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Russian Journal of Electrochemistry

, Volume 41, Issue 10, pp 1070–1076 | Cite as

Ionic Transport in Cation-Exchange Membranes MK-40 Modified with Zirconium Phosphate

  • S. A. Novikova
  • E. I. Volodina
  • N. D. Pis'menskaya
  • A. G. Veresov
  • I. A. Stenina
  • A. B. Yaroslavtsev
Article

Abstract

The synthesis of a composite membrane material on the basis of cation-exchange membrane MK-40 with inserted particles of acid zirconium phosphate is realized. It is shown that zirconium phosphate in the membrane's matrix takes on the form of small amorphous particles and is uniformly distributed. The obtained membrane is characterized by large values of conductance and diffusion coefficients for cations and anions, as well as by a lower selectivity when compared with the initial analogue. It is shown that the basic reason for this is the increase in the size of pores and channels, which are filled in the course of experiment by a solution of an electrolyte.

Key words

membrane composites conduction acid zirconium phosphate 

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Copyright information

© MAIK "Nauka/Interperiodica" 2005

Authors and Affiliations

  • S. A. Novikova
    • 1
  • E. I. Volodina
    • 2
  • N. D. Pis'menskaya
    • 2
  • A. G. Veresov
    • 3
  • I. A. Stenina
    • 1
  • A. B. Yaroslavtsev
    • 1
  1. 1.Kurnakov Institute of General and Inorganic ChemistryRussian Academy of SciencesMoscowRussia
  2. 2.Kuban State UniversityKrasnodarRussia
  3. 3.Moscow State UniversityMoscowRussia

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