes are considered.


Anion Exchange Acac Rhodium Acetylacetonate Cationic Complex 


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.


  1. 1.
    Haines, L.M., Inorg. Nucl. Chem. Lett., 1989, vol. 5, no.5, p. 399.Google Scholar
  2. 2.
    Meakin, P. and Jesson, J.P., J. Am. Chem. Soc., 1973, vol. 95, p. 5751.Google Scholar
  3. 3.
    Haines, L.M., Inorg. Chem., 1971, vol. 10, p. 1685.Google Scholar
  4. 4.
    Jesson, J.P. and Meakin, P., J. Am. Chem. Soc., 1973, vol. 95, p. 1344.Google Scholar
  5. 5.
    Teleshev, A.T., Kolesnichenko, N.V., Markova, N.A., and Terekhova, G.V., Neftekhimiya, 1991, vol. 39, no.7, pp. 1672–1673.Google Scholar
  6. 6.
    Nifantyev, E.E., Koroteev, M.P., Koroteev, A.M., Belsky, V.K., Stash, A.I., Antipin, M.Yu., Lysenko, K.A., and Cao, L., J. Organomet. Chem., 1999, vol. 587, pp. 18–27.Google Scholar
  7. 7.
    Nifant’ev, E.E., Koroteev, M.P., Koroteev, A.M., Belsky, V.K., and Magomedova, N.S., Zh. Obshch. Khim., 1991, vol. 61, no.11, pp. 2505–2513.Google Scholar
  8. 8.
    Aslanov, L.A., Sotman, S.S., Rybakov, V.B., and Andriyanov, V.I., Zh. Strukt. Khim., 1979, vol. 20, no.6, pp. 1125–1127.Google Scholar
  9. 9.
    Teleshov, A.T., Shishin, A.V., Malakhova, T.V., Kolesnichenko, N.V., and Nifantyev, E.E., Zh. Obshch. Khim., 1993, vol. 63, no.7, pp. 1672–1673.Google Scholar
  10. 10.
    Gordon, A.J. and Ford, R.A., The Chemist’s Companion, New York: Wiley, 1972.Google Scholar
  11. 11.
    Nifant’ev, E.E. and Petrova, I.M., Zh. Obshch. Khim., 1970, vol. 40, no.9, pp. 2196–2199.Google Scholar
  12. 12.
    Kochetkov, N.K., Nifantyev, E.E., Koroteev, M.P., Zhane, Z.K., and Borisenko, A.A., Carb. Res., 1976, vol. 47, no.2, pp. 221–231.Google Scholar
  13. 13.
    Varshavskii, Yu.S. and Cherkasova, T.G., Zh. Neorg. Khim., 1967, vol. 12, p. 1709.Google Scholar
  14. 14.
    Billman, J.H., Sojka, S.A., and Taylor, R.P., J. Chem. Soc., Perkin Trans., 1972, vol. 2, p. 2034.Google Scholar
  15. 15.
    Ewing, D.E., Org. Magn. Reson., 1979, vol. 12, p. 499.Google Scholar

Copyright information

© MAIK “Nauka/Interperiodica” 2004

Authors and Affiliations

  • A. M. Koroteev
    • 1
  • A. T. Teleshov
    • 1
  • M. P. Koroteev
    • 1
  • E. E. Nifant’ev
    • 1
  1. 1.Moscow State Pedagogical UniversityMoscowRussia

Personalised recommendations