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Russian Journal of General Chemistry

, Volume 74, Issue 9, pp 1313–1316 | Cite as

Rhodium(I) pentasubstituted cationic complexes on the basis of 1,2-O-Alkylidene-3,5,6-O-phosphinetriyl-α-D-glucofuranose

  • A. M. Koroteev
  • A. T. Teleshov
  • M. P. Koroteev
  • E. E. Nifant’ev
Article

Abstract

Reaction of 1,2-O-alkylidene-α-D-glucofuranose 3,5,6-phosphites with dicarbonylrhodium(I) acetylacetonate was studied. The structure of the reaction products is determined by the reagent ratio. At a 5:1 molar ratio, the step ligand-exchange process yields chiral complexes of the [RhL5]+acac type. Dynamics of and anion exchange in these complexes are considered.

Keywords

Anion Exchange Acac Rhodium Acetylacetonate Cationic Complex 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© MAIK “Nauka/Interperiodica” 2004

Authors and Affiliations

  • A. M. Koroteev
    • 1
  • A. T. Teleshov
    • 1
  • M. P. Koroteev
    • 1
  • E. E. Nifant’ev
    • 1
  1. 1.Moscow State Pedagogical UniversityMoscowRussia

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